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1.
Near-liquidus melting experiments were performed on a high-K latite at fO2's ranging from iron-wustite-graphite (IWG) to nickel-nickel oxide (NNO) in the presence of a C-O-H fluid phase. Clinopyroxene is a liquidus phase under all conditions. At IWG
, the liquidus at 10 kb is about 1,150° C but is depressed to 1,025° C at NNO and
. Phlogopite and apatite are near-liquidus phases, with apatite crystallizing first at pressures below 10 kb. Phlogopite is a liquidus phase only at NNO and high
. Under all conditions the high-K latites show a large crystallization interval with phlogopite becoming the dominant crystalline phase with decreasing temperature. Increasing fO2 affects phlogopite crystallization but the liquidus temperature is essentially a function of
. The chemical compositions of the near-liquidus phases support formation of the high-K latites under oxidizing conditions (NNO or higher) and high
. It is concluded from the temperature of the H2O-saturated liquidus at 10 kb, the groundmass: crystal ratio and presence of chilled latite margins around some xenoliths that the Camp Creek high-K latite magma passed thru the lower crust at temperatures of 1,000° C or more. 相似文献
2.
Dr. T. D. Peterson Dr. S. Esperança Dr. A. N. LeCheminant 《Mineralogy and Petrology》1994,51(2-4):251-276
Summary Early Proterozoic ultrapotassic dikes, lava flows, and pyroclastic rocks of the Christopher Island Formation (CIF) erupted throughout an area 600 × 300 km within the Churchill Province of the Canadian Shield at 1.84 Ga. The rocks range from mafic lamprophyres (mg # 60; SiO2 47–54%, mean K2O/Na2O > 4) with phenocrysts of phlogopite + diopside + apatite ± olivine ± magnetite, to phenocryst-poor felsic rocks and sanidine porphyries (SiO255–69%). All samples have high incompatible element contents and display large depletions of high field strength elements relative to K, Rb, Sr, Ba, and Th. The CIF has geochemical and petrographic characteristics of both minettes and lamproites, but overall most closely resembles young Mediterranean lamproites. Felsic rocks of the CIF were produced by crystal fractionation and crustal contamination of mafic ultrapotassic magma, and include both high-silica lamproites strongly enriched in Zr, U, and Th, and weakly potassic to sodic rocks of trachytic composition. Flows and feeder dikes have relatively homogeneous Nd, 1840 Ma (–6 to –11) but highly variable ES., 1840 Ma (–40 to + 100); samples classified as lamproites have higher average Sr. Dike samples have highly variable present-day Pb isotope compositions, ranging from moderately to strongly nonradiogenic. Geochemical and isotopic data are consistent with contributions from depleted Archean lithospheric mantle, and OIB-type convecting mantle, both metasomatized by subduction-related processes during the Early Proterozoic. The lithospheric mantle probably contained Archean enriched domains as well. Proterozoic enrichment may have accompanied shallow underplating of subducted oceanic lithosphere beneath the Churchill Province during amalgamation of the Laurentian supercontinent. There are strong analogies in isotopic composition, and interpreted source region history, between the CIF and lamproites and minettes of the Wyoming Province and western Greenland, which suggest the existence of a Laurentian ultrapotassic superprovince.
With 7 Figures 相似文献
Geochemie und Entstehung der Proterozoischen ultrapotassischen Gesteine der Churchill Provinz, Kanada
Zusammenfassung Altproterozoische, ultrapotassische Gänge, Lavaströme und pyroklastische Gesteine der Christopher Island Formation (CIF), eruptierten in einem Gebiet von 600 × 300 km in der Churchill Provinz des Kanadischen Schildes vor 1.84 Ga. Die Zusammensetzung dieser Gesteine variiert von mafischen Lamprophyren (mg > 60; SiO2 = 47–54%, durchschnittliches K2O/Na2O > 4) mit Phänokristallent von Phlogopit + Diopsid + Apatit + Olivin + Magnetit, bis zu phänokristallarmen felsischen Gesteinen und Sanidinporphyren (SiO2 = 55–69%). Alle Proben zeigen hohe Gehalte an inkompatiblen Elementen und zeigen beträchtliche Verarmung an high field strength Elementen relativ zu K, Rb, Sr, Ba und Th. Die CIF hat geochemische und petrographische Eigenschaften sowohl von Minetten wie von Lamproiten, aber im allgemeinen ähnelt sie am stärksten jungen mediterranen Lamproiten. Felsische Gesteine der CIF wurden durch Fraktionierung und Krustenkontamination aus mafischen ultrapotassischen Magmen gebildet. Letztere umfassen sowohl siliziumreiche Lamproite, die deutlich an Zr, U und Th angereichert sind und schwach potassische bis sodische Gesteine von trachytischer Zusammensetzung. Lavenergüsse und zufuhrgänge zeigent ein relativ homogenes Nd, 1840 Ma (–6 bis –11) aber ein sehr variables Sr, 1840 Ma (-40 bis + 100); Proben die als Lamproite klassifiziert wurden, zeigent höhere durchschnittliche Sr-Werte. Proben von Gängen haben sehr variable Bleiisotopen-Zusammensetzungen, die von mäßig bis stark nichtradiogen variieren. Geochemische und Isotopendaten weisen auf Beiträge aus verarmtem archaischen lithosphärischen Mantel und aus konvektierendem OIB-Typ Mantel hin, die beide während des Alproterozoikums durch Subduktions-Vorgänge metasomatisiert wurden. Der lithosphärische Mantel enthielt wahrscheinlich auch angereicherte archaische Domänen. Proterozoische Anreicherungsvorgänge dürften seichtes Underplating subduzierter ozeanischer Lithosphäre unter der Churchill Provinz während der Amalgamation des laurentischen Superkontinentes begleitet haben. Es gibt starke Analogien in der Isotopenzusammensetzung und in der interpretierten Geschichte der Ursprungsregion, zwischen den CIF und Lamproiten und Minetten der Wyoming Provinz, und des westlichen Grönland. Diese weisen auf die Existenz einer laurentischen ultrapotassischen Superprovinz hin.
With 7 Figures 相似文献
3.
Marc Peipoch Esperança Gacia Alba Blesa Miquel Ribot Joan L. Riera Eugènia Martí 《Aquatic Sciences - Research Across Boundaries》2014,76(2):203-215
We examined the relevance of dissolved inorganic nitrogen (DIN) forms (nitrate and ammonium) in stream water as N sources for different macrophyte species. To do this, we investigated the variability and relationships between 15N natural abundance of DIN forms and of four different macrophyte species in five different streams influenced by inputs from wastewater treatment plants and over time within one of these streams. Results showed that 15N signatures were similar in species of submersed and amphibious macrophytes and in stream water DIN, whereas 15N signatures of the riparian species were not. 15N signatures of macrophytes were generally closer to 15N signatures of nitrate, regardless of the species considered. Our results showed significant relationships between 15N signatures of DIN and those of submersed Callitriche stagnalis and amphibious Veronica beccabunga and Apium nodiflorum, suggesting stream water DIN as a relevant N source for these two functional groups. Moreover, results from a mixing model suggested that stream water DIN taken up by the submersed and amphibious species was mostly in the form of nitrate. Together, these results suggest different contribution to in-stream N uptake among the spatially-segregated species of macrophytes. While submersed and amphibious species can contribute to in-stream N uptake by assimilation of DIN, macrophyte species located at stream channel edges do not seem to rely on stream water DIN as an N source. Ultimately, these results add a functional dimension to the current use of macrophytes for the restoration of stream channel morphology, indicating that they can also contribute to reduce excess DIN in streams. 相似文献
4.
Experimental melting relationships for a mafic minette (mica-lamprophyre) from Buell Park, Arizona were determined under fO2 conditions equivalent to the ironwüstite-graphite and quartz-fayalite-magnetite buffers, at pressures of 10–20 kbar. A comparison between experimental products and phenocrysts in the most primitive minettes indicates that those lavas preserve a near-liquidus assemblage of olivine, diopside and Ti-rich phlogopite crystallized in the upper mantle under fO2QFM and in the presence of an H2O-bearing fluid phase. It is suggested that micalamprophyric (minette) magmas may originate from a metasomatized, garnet-bearing peridotitic source at deeper levels in the mantle (P20 kbar) but can also be in equilibrium with a phlogopite-bearing wehrlite (±opx) source at pressures of 17–20 kbar, under reducing or oxidizing mantle conditions. Owing to their rapid crystallization rate and high liquidus temperatures, a series of potassic daughter melts (potassic latites and felsic minettes) can be formed by segregation from mafic minette parents during their ascent through the cooler continental crust. The preservation of olivine in equilibrium with phlogopite phenocrysts in primitive minettes precludes a petrogenetic process dominated by assimilation/fractional crystallization in a shallow magma chamber and supports a model by which some lamprophyric magmas are brought to near surface conditions at temperatures in the range of 1,000–1,200° C and chilled rapidly. 相似文献
5.
Violante-Carvalho Nelson Skvortsov Alexei Babanin Alexander Pereira Henrique Pinho Uggo Esperança Paulo T. T. 《Ocean Dynamics》2021,71(3):379-389
Ocean Dynamics - Dispersion of a passive tracer by water waves is of significant importance for many scientific and technological problems including bio-diversity of marine life, ecological impact... 相似文献
6.
S. Esperança G. M. Crisci R. de Rosa R. Mazzuoli 《Contributions to Mineralogy and Petrology》1992,112(4):450-462
Volcanic rocks on the island of Lipari show the entire range of Sr, Nd, Pb isotopic compositions displayed by other islands in the Aeolian archipelago. The rapid isotopic evolution of subaerial volcanic rocks on Lipari towards crustal values together with the appropriate isotopic composition of the neighbouring Calabrian crust (Serre) indicate that many geochemical characteristics observed in the lavas can be attributed to contamination and mixing with crustal materials and melts. Interpretation of the data is complicated by the fact that underplating onto the crust-mantle boundary and the specific lithologies present in the crustal section differ underneath each individual sector of the island. In the central and northern parts of the island, metapelitic rocks were incorporated to provide the more radiogenic Sr isotopic compositions of some lavas. The products from M. Guardia in the southern part of Lipari, where activity is restricted to the last 30–40 ka, bear geochemical similarities to the island of Vulcano, where it is proposed that considerable remobilization of the crust took place in the presence of mafic mantle-derived melts. On Lipari the petrogenetic processes of magma mixing and assimilation dominate over fractional crystallization, and the observed increase of K2O over Na2O can be correlated with contributions from metapelitic crustal lithologies. It is suggested that the variability in isotopic composition and the budget of alkalis (Na2O versus K2O) in the lavas can be explained by invoking a heat source from an intruding asthenospheric MORB-type mantle into a cooler lithospheric crust/mantle during the opening of the Tyrrhenian basin. 相似文献
7.
Núria Marbà Carlos M. Duarte Jorge Terrados Zayda Halun Esperança Gacia Miguel D. Fortes 《Estuaries and Coasts》2010,33(1):107-117
We examined the rhizosphere structure of 14 seagrass meadows (seven mixed, three Enhalus acoroides, two Zostera japonica, one Thalassia hemprichii, and one Halophila ovalis) in the Philippines and Vietnam and tested their effect on sediment redox potential by comparing the redox potential in vegetated
vs unvegetated sediments. The effect of seagrass photosynthesis on sediment redox potential was tested in an E. acoroides meadow during a short-term (2-day) clipping experiment. In all the meadows, the centroidal depth (i.e., depth comprising
50%) of seagrass belowground biomass was within the top 15 cm sediment layer. Redox potentials in vegetated sediments tended
to be higher than those in adjacent unvegetated ones; sediment redox potential anomaly ranged from −61 to 133 mV across the
meadows. The centroidal depths of positive redox potential anomaly and seagrass root biomass were significantly correlated
across the meadows investigated (type II regression analysis, slope = 0.90, lower confidence limit [CL] = 0.42 upper CL = 1.82,
R
2 = 0.59, p < 0.01). Experimental removal of E. acoroides leaves resulted in a decrease in rhizosphere redox potential by 20 mV, further confirming the positive effect of seagrass
roots and rhizomes on sediment redox potential and, thus, the general conditions for microbial processes in the coastal zone. 相似文献
8.
Núria Marbà Carlos M. Duarte Elena Díaz-Almela Jorge Terrados Elvira Álvarez Regino Martínez Rocío Santiago Esperança Gacia Antoni M. Grau 《Estuaries and Coasts》2005,28(1):53-62
Direct census of shoots tagged in permanent plots was used to assess the present (2000–2002)Posidonia oceanica population dynamics in 25 meadows along the Spanish Mediterranean Coast. Shoot density ranged from 154±8 to 1,551±454 shoots
m−2, absolute shoot mortality from 5±0 to 249±53 shoots m−2 yr−1, and absolute shoot recruitment from <5 ±1 to 62±42 shoots m−2yr−1. Specific shoot mortality and recruitment rates, which are mathematically and statistically (p>0.05) independent of shoot
density, varied from 0.015±0.006 to 0.282±0.138 yr−1 and 0.018±0.005 to 0.302±0.093 yr−1, respectively. Absolute shoot mortality rate was scaled to shoot density (Pearson correlation, r=0.78, p<0.0001), and variability
in specific shoot recruitment rate was partially due to differences in the percentage of growing apexes, which produce most
of the recruits within the population (Pearson correlation, r=0.50, p<0.001), demonstrating the existence of structural constraints
on shoot demography. Shoot half-life was estimated to range from 2.5 to 60.4 yr and meadow turnover times between 6.7 yr and
more than a century, provided current estimates of shoot mortality, recruitment rates, and density remain uniform. There were
differences in shoot mortality and recruitment at the regional scale, with the meadows developing along the coast of the Spanish
mainland experiencing the highest shoot mortality (Tukey test, p<0.05) and tending to exhibit the highest shoot recruitment.
The low shoot recruitment did not balance shoot mortality in most (60%) of the meadows, showing a prevalence of declining
populations among the 25 meadows studied (Wilcoxon ranked sign test, p<0.0005). This study demonstrates the power of direct
census of seagrass shoots in permanent plots to evaluate the present status of seagrass meadows, to detect on-going population
decline, and to provide some insight onto the possible factors involved. The incorporation of direct census of seagrass meadows
to monitoring programs will help provide the early-warning signals necessary to support management decisions to conserve seagrass
meadows. 相似文献
9.
R. W. Carlson S. Esperança D. P. Svisero 《Contributions to Mineralogy and Petrology》1996,125(4):393-405
During the late Mesozoic, an unusually broad range of alkalic magma compositions was erupted along the southern border of the São Francisco craton of Brazil. This magmatic activity includes carbonatite, kimberlite, lamprophyre, lamproite, syenite and the largest known example of extrusive kamafugite, the Mata da Corda formation. To determine the nature of the sources of this magmatism, and their geochemical history, an Os isotope study along with major and trace element and Sr, Nd and Pb isotope analyses of kimberlitic, lamproitic and kamafugitic rocks from the Alto Paranaíba province of Brazil was undertaken. This complements recent geochemical and isotopic studies of these magmas. The Os isotope data for Alto Paranaíba samples point to a peridotitic lithospheric mantle source for the kimberlites and lamproites that was variably depleted in Re, presumably by melt removal at some time between the late Archean and mid-Proterozoic. These lithospheric peridotites experienced LIL-element enrichment by fluid/melt metasomatism at roughly 1 Ga, most likely during mobile belt formation along the western border of the São Francisco craton. Kamafugitic samples have very radiogenic Os, suggestive of mafic (e.g. pyroxenite, websterite, eclogite) source materials that again appear to have been stabilized in the lithospheric mantle of Brazil in the mid to late Proterozoic. The Os isotope evidence for lithospheric sources for the Alto Paranaíba activity, coupled with Sr, Nd and Pb isotopic characteristics that overlap those of the Walvis Ridge hot-spot trace indicate that the EM1 component in South Atlantic ocean island basalts most likely represents the influence of delaminated Brazilian lithospheric mantle mixed into mantle circulation beneath the South Atlantic and is not related to the plume(s) commonly associated with this ocean island magmatism. 相似文献
10.
The geochemical characteristics of primitive tholeiitic and alkaline volcanic rocks that erupted in the Plio-Pleistocene
along fissures on the Hyblean plateau in Sicily (Italy) were used to constrain the mantle sources involved in the volcanic
activity of this area of the Mediterranean. It is shown that some of the Hyblean plateau magmas with the most extreme isotopic
compositions have combined radiogenic Nd, Sr and Pb, a feature that is distinct from the mixing end-members of the oceanic
array. In addition, alkalinity in the basalts is found to be positively correlated with an increase in some HFSE ratios (e.g.
Nb/Ta, Zr/Hf) and negatively correlated with ratios between HFSE and MREE (e.g. Ti/Eu), a characteristic that is attributed
to a mantle source that has been modified by a carbonatitic metasomatic agent. This metasomatic enrichment had the effect
of increasing the U/Pb of portions of the lower lithosphere, possibly by adding phases such as sodic pyroxene and apatite
to the basalt-depleted lithosphere. It is suggested that rock types that formed by melting metasomatized portions of lithosphere-asthenosphere
boundary affected by this recent enrichment in U/Pb fall along a trend with a shallow slope in a plot of 206Pb/204Pb versus 207Pb/204Pb, and have Nd isotopic compositions that are as radiogenic as present day MORB. The isotopic compositions and trace-element
concentrations of the Hyblean plateau basalts are, therefore, mostly consistent with the interaction of a MORB-type mantle
source with a young lithosphere that was probably formed in the Phanerozoic and metasomatized by CO2-rich fluids, possibly during the Jurassic. The absence of a geochemical component indicative of involvement of older Proterozoic
lithosphere and continental crust in the evolution of these magmas distinguishes them from those erupted along the margins
of the Tyrrhenian sea, and supports the suggestion that at least portions of the lithosphere underneath Sicily have oceanic
affinity and may be genetically related to the adjacent Ionian abyssal plain.
Received 4 June 1997 / Accepted 25 November 1997 相似文献