Diamond in metasedimentary crustal rocks from Pohorje,Eastern Alps: a window to deep continental subduction          下载免费PDF全文

M. Janák  N. Froitzheim  K. Yoshida  V. Sasinková  M. Nosko  T. Kobayashi  T. Hirajima  M. Vrabec 《Journal of Metamorphic Geology》2015,33(5):495-512

We report the first finding of diamond and moissanite in metasedimentary crustal rocks of Pohorje Mountains (Slovenia) in the Austroalpine ultrahigh‐pressure (UHP) metamorphic terrane of the Eastern Alps. Microscopic observations and Raman spectroscopy show that diamond occurs in situ as inclusions in garnet, being heterogeneously distributed. Under the optical microscope, diamond‐bearing inclusions are of cuboidal to rounded shape and of pinkish, yellow to brownish colour. The Raman spectra of the investigated diamond show a sharp, first order peak of sp³‐bonded carbon, in most cases centred between 1332 and 1330 cm^?1, with a full width at half maximum between 3 and 5 cm^?1. Several spectra show Raman bands typical for disordered graphitic (sp²‐bonded) carbon. Detailed observations show that diamond occurs either as a monomineralic, single‐crystal inclusion or it is associated with SiC (moissanite), CO₂ and CH₄ in polyphase inclusions_. This rare record of diamond occurring with moissanite as fluid‐inclusion daughter minerals implies the crystallization of diamond and moissanite from a supercritical fluid at reducing conditions. Thermodynamic modelling suggests that diamond‐bearing gneisses attained P–T conditions of ≥3.5 GPa and 800–850 °C, similar to eclogites and garnet peridotites. We argue that diamond formed when carbonaceous sediment underwent UHP metamorphism at mantle depth exceeding 100 km during continental subduction in the Late Cretaceous (c. 95–92 Ma). The finding of diamond confirms UHP metamorphism in the Pohorje Mountains, the most deeply subducted part of Austroalpine units.  相似文献   

Gas seepage from Tokamachi mud volcanoes, onshore Niigata Basin (Japan): Origin, post-genetic alterations and CH₄-CO₂ fluxes     

G. Etiope  R. NakadaK. Tanaka  N. Yoshida 《Applied Geochemistry》2011,26(3):348-359

Methane and CO₂ emissions from the two most active mud volcanoes in central Japan, Murono and Kamou (Tokamachi City, Niigata Basin), were measured in from both craters or vents (macro-seepage) and invisible exhalation from the soil (mini- and microseepage). Molecular and isotopic compositions of the released gases were also determined. Gas is thermogenic (δ¹³C_CH4 from −32.9‰ to −36.2‰), likely associated with oil, and enrichments of ¹³C in CO₂ (δ¹³C_CO2 up to +28.3‰) and propane (δ¹³C_C3H8 up to −8.6‰) suggest subsurface petroleum biodegradation. Gas source and post-genetic alteration processes did not change from 2004 to 2010. Methane flux ranged within the orders of magnitude of 10¹-10⁴ g m⁻² d⁻¹ in macro-seeps, and up to 446 g m⁻² d⁻¹ from diffuse seepage. Positive CH₄ fluxes from dry soil were widespread throughout the investigated areas. Total CH₄ emission from Murono and Kamou were estimated to be at least 20 and 3.7 ton a⁻¹, respectively, of which more than half was from invisible seepage surrounding the mud volcano vents. At the macro-seeps, CO₂ fluxes were directly proportional to CH₄ fluxes, and the volumetric ratios between CH₄ flux and CO₂ flux were similar to the compositional CH₄/CO₂ volume ratio. Macro-seep flux data, in addition to those of other 13 mud volcanoes, supported the hypothesis that molecular fractionation (increase of the “Bernard ratio” C₁/(C₂ + C₃)) is inversely proportional to gas migration fluxes. The CH₄ “emission factor” (total measured output divided by investigated seepage area) was similar to that derived in other mud volcanoes of the same size and activity. The updated global “emission-factor” data-set, now including 27 mud volcanoes from different countries, suggests that previous estimates of global CH₄ emission from mud volcanoes may be significantly underestimated.  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987114000917     

Miyuki Tahata  Yusuke Sawaki  Yuichiro Ueno  Manabu Nishizawa  Naohiro Yoshida  Toshikazu Ebisuzaki  Tsuyoshi Komiya  Shigenori Maruyama 《地学前缘(英文版)》2015,6(1):121-136

Important ecological changes of the Earth(oxidization of the atmosphere and the ocean) increase in nutrient supply due to the break-up of the super continent(Rodinia) and the appearance of multi-cellular organisms(macroscopic algae and metazoan) took place in the Ediacaran period,priming the Cambrian explosion.The strong perturbations in carbon cycles in the ocean are recorded as excursions in carbonate and organic carbon isotope ratio(δ~(13)C_(carb) and δ~(13)C_(org)) from the Ediacaran through early Cambrian periods.The Ediacaran-early Cambrian sediment records of δ~(13)C_(carb) and δ~(13)C_(org),obtained from the drill-core samples in Three Gorges in South China,are compared with the results of numerical simulation of a simple one-zone model of the carbon cycle of the ocean,which has two reservoirs(i.e.,dissolved organic carbon(DOC) and dissolved inorganic carbon(DIC).The fluxes from the reservoirs are assumed to be proportional to the mass of the carbon reservoirs.We constructed a model,referred to here as the Best Fit Model(BFM),which reproduce δ~(13)C_(carb) and δ~(13)C_(org) records in the Ediacaran-early Cambrian period noted above.BFM reveals that the Shuram excursion is related to three major changes in the carbon cycle or the global ecological system of the Earth:(1) an increase in the coefficient of remineralization by a factor of ca.100,possibly corresponding to a change in the dominant metabolism from anaerobic respiration to aerobic respiration,(2) an increase of carbon fractionation index from 25‰ to 33‰,possibly corresponding to the change in the primary producer from rock-living cyanobacteria to free-living macro algae,and(3) an increase in the coefficient of the organic carbon burial by a factor of ca.100,possibly corresponding to the onset of a biological pump driven by the flourishing metazoan and zooplankton.The former two changes took place at the start of the Shuram excursion,while the third occurred at the end of the Shuram excursion.The other two excursions are explained by the tentative decrease in primary production due to cold periods,which correspond to the Gaskiers(ca.580 Ma) and Bikonor(ca.542 Ma) glaciations.  相似文献   

http://www.sciencedirect.com/science/article/pii/S167498711300162X     

Fumiko Tajima  Masaki Yoshida  Eiji Ohtani 《地学前缘(英文版)》2015,6(1):79-93

Seismic observations have shown structural variation near the base of the mantle transition zone(MTZ)where subducted cold slabs,as visualized with high seismic speed anomalies(HSSAs),flatten to form stagnant slabs or sink further into the lower mantle.The different slab behaviors were also accompanied by variation of the "660 km" discontinuity depths and low viscosity layers(LVLs) beneath the MTZ that are suggested by geoid inversion studies.We address that deep water transport by subducted slabs and dehydration from hydrous slabs could affect the physical properties of mantle minerals and govern slab dynamics.A systematic series of three-dimensional numerical simulation has been conducted to examine the effects of viscosity reduction or contrast between slab materials on slab behaviors near the base of the MTZ.We found that the viscosity reduction of subducted crustal material leads to a separation of crustal material from the slab main body and its transient stagnation in the MTZ.The once trapped crustal materials in the MTZ eventually sink into the lower mantle within 20-30 My from the start of the plate subduction.The results suggest crustal material recycle in the whole mantle that is consistent with evidence from mantle geochemistry as opposed to a two-layer mantle convection model.Because of the smaller capacity of water content in lower mantle minerals than in MTZ minerals,dehydration should occur at the phase transformation depth,~660 km.The variation of the discontinuity depths and highly localized low seismic speed anomaly(LSSA) zones observed from seismic P waveforms in a relatively high frequency band(~1 Hz) support the hypothesis of dehydration from hydrous slabs at the phase boundary.The LSSAs which correspond to dehydration induced fluids are likely to be very local,given very small hydrogen(H~+) diffusivity associated with subducted slabs.The image of such local LSSA zones embedded in HSSAs may not be necessarily captured in tomography studies.The high electrical conductivity in the MTZ beneath the northwestern Pacific subduction zone does not necessarily require a broad range of high water content homogeneously.  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987114001108     

Masaki Yoshida 《地学前缘(英文版)》2015,6(1):1-2

<正>About three decades after the establishment of the plate tectonics theory in the late 1960s,Maruyama(1994)proposed the"plume tectonics"theory based on whole-mantle seismic tomography image(Fukao,1992;Fukao et al.,1994).According to this theory,the earth's interior is divided into three regimes:the earth's surface region governed by lateral motions of tectonic plates,the mantle governed by vertical motions of"superplumes"(i.e.,large-  相似文献   

Effects of mass source/sink at the western boundary on the wind-driven gyres: Implications for the ventilation of the north pacific intermediate layer through convection in the Okhotsk Sea and tidal mixing at the Kuril Straits     

Tomohiro Nakamura  Takahiro Toyoda  Yoichi Ishikawa  Toshiyuki Awaji 《Journal of Oceanography》2010,66(1):41-60

A steady quasi-geostrophic 2.5-layer model, forced by both Ekman pumping and a mass source/sink situated at the western boundary has been constructed to investigate the effect of diapycnal transport due to convection in the Okhotsk Sea and tidal mixing at the Kuril Straits on the intermediate layer in the North Pacific. The model illustrates a combined effect of the wind-driven and mass-driven circulations. First, net mass input induces a “barotropic” mode inter-gyre flow along the western boundary through the dynamical influence of Kelvin waves. This flow creates characteristic curves (geostrophic contours) that facilitate inter-gyre communication through the western boundary layer from the location of the mass source to the subtropical gyre. Due to the effect of wind-driven circulation, the offshore part turns eastward into the interior, encircles the outer rim of the region (which would otherwise be the pool region in the absence of mass input), and then encounters the western boundary. Eventually, the water fed into the lower layer flows mostly along this path and later flows away to the equatorial region. Conversely, in the upper layer, water is fed from the equator to the subtropics, and to the subpolar interior region through the western boundary current. The water then circulates along the outer rim and is absorbed into the mass sink. The model is controlled mainly by three nondimensional parameters: (1) the ratio of net mass input rate to the maximum Sverdrup transport (Q/T _Sv ^max ), which affects the inter-gyre communication by altering the paths of geostrophic contours, (2) the ratio of a mass input rate into the lower layer to that in total (Q ₂/Q), which controls the vertical structure of the inter-gyre flow, and (3) the measure of the wind forcing effect relative to the β effect, which determines the horizontal extent of the area influenced by the mass input. The other parameter regimes with respect to Q/T _Sv ^max and Q ₂/Q are also presented.  相似文献   

Future supercontinent assembled in the northern hemisphere     

Masaki Yoshida  M. Santosh 《地学学报》2011,23(5):333-338

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Seismic vertical array analysis for phase decomposition     

Kunikazu Yoshida  Tsutomu Sasatani 《Geophysical Journal International》2008,174(2):707-718

We propose a vertical array analysis method that decomposes complex seismograms into body and surface wave time histories by using a velocity structure at the vertical array site. We assume that the vertical array records are the sum of vertically incident plane P and S waves, and laterally incident Love and Rayleigh waves. Each phase at the surface is related to that at a certain depth by the transfer function in the frequency domain; the transfer function is obtained by Haskell's matrix method, assuming a 1-D velocity structure. Decomposed P , S and surface waves at the surface are estimated from the vertical array records and the transfer functions by using a least-squares method in the frequency domain; their time histories are obtained by the inverse Fourier transform. We carried out numerical tests of this method based on synthetic vertical array records consisting of vertically incident plane P and S waves and laterally incident plane Love and Rayleigh waves. Perfect results of the decomposed P , S , Love and Rayleigh waves were obtained for synthetic records without noise. A test of the synthetic records in which a small amount of white noise was added yielded a reasonable result for the decomposed P , S and surface waves. We applied this method to real vertical array records from the Ashigara valley, a moderate-sized sedimentary valley. The array records from two earthquakes occurring at depths of 123 and 148 km near the array (epicentral distance of about 31 km) exhibited long-duration later phases. The analysis showed that duration of the decomposed S waves was a few seconds and that the decomposed surface waves appeared a few seconds after the direct S -wave arrival and had very long duration. This result indicated that the long-duration later phases were generated not by multireflected S waves, but by basin-induced surface waves.  相似文献   

Effects of Earth's curvature and radial heterogeneity in dislocation studies:Case studies of the 2008 Wenchuan earthquake and the 2004 Sumatra earthquake          下载免费PDF全文

Guangyu Fu  Wenke Sun  Yoichi Fukuda  Shanghua Gao  Takashi Hasegawa 《地震科学（英文版）》2010,23(4):301-308

Recently,effects of Earth's curvature and radial heterogeneity on coseismic deformations are often investigated based on the 2004 Sumatra earthquake.However,such effects are strongly related to earthquake types.As a low dip angle event,the 2004 Sumatra earthquake is not a good seismic case for such a topic since the effects for moderate dip angle events are much bigger.In this study,the half-space and spherical dislocation theories are used,respectively,to calculate coseismic displacements caused by the 2008 Wenchuan earthquake and the 2004 Sumatra earthquake.Effects of Earth's curvature and stratification are investigated through the discrepancies of results calculated using the two dislocation theories.Results show that the effects of Earth's curvature and stratification for the 2008 Wenchuan earthquake are much larger than those for the 2004 Sumatra earthquake.Ignoring the effects will cause errors up to 100%-200% in far field displacements for a moderate dip angle event like the 2008 Wenchuan earthquake.Such great effects are much bigger than those conclusions of previous studies.Besides,comparison with observations verifies that spherical dislocation theories yield better results than half-space ones in far fields.  相似文献   

Internal differentiation of Kutsugata lava flow from Rishiri Volcano,Japan: Processes and timescales of segregation structures' formation     

Takeshi Kuritani  Takeyoshi Yoshida  Yoshitaka Nagahashi 《Journal of Volcanology and Geothermal Research》2010

Internal differentiation processes in a solidifying lava flow were investigated for the Kutsugata lava flow from Rishiri Volcano in northern Japan. In a representative 6-m thick lava flow that was investigated in detail in this study, segregation products darker than the host lavas manifested mainly in the form of pipes (vesicle cylinders) and layers (vesicle sheets), occurring around 0.5–2.3 m and 2.0–4.0 m above the base, respectively. Both the cylinders and sheets are significantly richer in incompatible elements such as TiO₂ and K₂O than the host lavas, which suggest that these products essentially represent residual melt produced during solidification of the lava flow. Field observation and the geochemical features of the lavas suggest that the vesicle cylinders grew upward from near the base of the flow by continuous feeding of residual melt from the neighboring host lavas to the heads of the cylinders. On the other hand, the vesicle sheets were produced in situ in the solidifying lava flow as fracture veins caused by horizontal compression. The vesicle cylinders have a remarkably higher MgO content (up to 8 wt.%) than the host lava (< 6 wt.%), whereas the vesicle sheets display MgO depletion (as low as 3.5 wt.%). The relatively high MgO content of the vesicle cylinders cannot be explained solely by the mechanical mixing of olivine phenocrysts with the residual melt. It is suggested that the vesicle cylinders were produced by the extraction of olivine-bearing interstitial melt from an augite-plagioclase network in the host lava, whereas the vesicle sheets were formed by the migration of the residual melt from a crystal network consisting of plagioclase, augite, and olivine in the host lava into platy fractures. We infer that this selective crystal fractionation for forming the vesicle cylinders resulted from processes in which abundant vesicles rejected from the upward-migrating floor solidification front prevented olivine crystals from being incorporated into the crystal network in the host lava. The vesicle cylinders are considered to have formed in ∼ 1 day after the lava flow came to rest, while relatively large vesicle sheets (> 1 cm thick) appeared much later (after ∼ 9 days). The formation of these segregation products was essentially complete within 20 days after the lava emplacement.  相似文献