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A prominent feature of a granulite-facies shear zone from the Hidaka Main Zone (Japan) is the folding of orthopyroxene (opx) porphyroclasts. Dislocation density estimated by transmission electron microscope (TEM) and chemical etching in homogeneously folded domains is too low to account for the amplitude of crystallographic bending, leading us to propose a model similar to “flexural slip” folding, where folded layers are micrometer-wide opx layers between thin planar clinopyroxene (cpx) exsolutions. Extension (compression) in the extrados (intrados) of the folded layer is accommodated by dislocations at the cpx–opx interfaces. Alternatively to distributed deformation, crystal bending also localizes in grain boundaries (GBs), mostly oriented close to the (001) plane and with various misorientation angles but misorientation axes consistently close to the b-axis. For misorientation up to a few degrees, GBs were imaged as tilt walls composed of regularly spaced (100)[001] dislocations. For misorientation angles of 7°, individual dislocations are no longer visible, but high-resolution TEM (HRTEM) observation showed the partial continuity of opx tetrahedral chains through the boundary. For 21° misorientation, the two adjacent crystals are completely separated by an incoherent boundary. In spite of these atomic-scale variations, all GBs share orientation and rotation axis, suggesting a continuous process of misorientation by symmetric incorporation of (100)[001] dislocations. In addition to the dominant GBs perpendicular to the (100) plane, boundaries at low angle with (100) planes are also present, incorporating dislocations with a component of Burgers vector along the a-axis. The two kinds of boundaries combine to delimit subgrains, which progressively rotate with respect to host grains around the b-axis, eventually leading to recrystallization of large porphyroclasts.  相似文献   
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Sixteen global general circulation models were used to develop probabilistic projections of temperature (T) and precipitation (P) changes over California by the 2060s. The global models were downscaled with two statistical techniques and three nested dynamical regional climate models, although not all global models were downscaled with all techniques. Both monthly and daily timescale changes in T and P are addressed, the latter being important for a range of applications in energy use, water management, and agriculture. The T changes tend to agree more across downscaling techniques than the P changes. Year-to-year natural internal climate variability is roughly of similar magnitude to the projected T changes. In the monthly average, July temperatures shift enough that that the hottest July found in any simulation over the historical period becomes a modestly cool July in the future period. Januarys as cold as any found in the historical period are still found in the 2060s, but the median and maximum monthly average temperatures increase notably. Annual and seasonal P changes are small compared to interannual or intermodel variability. However, the annual change is composed of seasonally varying changes that are themselves much larger, but tend to cancel in the annual mean. Winters show modestly wetter conditions in the North of the state, while spring and autumn show less precipitation. The dynamical downscaling techniques project increasing precipitation in the Southeastern part of the state, which is influenced by the North American monsoon, a feature that is not captured by the statistical downscaling.  相似文献   
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The generation of vapor‐phase contaminant plumes within the vadose zone is of interest for contaminated site management. Therefore, it is important to understand vapor sources such as non‐aqueous‐phase liquids (NAPLs) and processes that govern their volatilization. The distribution of NAPL, gas, and water phases within a source zone is expected to influence the rate of volatilization. However, the effect of this distribution morphology on volatilization has not been thoroughly quantified. Because field quantification of NAPL volatilization is often infeasible, a controlled laboratory experiment was conducted in a two‐dimensional tank (28 cm × 15.5 cm × 2.5 cm) with water‐wet sandy media and an emplaced trichloroethylene (TCE) source. The source was emplaced in two configurations to represent morphologies encountered in field settings: (1) NAPL pools directly exposed to the air phase and (2) NAPLs trapped in water‐saturated zones that were occluded from the air phase. Airflow was passed through the tank and effluent concentrations of TCE were quantified. Models were used to analyze results, which indicated that mass transfer from directly exposed NAPL was fast and controlled by advective‐dispersive‐diffusive transport in the gas phase. However, sources occluded by pore water showed strong rate limitations and slower effective mass transfer. This difference is explained by diffusional resistance within the aqueous phase. Results demonstrate that vapor generation rates from a NAPL source will be influenced by the soil water content distribution within the source. The implications of the NAPL morphology on volatilization in the context of a dynamic water table or climate are discussed.  相似文献   
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We investigated effects of severe hypoxia (dissolved oxygen <1 ml l−1) on recruitment of mantis shrimp Oratosquilla oratoria in Tokyo Bay. Ten-year field surveys were conducted to examine quantitative relationships in annual mean densities of larvae and juveniles, and spatial distribution of juveniles and severe hypoxia. There was no significant correlation between annual mean densities of larvae and juveniles, suggesting that mortality during larval or juvenile stages varies among years, which might have regulated abundance of young-of-the-year juveniles. Juvenile density was low in the severely hypoxic area, implying that hypoxia could affect survivals and spatial distribution of juveniles. Meanwhile, there are yearly fluctuations in juvenile density in normoxic areas of both northern and southern part of the bay. This evidence suggests that abundance of post-settled juveniles might have been determined by not only effects of hypoxia, but also other factors influencing mortality during the early life stages.  相似文献   
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Degassing through open paths such as bubble and/or fracture networks is considered to be the principal mode of degassing in silicic magmas. However, its detailed mechanisms remain unclear. To investigate the behavior of bubbles in a hypothetical open-system condition, we performed a series of vesiculation experiments on natural rhyolitic obsidian using a newly designed semipermeable cell, which artificially maintains a pressure difference between its inside and outside. The thick-wall cell maintains a constant volume within the sample chamber, while allowing water vapor to escape the cell during the experimental runs. The cells containing obsidian cores with ca. 0.66 wt.% initial water content were externally heated to 1000 °C for a period of 1–288 h. The run charges generally showed a zonal structure composed of two contrasting regions: a central region within which the bubbles were concentrated (bubble-rich core, BC) and a bubble-free melt region surrounding the BC (bubble-free margin, BFM). With increased heating duration, the thickness of the BFM increased via dissolution of the outermost bubbles in the BC. The water content was nearly uniform throughout the BC, whereas an outward-decreasing gradient was observed in the BFM. We found that diffusive dehydration occurred from the sample surface, and the bubbles were resorbed into the melt. Thus, the BFM–BC boundary moved inwards. These processes were modelled numerically, and the calculation results were in good agreement with the experimental data. If a “lifetime” of open paths is approximated as the relaxation time of a melt in a shallow volcanic environment, then the paths have to be pinched off quickly (1.2 h at maximum pressure difference between the open path and the melt) and thus the thickness of the bubble-free layer reaches at most ~ 0.1 mm. For the formation of bubble-free obsidian layers with a width of a few millimeters, which are often observed in natural obsidian flows, open paths should be maintained for at least a few hundred hours.  相似文献   
9.
Toshihiro  Ike  Gregory F.  Moore  Shin'ichi  Kuramoto  Jin-Oh  Park  Yoshiyuki  Kaneda  Asahiko  Taira 《Island Arc》2008,17(3):358-375
Abstract   When seamounts and other topographic highs on an oceanic plate are subducted, they cause significant deformation of the overriding plate and may act as asperities deeper in the seismogenic zone. Kashinosaki Knoll (KK) is an isolated basement high of volcanic origin on the subducting Philippine Sea Plate that will soon be subducted at the eastern Nankai Trough. Seismic reflection imaging reveals a thick accumulation of sediments (∼1200 m) over and around the knoll. The lower portion of the sedimentary section has a package of high-amplitude, continuous reflections, interpreted as turbidites, that lap onto steep basement slopes but are parallel to the gentler basement slopes. Total sediment thickness on the western and northern slopes is approximately 40–50% more than on the summit and southeastern slopes of KK. These characteristics imply that the basal sedimentary section northwest of KK was deposited by infrequent high-energy turbidity currents, whereas the area southeast of KK was dominated by hemipelagic sedimentation over asymmetric basement relief. From the sediment structure and magnetic anomalies, we estimate that the knoll likely formed near the spreading center of the Shikoku Basin in the early Miocene. Its origin differs from that of nearby Zenisu Ridge, which is a piece of the Shikoku Basin crust uplifted along a thrust fault related to the collision of the Izu–Bonin arc and Honshu. KK has been carried into the margin of the Nankai Trough, and its high topography is deflecting Quaternary trench turbidites to the south. When KK collides with the accretionary prism in about 1 My, the associated variations in sediment type and thickness around the knoll will likely result in complex local variations in prism deformation.  相似文献   
10.
Temporal changes in nitrogen isotopic composition (δ15N) of the NO3 pool in the water column below the pycnocline in Ise Bay, Japan were investigated to evaluate the effect of nitrification on the change in the δ15N in the water column. The δ15N of NO3 in the lower layers varied from −8.5‰ in May to +8.4‰ in July in response to the development of seasonal hypoxia and conversion from NH4 + to NO3 . The significantly 15N-depleted NO3 in May most likely arose from nitrification in the water column. The calculated apparent isotopic discrimination for water column nitrification (ɛnit = δ15Nsubstrate − δ15Nproduct) was 24.5‰, which lies within the range of previous laboratory-based estimates. Though prominent deficits of NO3 from hypoxic bottom waters due to denitrification were revealed in July, the isotopic discrimination of denitrification in the sediments was low (ɛdenit = ∼1‰). δ15NNO3 in the hypoxic lower layer mainly reflects the isotopic effect of water column nitrification, given that water column nitrification is not directly linked with sedimentary denitrification and the effect of sedimentary denitrification on the change in δ15NNO3 is relatively small.  相似文献   
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