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LI  Yanbao 《中国海洋工程》2002,16(2):211-218
In this paper, the theoretical analysis and experimental studies are employed to investigate the reflection characteris-tics of partial standing waves caused by wave overtopping and sloping top of structures. Based on the principle of conser-vation of wave energy flux, the third-order Stokes wave theory is used to formulate the reflection coefficient at wave overtopping; the calculation results are regressed into an applied expression. A series of experiments of wave reflection for a vertical-wall structure with chamfered and overhanging upper sections are carried out to investigate the influence of top slope on wave reflection. The regularity of variation of wave reflection in this case is analysed based on the experimental results.  相似文献   
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The linear thermal expansions of åkermanite (Ca2MgSi2O7) and hardystonite (Ca2ZnSi2O7) have been measured across the normal-incommensurate phase transition for both materials. Least-squares fitting of the high temperature (normal phase) data yields expressions linear in T for the coefficients of instantaneous linear thermal expansion, $$\alpha _1 = \frac{1}{l}\frac{{dl}}{{dT}}$$ for åkermanite: $$\begin{gathered} \alpha _{[100]} = 6.901(2) \times 10^{ - 6} + 1.834(2) \times 10^{ - 8} T \hfill \\ \alpha _{[100]} = - 2.856(1) \times 10^{ - 6} + 11.280(1) \times 10^{ - 8} T \hfill \\ \end{gathered} $$ for hardystonite: $$\begin{gathered} \alpha _{[100]} = 15.562(5) \times 10^{ - 6} - 1.478(3) \times 10^{ - 8} T \hfill \\ \alpha _{[100]} = - 11.115(5) \times 10^{ - 6} + 11.326(3) \times 10^{ - 8} T \hfill \\ \end{gathered} $$ Although there is considerable strain for temperatures within 10° C of the phase transition, suggestive of a high-order phase transition, there appears to be a finite ΔV of transition, and the phase transition is classed as “weakly first order”.  相似文献   
4.
Wadsleyite (β-(Mg,Fe)2SiO4) is a major constituent of the Earth's transition zone and is known to accommodate OH. The portion of the transition zone between 400–550 km could be an important source or sink for hydroxyl in plumes and slabs intersecting this region. Micro-infrared spectroscopy has been carried out on the β-phase and coexisting metastable olivine synthesized in a multianvil apparatus at 14 GPa and 1550–1650 K under hydrous conditions. Single-crystal and polycrystal specimens of both phases were analyzed in the 1800–8500 cm?1 frequency region to determine the speciation, abundances, and partitioning behavior of the hydrous components in coexisting β-phase and olivine. β-phase spectra consistently show three distinct OH bands at 3329, 3580, and 3615 cm?1. OH concentrations range from 10000–65000 H/106 Si. A strong positive correlation of grain size and extent of transformation with OH concentration in the β-phase indicates that grain-growth and transformation rates are enhanced in a hydrous environment. Olivine spectra are variable, but consistently show a prominent broad-band absorbance representing molecular H2O, consistent with the infrared signature of the starting material. OH concentrations in olivine range from <300–1400 H/106 Si. The highest OH concentrations measured for olivine and the β-phase may represent solubility limits, in which case the OH solubility ratio between these two phases is approximately 1∶40. Where both phases coexist and are undersaturated with OH, the partitioning ratio of OH between them is about 1∶100. The large solubility contrast between olivine and the β-phase suggests a mechanism for hydrating the transition zone via olivine carried down in subducting slabs. Plumes impinging on an OH-rich upper transition region could cause H2 or H2O to be released upon transformation of the β-phase to olivine, resulting in initiation of secondary upwellings. If dissolution of OH weakens the β-phase, and if OH is present in the mantle, the region between 400–550 km could be a zone of low viscosity.  相似文献   
5.
The Great Lakes Environmental Research Laboratory has developed conceptual daily models for simulating moisture storages in and runoff from the 121 watersheds draining into the Laurentian Great Lakes, over-lake precipitation into each lake, and the heat storages in and evaporation from each lake. We combine these components as net basin supplies for each lake to consider climate change scenarios developed from atmospheric general circulation models (GCMs). Recent scenarios of a doubling of atmospheric Co2, available from the Goddard Institute for Space Studies, the Geophysical Fluid Dynamics Laboratory, and Oregon State University are considered by making changes in historical meteorological data similar to the changes observed in the GCMs, observing the impact of the changed data in the model outputs, and comparing outputs to model results using unchanged data, representing comparison to an unchanged atmosphere. This study indicates a 23 to 51% reduction in net basin supplies to all the Great Lakes; there is significant variation in the components of these supplies among the three GCMs. The basins various moisture storages become dryer and the lakes are warmer with associated hydrological impacts.GLERL Contribution NO. 646.  相似文献   
6.
NiAl2O4 is a largely inverse spinel, which in detail shows increasing randomisation with temperature of Ni and Al between the octahedral and tetrahedral cation sites of the spinel structure. We have used powder XRD to determine this cation distribution in various samples of NiAl2O4 quenched after annealing between 700 and 1400° C. The inversion parameter (x) can be measured with a precision of ± 0.004 (one standard deviation), and a comparison of different methods of synthesis, X-ray diffraction and refinement techniques, suggests a probable accuracy of better than 0.01. The results are supported by some preliminary single crystal refinements on flux-grown samples.Below 800° C the rate of cation ordering becomes very slow, and, despite reaching an apparently steady state, it is doubtful if our samples attained complete internal equilibrium. Above 1250° C the cation redistribution becomes so fast that the quenching method becomes unreliable. Between 800 and 1250° C inclusive, the degree of inversion changes smoothly from 0.87 at 800° C to 0.79 at 1250° C, and is accompanied by linear changes in u, the oxygen parameter, from 0.2555 to 0.2563 (±0.0002), and a0, the lattice parameter, from 8.0462 to 8.0522 Å (±0.0002 Å).  相似文献   
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PAH exposure was assessed in fish from Arthur Harbor, Antarctica and sites remote from human activities by measuring the concentrations of polycyclic aromatic hydrocarbon (PAH) metabolites in bile and PAH in tissues and stomach contents. The highest concentrations of biliary metabolites and tissue PAH were present in fish captured near an Argentine supply ship (Bahia Paraiso) that ran aground in Arthur Harbor in 1989. The presence of biliary PAH metabolites in fish collected near Palmer Station, a small US scientific station in Arthur Harbor, suggests low level exposure to contaminants. However, PAH tissue concentrations in fish from Palmer Station were similar to those from remote sites. Both tissue PAH and metabolite concentrations were low in fish captured at sites remote from human activities. The confirmation of PAH metabolites in the bile of fish from Arthur Harbor is direct evidence that the presence of humans has resulted in Antarctic fish being exposed to petroleum-derived PAH.  相似文献   
9.
An important problem in sedimentation analysis is the development of a channel section that preserves, as best as possible, the current sedimentation regime even though the flood frequency tendencies have been altered due to land development within the catchment. In order to accomplish this task, a methodology is needed that estimates sediment transport capacity for various channel configurations. Such a procedure is described which allows the computation of the total sediment transport capacity for each of several T-year return frequency runoff hydrographs. This information is used to obtain an approximate probability distribution for the total sediment transport capacity, and the mean and standard deviation of this distribution are computed.Comparing the results for the catchment in its present state with a future developed state, using a selection of new channel parameters, indicates how to improve the channel to control changes in sedimentation due to development. The analysis procedure provides a basis for estimating a new channel configuration such that the new flow conditions retain, as best as possible, the existing condition sedimentation effects, and hence retain the natural sediment supply and transport trends even though runoff flow rates have changed due to land development within the catchment.The results of Wilson Creek are typical of the several sites examined, see Table 3 below. The T=2, T=5, T=25, and T=100 year values for total sediment transport capacity, in kilotons, are 6.9, 39.4, 61.3, and 96.7 with a mean of 17.1 and standard deviation of 19.3. After development with no change in the channel the respective values increase to: 17.9, 84.6, 128.1, and 258.0 with a mean of 39.1 and standard deviation of 44.3. A new channel can be constructed which will reduce these sediment transport capacity values, after development, to 5.2, 41.0, 62.0, and 124.8 with a mean of 17.4 and standard deviation of 22.0.  相似文献   
10.
Hydrological models of the Great Lakes basin were used to study the sensitivity of Great Lakes water supplies to climate warming by driving them with meteorological data from four U.S. climate zones that were transposed to the basin. Widely different existing climates were selected for transposition in order to identify thresholds of change where major impacts on water supplies begin to occur and whether there are non-linear responses in the system. The climate zones each consist of 43 years of daily temperature and precipitation data for 1,000 or more stations and daily evaporation-related variables (temperature, wind speed, humidity, cloud cover) for approximately 20–35 stations. A key characteristic of these selected climates was much larger variability in inter-annual precipitation than currently experienced over the Great Lakes. Climate data were adjusted to simulate lake effects; however, a comparison of hydrologic results with and without lake effects showed that there was only minor effects on water supplies.  相似文献   
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