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The influence of ultraviolet light, heating, freezing and weathering on the mercury concentration in the primary feathers from Guillemot and Black Guillemot has been examined. Even within 8 months of exposure variation in mercury concentration due to either loss of mercury or weight loss of the feathers has been found to be less than 10% relative.  相似文献   
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The partial molal volume (V?) of silicic acid in 0.725 m NaCl at 20°C has been calculated from (1) direct volume changes due to the dissolution of anhydrous sodium silicate and (2) some literature values for the partial molal volumes of NaOH and water. V?Si(OH)4, unconnected for electrostriction effects, was found to be 53 ± 2 ml mole?1. V?si(Oh)4, corrected for volume changes due to solvent electrostriction by charged Si species, was estimated to be in the range 58–62 ml mole?1; this range is 7–11 ml mole?1 greater than the V?Si(OH)4 calculated from Willey's (Mar. Chem. 2, 239–250, 1974) solubility data obtained from the dissolution, in seawater, of amorphous silica subjected to hydrostatic pressure. Our V?Si(OH)4 does, however, agree within experimental error with the V?Si(OH)4 calculated from Jones and Pytkowicz's (Bull. Soc. Roy. Sci. Liege 42, 118–120, 1973) data for the solubility of amorphous silica in seawater at high pressure and is nearly in agreement with Willey's (Ph.D. thesis, Dalhousie University, 1975) solubility data for amorphous silica in 0.6 m NaCl.  相似文献   
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Hydration, ion-water interactions, and water structure effects in seawater were studied by determining differences (Δβ) between the compressibilities of test salt solutions and the compressibilities of reference solutions. The reference solutions were distilled water and seawater (35%0), and the test salt solutions were either 0.13 m or 0.26m with respect to one of the following test salts: LiCl, NaCl, KCl, CsCl, NaF, NaI, MgCl2, CaCl2, BaCl2, Na2SO4, K2SO4, and MgSO4. The compressibility measurements (to 900 bars) were carried out at 2°C and also at 15°C using a differential method in which a pressure increase or a temperature increase causes Δβ to become less negative. At 1 bar and 15°C, the Δβ (0.26 m, distilled water reference) values ranged from ?1.14 × 10?6 bar? for NaI to ?3.84 × 10?6 bar?1 for Na2SO4, and the Δβ (0.26 m, seawater reference) values ranged from ?1.30 × 10?6 bar?1 for NaCl to ?3.04 × 10?6 bar?1 for Na2SO4. The Δβ values were used to calculate hydration numbers. Entropy of transfer, excess hydrogen bond breaking (determined by NMR), and effective radii of ions are properties which can be used to describe the influence of ions on water structure. The extent to which these properties correlate with Δβ values depends upon whether the ion is an anion or a cation, and this correlation forms the thesis that anions alter water structure in a different way than do cations.  相似文献   
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Suitable vineyard soils enhance soil stability and biodiversity which in turn protects roots against erosion and nutrient losses. There is a lack of information related to inexpensive and suitable methods and tools to protect the soil in Mediterranean sloping vineyards(25° of slope inclination). In the vineyards of the Montes de Málaga(southern Spain), a sustainable land management practice that controls soil erosion is actually achieved by tilling rills in the down-slope direction to canalize water and sediments. Because of their design and use, we call them agri-spillways. In this research, we assessed two agri-spillways(between 10 m and 15 m length, and slopes between 25.8° and 35°) by performing runoff experiments under extreme conditions(a motor driven pump that discharged water flows up to 1.33 l s~(-1) for 12 to 15 minutes: ≈1000 l). The final results showed: i) a great capacity by these rills to canalize large amounts of water and sediments; and, ii) higher water flow speeds(between 0.16 m s-1 and 0.28 m s~(-1)) and sediment concentrationrates(up to 1538.6 g l~(-1)) than typically found in other Mediterranean areas and land uses(such as badlands, rangelands or extensive crops of olives and almonds). The speed of water flow and the sediment concentration were much higher in the shorter and steeper rill. We concluded that agri-spillways, given correct planning and maintenance, can be a potential solution as an inexpensive method to protect the soil in sloping Mediterranean vineyards.  相似文献   
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Specific dark energy models with linear inhomogeneous time-dependent equation of state, within the framework of 4d Friedman-Robertson-Walker (FRW) cosmology, are investigated. It is demonstrated that the choice of such 4d inhomogeneous fluid models may lead to a brane FRW cosmology without any explicit account of higher dimensions at all. Effectively, we thus obtain a brane dark energy universe without introducing the brane concept explicitly. Several examples of brane Rip cosmology arising from 4d inhomogeneous dark fluid models are given.  相似文献   
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The concept of negative temperatures has occasionally been used in connection with quantum systems. A recent example of this sort is reported in the paper of S. Braun et al. (Science 339:52, 2013), where an attractively interacting ensemble of ultracold atoms is investigated experimentally and found to correspond to a negative-temperature system since the entropy decreases with increasing energy at the high end of the energy spectrum. As the authors suggest, it would be of interest to investigate whether a suitable generalization of standard cosmological theory could be helpful, in order to elucidate the observed accelerated expansion of the universe usually explained in terms of a positive tensile stress (negative pressure). In the present note we take up this basic idea and investigate a generalization of the standard viscous cosmological theory, not by admitting negative temperatures but instead by letting the bulk viscosity take negative values. Evidently, such an approach breaks standard thermodynamics, but may actually be regarded to lead to the same kind of bizarre consequences as the standard approach of admitting the equation-of-state parameter w to be less than ?1. In universe models dominated by negative viscosity we find that the fluid’s entropy decreases with time, as one would expect. Moreover, we find that the fluid transition from the quintessence region into the phantom region (thus passing the phantom divide w=?1) can actually be reversed. Also in generalizations of the ΛCDM-universe models with a fluid having negative bulk viscosity we find that the viscosity decreases the expansion of the universe.  相似文献   
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The low frequency array (LOFAR) radiotelescope will be a powerful instrument for answering fundamental, unresolved scientific questions concerning solar system radio phenomena and related emissions from nearby stellar systems. This paper reviews the phenomena, emission mechanisms, open scientific questions, and LOFAR's capabilities. LOFAR will detect metric solar radio bursts in the corona and interplanetary medium, out to distances of order 10 solar radii, as well as Jovian radio emissions. Arguments are given that LOFAR may be sufficiently sensitive to detect stellar analoges of solar type II and III bursts, and may detect cyclotron-maser emissions from extra-solar planets. LOFAR may also aid space weather research, by passively detecting coronal mass ejections (CMEs) via scintillation and Faraday rotation effects, or by detecting radar signals bounced off CMEs and coronal density structures if a suitable solar radar is developed.  相似文献   
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