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1.
Accurate simulations and predictions of urban expansion are critical to manage urbanization and explicitly address the spatiotemporal trends and distributions of urban expansion. Cellular Automata integrated Markov Chain (CA-MC) is one of the most frequently used models for this purpose. However, the urban suitability index (USI) map produced from the conventional CA-MC is either affected by human bias or cannot accurately reflect the possible nonlinear relations between driving factors and urban expansion. To overcome these limitations, a machine learning model (Artificial Neural Network, ANN) was integrated with CA-MC instead of the commonly used Analytical Hierarchy Process (AHP) and Logistic Regression (LR) CA-MC models. The ANN was optimized to create the USI map and then integrated with CA-MC to spatially allocate urban expansion cells. The validated results of kappa and fuzzy kappa simulation indicate that ANN-CA-MC outperformed other variously coupled CA-MC modelling approaches. Based on the ANN-CA-MC model, the urban area in South Auckland is predicted to expand to 1340.55 ha in 2026 at the expense of non-urban areas, mostly grassland and open-bare land. Most of the future expansion will take place within the planned new urban growth zone.  相似文献   
2.
Meteorological time-series data are a fundamental input to hydrological investigations. But sourcing data is often laborious and plagued with difficulties. In an effort to improve efficiency and rigor we present an R-package, named AWAPer ( https://github.com/peterson-tim-j/AWAPer ), for the efficient estimation of daily area weighted catchment average and spatial variance of meteorological variables, including evapotranspiration. The package allows creation and updating of a data-cube of gridded daily data from 1900 onwards. Once created, point and area weighted estimates can be extracted at user-defined locations and time periods for anywhere within Australia. Examples of point and catchment average extraction are presented.  相似文献   
3.
Garnet crystals with quartz inclusions were hydrothermally crystallized from oxide starting materials in piston–cylinder apparatuses at pressures from 0.5 to 3 GPa and temperatures ranging from 700 to 800 °C to study how entrapment conditions affect remnant pressures of quartz inclusions used for quartz-in-garnet (QuiG) elastic thermobarometry. Systematic changes of the 128, 206 and 464 cm?1 Raman band frequencies of quartz were used to determine pressures of quartz inclusions in garnet using Raman spectroscopy calibrations that describe the P–T dependencies of Raman band shifts for quartz under hydrostatic pressure. Within analytical uncertainties, inclusion pressures calculated for each of the three Raman band frequencies are equivalent, which suggests that non-hydrostatic stress effects caused by elastic anisotropy in quartz are smaller than measurement errors. The experimental quartz inclusions have pressures ranging from ??0.351 to 1.247 GPa that span the range of values observed for quartz inclusions in garnets from natural rocks. Quartz inclusion pressures were used to model P–T conditions at which the inclusions could have been trapped. The accuracy of QuiG thermobarometry was evaluated by considering the differences between pressures measured during experiments and pressures calculated using published equation of state parameters for quartz and garnet. Our experimental results demonstrate that Raman measurements performed at room temperature can be used without corrections to estimate garnet crystallization pressures. Calculated entrapment pressures for quartz inclusions in garnet are less than ~?10% different from pressures measured during the experiments. Because the method is simple to apply with reasonable accuracy, we expect widespread usage of QuiG thermobarometry to estimate crystallization conditions for garnet-bearing silicic rocks.  相似文献   
4.
Analyses (n = 525) of chloride (Cl), bromide (Br), nitrate as nitrogen (NO3-N), sodium (Na+), calcium (Ca2+) and potassium (K+) in stream water, tile-drain water and groundwater were conducted in an urban-agricultural watershed (10% urban/impervious, 87% agriculture) to explore potential differences in the signature of Cl originating from an urban source as compared with an agricultural source. Only during winter recharge events did measured Cl concentrations exceed the 230 mg/L chronic threshold. At base flow, nearly all surface water and tile water samples had Cl concentrations above the calculated background threshold of 18 mg/L. Mann–Whitney U tests revealed ratios of Cl to Br (p = .045), to NO3-N (p < .0001), to Ca2+ (p < .0001), and to Na+ (p < .0001) to be significantly different between urban and agricultural waters. While Cl ratios indicate that road salt was the dominant source of Cl in the watershed, potassium chloride fertilizer contributed as an important secondary source. Deicing in watersheds where urban land use is minimal had a profound impact on Cl dynamics; however, agricultural practices contributed Cl year-round, elevating stream base flow Cl concentrations above the background level.  相似文献   
5.
A newly discovered, extensive sphalerite-bearing breccia (~7.5 wt.% Zn) is hosted in dolomitised Carboniferous limestones overlying Ordovician–Silurian metasedimentary rocks on the Isle of Man. Although base metal sulphide deposits have been mined historically on the island, they are nearly all quartz vein deposits in the metamorphic basement. This study investigates the origin of the unusual sphalerite breccia and its relationship to basement-hosted deposits, through a combination of petrographic, cathodoluminescence, fluid inclusion, stable isotope and hydrogeologic modelling techniques. Breccia mineralisation comprises four stages, marked by episodes of structural deformation and abrupt changes in fluid temperature and chemistry. In stage I, high-temperature (T h > 300°C), high-salinity (20–45 wt.% equiv. NaCl) fluid of likely basement origin deposited a discontinuous quartz vein. This vein was subsequently dismembered during a major brecciation event. Stages II–IV are dominated by open-space filling sphalerite, quartz and dolomite, respectively. Fluid inclusions in these minerals record temperatures of ~105–180°C and salinities of ~15–20 wt.% equiv. NaCl. The δ34S values of sphalerite (6.5–6.9‰ Vienna-Canyon Diablo troilite) are nearly identical to those of ore sulphides from mines in the Lower Palaeozoic metamorphic rocks. The δ18O values for quartz and dolomite indicate two main fluid sources in the breccia’s hydrothermal system, local Carboniferous-hosted brines (~0.5–6.0‰ Vienna standard mean ocean water) and basement-involved fluids (~5.5–11.5‰). Ore sulphide deposition in the breccia is compatible with the introduction and cooling of a hot, basement-derived fluid that interacted with local sedimentary brines.  相似文献   
6.
Evidence from shoreline and deep-lake sediments show Laguna Cari-Laufquén, located at 41°S in central Argentina, rose and fell repeatedly during the late Quaternary. Our results show that a deep (> 38 m above modern lake level) lake persisted from no later than 28 ka to 19 ka, with the deepest lake phase from 27 to 22 ka. No evidence of highstands is found after 19 ka until the lake rose briefly in the last millennia to 12 m above the modern lake, before regressing to present levels. Laguna Cari-Laufquén broadly matches other regional records in showing last glacial maximum (LGM) highstands, but contrasts with sub-tropical lake records in South America where the hydrologic maximum occurred during deglaciation (17–10 ka). Our lake record from Cari-Laufquén mimics that of high-latitude records from the Northern Hemisphere. This points to a common cause for lake expansions, likely involving some combination of temperature depression and intensification of storminess in the westerlies belt of both hemispheres during the LGM.  相似文献   
7.
While many coastal ecosystems previously supported high densities of seagrass and abundant bivalves, the impacts of overfishing, eutrophication, harmful algal blooms, and habitat loss have collectively contributed to the decline of these important resources. Despite improvements in wastewater treatment in some watersheds and subsequent reduced nutrient loading to neighboring estuaries, seagrass and bivalve populations in these locations have generally not recovered. We performed three mesocosm experiments to simultaneously examine the contrasting effects of nutrient loading and historic suspension-feeding bivalve densities on the growth of eelgrass (Zostera marina), juvenile bivalves (northern quahogs, Mercenaria mercenaria; eastern oysters, Crassostrea virginica; and bay scallops, Argopecten irradians), and juvenile planktivorous fish (sheepshead minnow, Cyprinodon variegatus). High nutrient loading rates led to significantly higher phytoplankton (chlorophyll a) levels in all experiments, significantly increased growth of juvenile bivalves relative to controls with lower nutrient loading rates in two experiments, and significantly reduced the growth of eelgrass in one experiment. The filtration provided by adult suspension feeders (M. mercenaria and C. virginica) significantly decreased phytoplankton levels in all experiments, significantly increased light penetration and the growth of eelgrass in one experiment, and significantly decreased the growth of juvenile bivalves and fish in two experiments, all relative to controls with no filtration from adult suspension feeders. These results demonstrate that an appropriate level of nutrient loading can have a positive effect on some estuarine resources and that bivalve filtration can mediate the effects of nutrient loading to the benefit or detriment of different estuarine resources. Future ecosystem-based approaches will need to simultaneously account for anthropogenic nutrient loading and bivalve restoration to successfully manage estuarine resources.  相似文献   
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Soil is a vital part of the natural environment and is always responding to changes in environmental factors, along with the influences of anthropogenic factors and land use changes. The long-term change in soil properties will result in change in soil health and fertility, and hence the soil productivity. Hence, the main aim of this paper focuses on the analysis of land use/land cover (LULC) change pattern in spatial and temporal perspective and to present its impact on soil properties in the Merawu catchment over the period of 18?years. Post classification change detection was performed to quantify the decadal changes in historical LULC over the periods of 1991, 2001 and 2009. The pixel to pixel comparison method was used to detect the LULC of the area. The key LULC types were selected for investigation of soil properties. Soil samples were analysed in situ to measure the physicochemical soil properties. The results of this study show remarkable changes in LULC in the period of 18?years. The effect of land cover change on soil properties, soil compaction and soil strength was found to be significant at a level of <0.05.  相似文献   
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