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When this article was originally published 相似文献
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Chantal Guillard Hervé Delprat Can Hoang-van Pierre Pichat 《Journal of Atmospheric Chemistry》1993,16(1):47-59
The photodegradation of naphthalene (NPH), chosen as a model of polynuclear aromatic pollutants, has been studied in the presence of a layer of four water-insoluble inorganic solids which can be found in the troposphere (TiO2, Fe2O3, muscovite, and a fly ash sample). Direct photolysis of NPH is negligible at >340 nm. Dark adsorption of NPH on TiO2 (mainly anatase, nonporous, 50 m2 g–1) at 293 K corresponds to a surface coverage ofca. 50% at equilibrium. Under these conditions (saturated surface), the stationary-state photocatalytic degradation reaches 0.4 molecule nm–2 h–1 (>340 nm, radiant fluxca. 22 mW cm–2). Dioxygen is required and its partial pressure in air is such that the degradation is zero order in O2. Water vapor markedly increases the rate. The other particulates have also an effect, less important than that of TiO2, however quite noticeable with respect to surface area unit for the fly ash sample which contains 3.2% Fe2O3. Apart from 1,4-naphthoquinone, which is the main intermediate product in all cases, 2-naphthol, phthalide, phthaldialdehyde, phthalic acid, acetophenone, benzaldehyde, benzoic acid are also formed on dry TiO2. Depending on their volatility, these compounds are transferred to the gas phase or remain principally adsorbed on the solid particles where they are further transformed. For instance, phthalic acid (or anhydride) and benzoic acid are generated from 1,4-naphthoquinone. Degradation mechanisms are briefly discussed. 相似文献
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Acta Geotechnica - Dynamic loading experiments of single glass bead cement-covered by epoxy resins of different compositions demonstrate the existence of diverse fracture patterns under similar... 相似文献
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F. E. Grousset C. R. Quetel B. Thomas O. F. X. Donard C. E. Lambert F. Guillard A. Monaco 《Marine Chemistry》1995,48(3-4)
The distribution of heavy metal was analyzed in water column particles collected in autumn (October 1985) and spring (March 1986) by two series of sediment traps from a mooring located in the northeastern Mediterranean Sea continental slope. Four traps were set, at 50, 100, 300, 600 m depths on the mooring in 645 m deep water in the Lacaze-Duthier canyon. The total metal concentrations were determined by ICP-MS. Results show that Rb and Sc contents display typical shale values. As, Cd, Pb, Sb, Zn (normalized to Sc) display high enrichment factors (up to 50) over shale compositions. Distinctive temporal variability as well as the respective contributions of local (Têt, Aude) and remote (Rhône) rivers and Sahara-derived aerosols have been identified. Fluxes of most elements observed in the upper 100 m can be attributed to atmospheric fluxes. In the deepest traps (300 and 600 m) these fluxes are, however, mostly dominated by riverine particles advected from the continental shelf. Most of the trace-element enrichments are more likely to be related to the anthropogenic input rather than to biological cycling. Isotopic composition of lead determined by ICP-MS enabled to evaluate that the proportion of anthropogenic lead derived from European gasoline consumption ranged between 50 and 100%. 相似文献
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Patrice Brehmer Jean Guillard Pablo I. Caballero Pinzon Pascal Bach 《Estuaries and Coasts》2011,34(4):739-744
Fish school swimming speeds is essential for ecological and management studies. The multibeam sonar in horizontal beaming
provided dynamic echo traces of mobile fish schools. We used two school swimming speed indicators: the average of a series
of instantaneous speed values, and the exploratory speed. These swimming speeds were estimated for each fish school observed
on the basis of their Euclidian position within the sonar beams. The average ISS values per school ranged from 0.15 m s−1 to 4.46 m s−1, while the ESS values per school were lower, ranging from 0.04 m s−1 to 3.77 m s−1. Multibeam sonar technology makes it possible to measure fish school swimming speeds in their natural habitat at small spatio-temporal
scales. This methodology can therefore be used to analyse in situ their movements, and has a wide range of applications in
behavioural studies and management purposes. 相似文献
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