Saraca indica leaf powder for decontamination of Pb: removal, recovery, adsorbent characterization and equilibrium modeling   总被引：5，自引：5，他引：0  

P. Goyal  P. Sharma  S. Srivastava  M. M. Srivastava 《International Journal of Environmental Science and Technology》2008,5(1):27-34

The present study explores the effectiveness of Saraca indica leaf powder, a surplus low value agricultural waste, in removing Pb ions from aqueous solution. The influence of pH, biomass dosage, contact time, particle size and metal concentration on the removal process were investigated. Batch studies indicated that maximum biosorption capacity for Pb was 95.37% at the pH 6.5. The sorption process followed the first order rate kinetics. The adsorption equilibrium data fitted best to both Langmuir and Freundlich isotherms. Morphological changes observed in scanning electron micrographs of untreated and metal treated biomass confirmed the phenomenon of biosorption. Fourier transform infrared spectroscopy of native and exhausted leaf powder confirmed lead biomass interactions responsible for sorption. Acid regeneration was tried for several cycles with a view to recover the sorbed metal ion and also to restore the sorbent to its original state. The findings showed that Saraca indica leaf powder can easily be envisaged as a new, vibrant, low cost biosorbent for metal clean up operations.  相似文献   

Mixed-layer characteristics as related to the monsoon climate of New Delhi,India     

M. Gamo  P. Goyal  Manju Kumari  U. C. Mohanty  M. P. Singh 《Boundary-Layer Meteorology》1994,67(3):213-227

Annual variations of mixed-layer characteristics at New Delhi, India have been studied for a weak monsoon (1987) and a strong monsoon (1988) year. In the weak monsoon year (1987), the maximum mixing depthh _max was found to have a value of around 3000 m during the pre-monsoon, less than 2000 m during the summer monsoon, around 2000 m during the post-monsoon, and less than 1000 m in the winter season. For the strong monsoon year (1988),h _max values were less than 1987 values for comparable periods throughout the year. The seasonal and yearly differences ofh _max were explained by the surface energy balance and potential temperature gradient at a time close to sunrise. According to the spatial patterns of obtained by an objective analysis of the 850 to 700 hPa layers. mixed-layer characteristics obtained at New Delhi are representative of the north and central regions of India.  相似文献   

R+ bacteria in estuarine sediments     

Sagar M. Goyal  Charles P. Gerba  Joseph L. Melnick 《Marine pollution bulletin》1979,10(1):25-27

Increased construction of coastal canal communities had led to a deterioration of the water quality in the canals. In addition to being used for recreational activities, the canals serve as a dumping place for domestic sewage from these communities. This study was conducted to determine the prevalence of transferable drug-resistant (R⁺) bacteria in six coastal canals. A significantly higher number of R⁺ bacteria (both pathogenic and nonpathogenic) occurred in the bottom sediments than in the overlaying water. These sediments can be resuspended following rain, dredging, storms, boating, and diving, thus releasing their bacterial populations into the overlaying water.  相似文献   

Geomorphic portrait of the Little Rann of Kutch     

Vishal Gupta  A. A. Ansari 《Arabian Journal of Geosciences》2014,7(2):527-536

Little Rann of Kutch is an integral part of the Rann of Kutch, occupying southeastern part of it. It remains a saline-inundated regime, partially seasonal and partially around the year. The study area experiences a very high ambient temperature at one point of time while it gets flooded by both the tidal water ingression and freshwater poured by the seasonal rivers during the monsoon season. And as a result, the area experiences a seasonal reversal of geomorphic processes which in turn is reflected through its distinctive and dynamic landforms. Geologically, this area was a part of oceanic floor and has immerged in the recent past. Geomorphology of the area plays a dominant role in the pattern and cause of saline water intrusion. The surface of Rann is at or slightly above sea level and possesses a monotonously plain character with some outcrop in the form of sandstone capped by basalts, resembling to island in the mid of the Rann. During 3 months of the southwest monsoon, storm tides, aided by the wind, force water from the Arabian Sea over the flat surface of the Ranns. Rainfall is fairly low, so that as the water recede and evaporate, they leave behind a crust of halite and gypsum crystals which grow in the clay and sands. This monotonously saline flat surface with annual inundation, have executed the Rann a mysterious piece of terrain. The characteristics and role of sediments in terms of erosional and depositional characteristics, their plasticity, facilitating capillary rise, their hygroscopic absorption capacity, infiltration capacity, permeability, etc. gives both short- and long-term implication to the area. Apart from the above concern, the soil has a great deal to play in terms of the vegetal and faunal cover. Considering these above characteristics, study area has been regionalized in order to have a better understanding and planning for the study area. The study area being an economic zone, also confronts with several environmental problems.  相似文献   

Watershed Delineation in Flat Terrain of Thar Desert Region in North West India – A Semi Automated Approach Using DEM     

Apurba K. Bera  Vishal Singh  Niteenkumar Bankar  Sagar S. Salunkhe  J. R. Sharma 《Journal of the Indian Society of Remote Sensing》2014,42(1):187-199

Thar desert spreads in western part of Rajasthan, northern part of Gujarat, and some parts of Punjab and Haryana. The terrain is dominated by slightly sloping plains, broken by some dunes and low barren hills. The area is characterized by low average annual rainfall which is erratic in distribution and intensity. Drought will remain a major hindrance for agricultural production in Thar desert. Due to water stress condition, many watershed based development activities has been adopted by government and non-government organizations for the growth and sustainable development of this region. The need of this hour is preparation of a national level watershed atlas of 1:50,000 scale because majority of thematic maps are being produced presently on same or 1:10,000 scale. The manual delineation of watershed boundary in flat terrain based on topographic map will be time consuming and less accurate in the absence of prominent contour lines. Automated approach for watershed delineation using Digital Elevation Model (DEM) along a suitable algorithm has the advantage because the output is not only less time consuming but also independent from human decisions. Hence, a case study has been carried out in Churu sub-basin part of Indus basin which is located in Thar desert region. Depression less DEM with different spatial resolutions was used as input in hydrology tool of ArcGIS spatial analyst function for characterization of watersheds. The Churu sub-basin has been divided into various numbers of watersheds with an average size of 600 km². These watershed boundaries have been validated with respect to high resolution satellite imageries (IRS P6 LISS IV), Survey of India toposheets, ancillary data and limited field checks.  相似文献   

Mid-level clouds over the Sahara in a convection-permitting regional model     

Mantsis  Damianos F.  Sherwood  Steven  Dixit  Vishal  Morrison  Hugh  Thompson  Greg 《Climate Dynamics》2020,54(7):3425-3439

Climate Dynamics - The simulation of Saharan mid tropospheric clouds is investigated with the weather research and forecasting (WRF) regional atmospheric model at convection permitting...  相似文献   

Refined conceptualization of TOPMODEL for shallow subsurface flows     

M. Todd Walter  Tammo S. Steenhuis  Vishal K. Mehta  Dominique Thongs  Mark Zion  Elliot Schneiderman 《水文研究》2002,16(10):2041-2046

The TOPMODEL framework was used to derive expressions that account for saturated and unsaturated flow through shallow soil on a hillslope. The resulting equations were the basis for a shallow‐soil TOPMODEL (STOPMODEL). The common TOPMODEL theory implicitly assumes a water table below the entire watershed and this does not conceptually apply to systems hydrologically controlled by shallow interflow of perched groundwater. STOPMODEL provides an approach for extending TOPMODEL's conceptualization to apply to shallow, interflow‐driven watersheds by using soil moisture deficit instead of water table depth as the state variable. Deriving STOPMODEL by using a hydraulic conductivity function that changes exponentially with soil moisture content results in equations that look very similar to those commonly associated with TOPMODEL. This alternative way of conceptualizing TOPMODEL makes the modelling approach available to researchers, planners, and engineers who work in areas where TOPMODEL was previously believed to be unsuited, such as the New York City Watershed in the Catskills region of New York State. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Aluminum Consumption and Economic Growth: Evidence from Rich Countries     

Vishal Chandr Jaunky 《Natural Resources Research》2012,21(2):265-278

The article attempts to test the aluminum consumption–economic growth nexus for 20 rich economies for the period 1970–2009. Various panel data unit root and cointegration tests are applied. The series are found to be integrated of order one and cointegrated, especially after controlling for cross-sectional dependence. Moreover, the Blundell–Bond system generalized methods-of-moments is employed to conduct a panel causality test in a vector error-correction mechanism setting. Unidirectional causality running from aluminum consumption to real GDP is uncovered in the short-run, while real GDP is found to Granger-cause aluminum consumption in the long-run. Moreover, a 1% increase in real GDP generates an increase of 0.44% in aluminum consumption in the long-run for the whole panel.  相似文献   

Particle composition and size distributions in and around a deep-pit swine operation,Ames, IA   总被引：1，自引：0，他引：1  

Randal S. Martin  Philip J. Silva  Kori Moore  Mark Erupe  Vishal S. Doshi 《Journal of Atmospheric Chemistry》2008,59(2):135-150

The contribution of emissions from agricultural facilities is rapidly becoming a major concern for local and regional air quality. Characterization of particle properties such as physical size distribution and chemical composition can be valuable in understanding the processes contributing to emissions and ultimate fate of particulate matter from agricultural facilities. A measurement campaign was conducted at an Iowa, deep-pit, three-barn swine finishing facility to characterize near-source ambient particulate matter. Size-specific mass concentrations were determined using minivol samplers, with additional size distribution information obtain using optical particle counters. Particulate composition was determined via ion chromatographic analysis of the collected filters. A thermal-CO₂ elemental/organic carbon analyzer measured particulate carbon. The chemical composition and size distribution of sub-micron particles were determined via real-time aerosol mass spectrometry. Primary particulate was not found to be a major emission from the examined facility, with filter-based impactor samples showing average near-source increases (~15–50 m) in ambient PM₁₀ of 5.8 ± 2.9 μg m⁻³ above background levels. PM_2.5 also showed contribution attributable to the facility (1.7 ± 1.1 μg m⁻³). Optical particle counter analysis of the numerical size distributions showed bimodal distributions for both the upwind and downwind conditions, with maximums around 2.5 μm and below the minimum quantified diameter of 0.3 μm. The distributions showed increased numbers of coarse particles (PM₁₀) during periods when wind transport came from the barns, but the differences were not statistically significant at the 95% confidence level. The PM₁₀ aerosols showed statistically increased concentrations of sulfate, nitrate, ammonium, calcium, organic carbon, and elemental carbon when the samplers were downwind from the pig barns. Organic carbon was the major constituent of the barn-impacted particulate matter in both sub-micron (54%) and coarse size (20%) ranges. The AMS PM₁ chemical speciation showed similar species increases, with the exception of and Ca⁺², the latter not quantified by the AMS.  相似文献   

Quantifying groundwater sensitivity and resilience over peninsular India     

Nikhil Kumar  Jhilam Sinha  Chandra A. Madramootoo  Manish Kumar Goyal 《水文研究》2020,34(26):5327-5339

Groundwater in India plays an important role to support livelihoods and maintain ecosystems and the present rate of depletion of groundwater resources poses a serious threat to water security. Yet, the sensitivity of the hydrological processes governing groundwater recharge to climate variability remains unclear in the region. Here we assess the groundwater sensitivity (precipitation–recharge relationship) and its potential resilience towards climatic variability over peninsular India using a conceptual water balance model and a convex model, respectively in 54 catchments over peninsular India. Based on the model performance using a comprehensive approach (Nash Sutcliffe Efficiency [NSE], bias and variability), 24 out of 54 catchments are selected for assessment of groundwater sensitivity and its resilience. Further, a systematic approach is used to understand the changes in resilience on a temporal scale based upon the convex model and principle of critical slowing down theory. The results of the study indicate that the catchments with higher mean groundwater sensitivity (GWS) encompass high variability in GWS over the period (1988–2011), thus indicating the associated vulnerability towards hydroclimatic disturbances. Moreover, it was found that the catchments pertaining to a lower magnitude of mean resilience index incorporates a high variability in resilience index over the period (1993–2007), clearly illustrating the inherent vulnerability of these catchments. The resilience of groundwater towards climatic variability and hydroclimatic disturbances that is revealed by groundwater sensitivity is essential to understand the future impacts of changing climate on groundwater and can further facilitate effective adaptation strategies.  相似文献