A new occurrence of retrogressed eclogite from the Sanbagawa belt of southwest Japan and its significance     

Tomoki Taguchi  Shunsuke Endo  Yohei Igami  Akira Miyake 《Island Arc》2019,28(5)

The present paper reports, for the first time, the occurrence of an omphacite‐bearing mafic schist from the Asemi‐gawa region of the Sanbagawa belt (southwest Japan). The mafic schist occurs as thin layers within pelitic schist of the albite–biotite zone. Omphacite in the mafic schist only occurs as inclusions in garnet, and albite is the major Na phase in the matrix, suggesting that the mafic schist represents highly retrogressed eclogite. Garnet grains in the sample show prograde‐type compositional zoning with no textural or compositional break, and contain mineral inclusions of omphacite, quartz, glaucophane, barroisite/hornblende, epidote and titanite. In addition to the petrographic observations, Raman spectroscopy and focused ion beam system–transmission electron microscope analyses were used for identification of omphacite in the sample. The omphacite in the sample shows a strong Raman peak at 678 cm^?1, and concomitant Raman peaks are all consistent with those of the reference omphacite Raman spectrum. The selected area electron diffraction pattern of the omphacite is compatible with the common P2/n omphacite structure. Quartz inclusions in the mafic schist preserve high residual pressure values of Δω₁ > 8.5 cm^?1, corresponding to the eclogite facies conditions. The combination of Raman geothermobarometries and garnet–clinopyroxene geothermometry gives peak pressure–temperature (P–T) conditions of 1.7–2.0 GPa and 440–540 °C for the mafic schist. The peak P–T values are comparable to those of the schistose eclogitic rocks in other Sanbagawa eclogite units of Shikoku. These findings along with previous age constraints suggest that most of the Sanbagawa schistose eclogites and associated metasedimentary rocks share similar simple P–T histories along the Late Cretaceous subduction zone.  相似文献   

Governance of disaster emergency wells in three cities in Japan affected by earthquakes     

Endo  Takahiro  Iizuka  Tomoki  Koga  Hitomi  Hamada  Nahoko 《Hydrogeology Journal》2023,31(5):1147-1163

Concern has grown regarding how public and private sectors should make effective use of local groundwater to alleviate negative impacts of water-supply cutoff following an earthquake event, which can be regarded as an emergency groundwater governance problem. Existing literature on groundwater governance, however, is based on the tacit assumption of groundwater utilization under normal social conditions, and scant consideration has been given to the role of groundwater following occurrence of a natural disaster. This study conducted questionnaire surveys to reveal how groundwater was used in three cities (Kumamoto, Sapporo, and Sendai) in Japan struck by large earthquakes between 2010 and 2020. Results revealed substantial differences between these cities in terms of groundwater utilization following earthquake occurrence. The time between the restoration of the electricity supply and restoration of the waterworks, and the social capital accumulated by local governments, are indicated as possible reasons for such differences. Analysis also identified policy challenges for improved groundwater governance in an emergency: (1) establishment of a strategy for emergency water supply through combined use of groundwater and other water sources, (2) enhancement of methods for timely inspection of groundwater quality following occurrence of a disaster, (3) maintenance of records of the number of registered disaster emergency wells (DEWs), (4) creation of methods for publicizing locational information on DEWs with adequate regard for the privacy of well owners, and (5) recognition of the importance of making DEWs part of overall disaster preparedness.

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Progressive changes in lithological association of the Sanbagawa metamorphic complex,Southwest Japan: Relict clinopyroxene and detrital zircon perspectives          下载免费PDF全文

Shunsuke Endo  Kazuhiro Miyazaki  Tohru Danhara  Hideki Iwano  Takafumi Hirata 《Island Arc》2018,27(5)

The main tectono‐stratigraphic unit (Shirataki unit) of the Sanbagawa metamorphic complex in central Shikoku is characterized by abundant mafic schist layers that show the mid‐ocean ridge basalt (MORB) affinity. These MORB‐derived schist layers are absent in a southern (structurally lower) domain within the unit. Instead, sporadic occurrences of small metabasite lenses that contain relict igneous minerals (Ti‐rich augite and kaersutite) indicative of alkali basalt magmatism are newly recognized in the southern domain. Compositions of relict clinopyroxene in metabasalt are useful to identify the tectonic setting and origin of the protolith basalt, and those in each unit of the Sanbagawa metamorphic complex are presented. The metamorphic grade of the Shirataki unit generally increases structurally upwards in the southern side of the highest‐grade zone, and metamorphic zonation is subparallel to lithostratigraphic succession. The protolith assemblage of the Shirataki unit shows a distinct change from the southern low‐grade domain (lower Shirataki subunit) composed of terrigenous sedimentary rocks (mudstone and sandstone) with minor alkali basalt to the northern higher‐grade domain (upper Shirataki subunit) consisting of terrigenous and pelagic sedimentary rocks with abundant MORB. The youngest detrital zircon U–Pb ages (ca 95–90 Ma) suggest that both domains have Late Cretaceous depositional ages at the trench. Progressive peeling of oceanic plate stratigraphy during subduction can account for the observed change of lithological association in the Shirataki unit.  相似文献   

Petrogenesis and implications of jadeite‐bearing kyanite eclogite from the Sanbagawa belt (SW Japan)     

S. Endo  M. Tsuboi 《Journal of Metamorphic Geology》2013,31(6):647-661

Jadeite‐bearing kyanite eclogite has been discovered in the Iratsu body of the Sanbagawa belt, SW Japan. The jadeite + kyanite assemblage is stable at higher pressure–temperature (P–T) conditions or lower H₂O activity [a(H₂O)] than paragonite, although paragonite‐bearing eclogite is common in the Sanbagawa belt. The newly discovered eclogite is a massive metagabbro with the peak‐P assemblage garnet + omphacite + jadeite + kyanite + phengite + quartz + rutile. Impure jadeite is exclusively present as inclusions in garnet. The compositional gap between the coexisting omphacite (P2/n) and impure jadeite (C2/c) suggests relatively low metamorphic temperatures of 510–620 °C. Multi‐equilibrium thermobarometry for the assemblage garnet + omphacite + kyanite + phengite + quartz gives peak‐P conditions of ~2.5 GPa, 570 °C. Crystallization of jadeite in the metagabbro is attributed to Na‐ and Al‐rich effective bulk composition due to the persistence of relict Ca‐rich clinopyroxene at the peak‐P stage. By subtracting relict clinopyroxene from the whole‐rock composition, pseudosection modelling satisfactorily reproduces the observed jadeite‐bearing assemblage and mineral compositions at ~2.4–2.5 GPa, 570–610 °C and a(H₂O) >0.6. The relatively high pressure conditions derived from the jadeite‐bearing kyanite eclogite are further supported by high residual pressures of quartz inclusions in garnet. The maximum depth of exhumation in the Sanbagawa belt (~80 km) suggests decoupling of the slab–mantle wedge interface at this depth.  相似文献   

Effect of ocean acidification on coastal phytoplankton composition and accompanying organic nitrogen production     

Takeo Hama  Shoko Kawashima  Koichi Shimotori  Yuhi Satoh  Yuko Omori  Shigeki Wada  Taiki Adachi  Shun Hasegawa  Takashi Midorikawa  Masao Ishii  Shu Saito  Daisuke Sasano  Hiroko Endo  Tsuyoshi Nakayama  Isao Inouye 《Journal of Oceanography》2012,68(1):183-194

The effect of ocean acidification, caused by the increase in pCO₂ in seawater, on phytoplankton population and on related organic nitrogen production was experimentally examined by use of a natural coastal microbial population. pCO₂ and pH were controlled by aeration with air in which pCO₂ was at the current level (control), for which ambient air was used, and with air in which pCO₂ was ??800?? and ??1200?? ppm, in 500-L culture vessels. The experiment was continued for 15?days after addition of the inorganic nutrients such as nitrate, phosphate, and silicate. During most of the experimental period, a minor increase in phytoplankton biomass was noted, probably because of low irradiance, an increase in phytoplankton biomass was observed at the end of the experiment. Flow cytometric and microscopic observations revealed that this increase was because of Chrysochromulina sp. (Haptophyceae). The growth of Chrysochromulina sp. was most obvious in the control vessel, and tended to be obscured by increasing pCO₂ (decrease in pH), indicating the possibility that ocean acidification inhibits the growth of specific phytoplankton groups, for example Chrysochromulina sp. Production of particulate organic nitrogen (PON), determined by the ¹⁵N tracer method, also diminished under acidified conditions compared with that at the current level.  相似文献   

Material flows of an evolving magnetic field     

Yoshinari Nakagawa 《Astrophysics and Space Science》1990,174(1):95-109

The possibility of material flows to trace out the magnetic field configuration is examined through numerical simulations. In particular, the evolution of a magnetic arcade due to differential motions of its footpoints is considered. With the use of numerical scheme based on the method of projected characteristics and newly derived proper boundary conditions, it is shown that material flows develop to outline the configuration of evolving magnetic field. Physical implications of the results are discussed.  相似文献   

Preservation of the shell matrix protein dermatopontin in 1500 year old land snail fossils from the Bonin islands     

Isao Sarashina  Yoshiki Kunitomo  Minoru Iijima  Satoshi Chiba  Kazuyoshi Endo   《Organic Geochemistry》2008,39(12):1742

Organic molecules such as proteins can be preserved in certain fossils. The bulk properties of fossil proteins of both vertebrates and invertebrates have been studied for over half a century. Named proteins have so far been identified, however, only in vertebrate fossils, such as collagen from mammoth bones. Using immunological assays, we examined 1500 year old fossils of the extinct land snail Mandarina luhuana from the Bonin islands for the presence of dermatopontin, a molluscan shell matrix protein. First, we examined the shell microstructure and mineralogy of the fossil shells using scanning electron microscopy (SEM) and powder X-ray diffraction (XRD) in order to estimate the extent of diagenetic alteration. The results suggest that the original microstructure and mineralogy of the shells are preserved. Antiserum raised against the Type-1 dermatopontin fragment of the living land snail Euhadra brandtii showed significant immunological reactivity with the extracts from the fossil shells of M. luhuana. Immunological binding curves drawn for the shell extracts of extant M. aureola and the extinct M. luhuana confirmed the presence of dermatopontin in the fossil shells and provided an estimate that about 75–98% of the original dermatopontin was lost from the M. luhuana fossils. This is the first report of a named protein being identified in invertebrate fossils.  相似文献   

Nitrous oxide in the sea     

Tadashi Yoshinari 《Marine Chemistry》1976,4(2):189-202

A new gas chromatographic method was developed for the measurement of nitrous oxide (N₂O) in seawater. It takes 15 min for the analysis in a sample of 640 ml seawater.By this method, more than 1000 samples taken over various depths and areas in the sea were analyzed. In the western North Atlantic, the N₂O concentration over a range of oceanic depths gave characteristic profiles that were negatively correlated with oxygen profiles, reaching its maximum (c.a. 1 μg/l) in the oxygen-minimum layer at mid-depths. In the Caribbean, the N₂O maximum reached higher concentrations than in the North Atlantic. N₂O was near equilibrium with that in the atmosphere in Atlantic surface waters, but supersaturation of N₂O was observed in surface waters of the Gulf of St. Lawrence in early June and in most surface samples from the Caribbean Sea in March.The estimated rate of N₂O production in the sea may be significant in terms of geochemical cycling of combined nitrogen to the atmosphere.  相似文献   

Reconstruction of sea surface dimethylsulfide in the North Pacific during 1970s to 2000s     

Y.W. Watanabe  H. Yoshinari  A. Sakamoto  Y. Nakano  N. Kasamatsu  T. Midorikawa  T. Ono 《Marine Chemistry》2007,103(3-4):347-358

We proposed an empirical equation of sea surface dimethylsulfide (DMS, nM) using sea surface temperature (SST, K), sea surface nitrate (SSN, μM) and latitude (L, °N) to reconstruct the sea surface flux of DMS over the North Pacific between 25°N and 55°N: ln DMS = 0.06346 · SST − 0.1210 · SSN − 14.11 · cos(L) − 6.278 (R² = 0.63, p < 0.0001). Applying our algorithm to climatological hydrographic data in the North Pacific, we reconstructed the climatological distributions of DMS and its flux between 25 °N and 55 °N. DMS generally increased eastward and northward, and DMS in the northeastern region became to 2–5 times as large as that in the southwestern region. DMS in the later half of the year was 2–4 times as large as that in the first half of the year. Moreover, applying our algorithm to hydrographic time series datasets in the western North Pacific from 1971 to 2000, we found that DMS in the last three decades has shown linear increasing trends of 0.03 ± 0.01 nM year^− 1 in the subpolar region, and 0.01 ± 0.001 nM year^− 1 in the subtropical region, indicating that the annual flux of DMS from sea to air has increased by 1.9–4.8 μmol m^− 2 year^− 1. The linear increase was consistent with the annual rate of increase of 1% of the climatological averaged flux in the western North Pacific in the last three decades.  相似文献   

Standing stocks and production rates of phytoplankton and planktonic copepods in the Inland Sea of Japan   总被引：1，自引：0，他引：1  

Shin-ichi Uye  Hiroshi Kuwata  Takuo Endo 《Journal of Oceanography》1986,42(6):421-434

Standing stocks and production rates of phytoplankton and planktonic copepods were investigated at 15 stations in the Inland Sea of Japan during four cruises in October–November 1979, January, April and June 1980. The overall mean of phytoplankton biomass was relatively constant during the study period, ranging from 2.3 mg chl.a m^–3 in April to 3.6 mg chl.a m^–3 in October–November. Primary production was low in January (mean: 90 mg C m^–2 d^–1), but higher than 375 mg C m^–2 d^–1 on the other occasions. Integrated annual primary production was 122 g C m^–2 yr^–1. In terms of carbon weight,Paracalanus parvus was the most important copepod species. The variation of the mean copepod biomass (range: 7.6 mg C m^–3 in April to 20.2 mg C m^–3 in June) was smaller than that of copepod production, which was estimated by the Ikeda-Motoda's physiological method. Copepod producion was low in cold seasons (0.6 and 0.9 mg C m^–3 d^–1 in January and April, respectively), and increased, following the elevation of primary production, to 4.9 mg C m^–3 d^–1 in June. Annual copepod production was 33.7 g C m^–2 yr^–1, of which herbivore (secondary) production was 26.4 g C m^–2 yr^–1 (21.7% of primary production). The ratios of pelagic planktivorous fish catch and total fish catch to the primary production were 0.82 and 1.8%, respectively, indicating very high efficiency in exploiting fishery resources in the Inland Sea of Japan.  相似文献