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1.
In the northwestern margin of the Clarion and Clipperton fracture zones, manganese nodules are latitudinally variable in character, resulting from the progressive (re)generation of nodules since the Oligocene as the Pacific Plate migrates northwestward beneath the equatorial production zone. Complemented by the surface water productivity, bottom current activities have concentrated nodules in the Oligocene to Miocene siliceous clay. Resedimentation processes on nodules form three types of nodules with concentric structures and 10 Å-manganaterich bottoms, by periodically causing the diagenetic growth of nodules within the topmost sediment layer.  相似文献   
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Biotite is widely used for Rb-Sr and K-Ar isotopic dating and influences Sr isotope geochemistry of hydrological regimes. The isotopic system of biotite behaves diversely in response to surface weathering; i.e. the complete preservation of original Rb-Sr and K-Ar isotopic ages or dramatic reduction. In this study, we have explored the relation between the behavior of isotopic systems and complex weathering processes of biotites in the weathering profiles distributed on the Mesozoic granitoids in South Korea. In the lower parts of the profiles, biotite in the early stages of weathering was transformed into either oxidized biotite or hydrobiotite, with a mass release of 87Sr and 40Ar forced by the rapid oxidation of ferrous iron. During the transformation to oxidized biotite, 87Sr and 40Ar were preferentially released relative to Rb and K, respectively, via solid-state diffusion through the biotite lattice, resulting in a drastic reduction of original isotopic age. The reduction of Rb-Sr age was greater than that of K-Ar age because K was preferentially released over Rb whereas 87Sr and 40Ar were released proportionally to each other. However, during the transformation of biotite to hydrobiotite (i.e., to regularly interstratified biotite-vermiculite), 87Sr, Rb, 40Ar, and K were completely retained in the alternating biotite interlayer, and thus the original isotopic age can be preserved. In the upper parts of the profiles, where iron oxidation was almost completed, 87Sr, Rb, 40Ar, and K were gradually and proportionally released, with no further significant change in isotopic age during the gradual transformation of the early-formed oxidized biotite into hydrobiotite and vermiculite or during their final decomposition to kaolinite. The ratios and amounts of isotopes released from weathered biotites are dependent upon the degree of iron oxidation and the pathways of mineralogical transformation. Regional and local variations in isotopic systems affected by particular weathering processes should be considered when dating biotite or biotite-bearing rocks in weathering environments, modeling the transfer of Sr isotopes to hydrologic regimes, and tracking the provenance of sediments.  相似文献   
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Rare earth elements (REEs: La-Lu) in surface sediments collected from the mouth and middle tidal flats of Gomso Bay, South Korea, in August 2011 and May 2012 were analyzed to investigate the fine-grained sediment provenance. The upper continental crust (UCC)-normalized light REEs (LREEs: La to Nd) were more enriched than the middle REEs (MREEs: Sm to Dy) and heavy REEs (HREEs: Ho to Lu), resulting in large (La/Yb)UCC (1.9 ± 0.4) to (Gd/Yb)UCC (1.4 ± 0.2) ratios. The monthly (La/Yb)UCC values differed between the mouth and middle tidal flats due to deposition of fine-grained sediments that originated from distant rivers (the Geum and Yeongsan) and the Jujin Stream, located on the southern shore of the inner bay. We observed relative reductions in the (La/Yb)UCC value and REE content in the sediments from the mouth of the bay compared with those from Jujin Stream sediments. Confined to the middle tidal flat around the KH Line of Jujin Stream, the sediments, most enriched in LREEs but depleted in Eu, were distributed in August as strong Jujin Stream runs. Here, we suggest that an increase in LREE/HREE and decrease in MREE/LREE ratios can be used as a proxy to identify the Jujin Stream provenance in mixed riverine sediments and to trace Jujin Stream sediments within the Gomso Bay tidal flat, especially in the summer rainy season.  相似文献   
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In this article, the possibility of sharing rain barrels and the potential benefit of reducing storage size through physical and non‐physical connections of rain barrels in a community are investigated. Using the concepts of homogeneous/heterogeneous users in rainwater harvesting systems (RWHS), two simple cases of a community composed of four prospective users are examined. The first is performed with the users who have the same mean and variance in water demands (homogeneous users), and the second is with the users with different means and variances (heterogeneous users). To take account for the rainfall characteristics in different places, historical records from six cities in the USA are used for storage–reliability–yield analysis. The result indicates that required total storage can be reduced by connecting multiple rain barrels. In addition, a significant difference is found between homogeneous and heterogeneous user groups. Homogeneous users do not achieve a substantial benefit from connecting their rain barrels; these users may even be disadvantaged by sharing. In contrast, heterogeneous users receive benefit by reducing the total required storage. Most benefit is expected between users with maximum difference in mean water demands. The reduction in storage size was as considerable as 37% in this study. The quantity of storage reduction depends on locations and target reliabilities. Knowledge of the benefits and limitations of rain barrel connections can improve RWHS performance through ability to customize a network plan for individual users. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
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Periodicites in hydrologic data are frequently estimated and studied. In some cases the periodic components are subtracted from the data to obtain the stochastic components. In other cases the physical reasons for the occurrence of these periodicities are investigated. Apart from the annual cycle in the hydrologic data, periods corresponding to the 11 year sunspot cycle, the Hale cycle and others have been detected.The conclusions from most of these studies depend on the reliability and robustness of the methods used to detect these periodicities. Several spectral analysis methods have been proposed to investigate periodicities in time series data. Several of these have been compared to each other. The methods by Siddiqui and Wang and by Damsleth and Spjotvoll, which are stepwise procedures of spectrum estimation, have not been evaluated.  相似文献   
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The effect of weathering on optically stimulated luminescence dating   总被引:2,自引:0,他引:2  
Optically stimulated luminescence (OSL) dating was applied to quartz samples recovered from the gravel sediments of deformed marine terrace at the Suryum site, southeastern Korea, but has yielded stratigraphically inconsistent ages. Micromorphological, chemical, and mineralogical analyses of the gravels indicate the possible influence of chemical weathering on the apparent OSL ages. In the course of weathering after emerging from beach environments, originally permeable gravels underwent infilling by halloysite-rich clays in their voids, export and import of radioactive elements, and loss of mechanical strength with the creation of a porosity within pebbles. Calculation based on the evolution of the weathering profile showed a severe fluctuation of dose rate caused by the change of water content and radioactive element concentrations. Samples recovered from the weathering profile inevitably include quartz grains derived from mechanically weakened pebbles or illuviated from the upper layer, making it difficult to determine the equivalent dose (De) values of exclusively depositional quartz sands. Quantitative evaluation of the change of fabric and chemistry of the sediments on the basis of pedologic insight significantly aids in the derivation of OSL ages consistent with geomorphology and other independent age controls.  相似文献   
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