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Carbonate rocks are important reservoirs for global petroleum exploration.The largest oilfield in the South China Sea,Liuhua 11-1,is distributed in the massive carbonate reef area of the Zhujiang(Pearl)River Mouth Basin.Previous studies showed that one 802.17-m-long core from well Xichen-1 in the South China Sea mainly consisted of white and light gray-white organic reefs.Recently,a Miocene whole core(161.9 m long)of well Xiyong-2,near well Xichen-1,was found to contain six layers of yellowish brown,light yellowish gray,iron black,or light yellowish gray-white organic reefs.Scanning electron microscope images of these layers reveal a typical ferroan dolomite rich in Fe(up to 29%),with the high concentrations of Mn,Cu,W,Zn,Cr,Ni,and Co.Systematic X-ray powder diffraction analysis yields a 1.9–6.1 match in phase ratio with ankerite,5.4–26.9 with dolomite,and zero with calcite,which indicate that the samples can be classified as ferroan dolomite.The iron and heavy metals are inferred to be originated from multiple volcanic eruptions of Gaojianshi Island in the Dongdao Atoll during the middle-late Miocene.These elements were dissolved in seawater,likely as a sol,and carried to Yongxing Island in the Xuande Atoll by sea currents and tides enhanced by prevailing winds,and deposited as a part of the sedimentation process in the study area.The ferroan dolomite has Sr content of (125–285)×10~(-6),which is lower than the accepted Sr boundary value of dolomite.This finding suggests that dolomitization occurred during large-scale global glacial regression in the late Miocene.The isolated Xisha carbonate platform,exposed to air,underwent freshwater leaching and dolomitization induced by mixed water,and caused the extensive Fe-Mg exchange along the organic reef profile to form ankerite and ferroan dolomite.These results may help to understand paleoceanographic environmental changes in the South China Sea during the Miocene. 相似文献
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南黄海盆地是中国海域历经54年勘探至今尚未实现工业油气发现的唯一大型含油气盆地,特别是29年前发现的白垩系黑色页岩含轻质油,属于页岩油范畴。分析了南黄海盆地白垩系勘探研究现状,提出白垩系主要分布于盆地北部,有8口井钻遇,K1系红浦口组,K2系黑泰州组,与苏北盆地近似;在最新地震测线上表现为顶蚀,与古/新近系及下伏侏罗系均呈不整合接触,斜层状分布,残留沉积,部分构成次凹的特征。通过近海灵山岛露头调查、剖面实测和包括常规生油岩有机质丰度、类型、成熟度、等离子质谱、U-Pb同位素年龄等测试,发现下白垩统多套深灰黑色含煤泥岩层,发育Ⅰ型和Ⅲ型干酪根,自由烃0.02~0.07mg/g或为零,生油潜力0.06~0.03mg/g或为零,残留有机碳1.85%~1.99%或0.70%~0.84%,氧指数4及超过10,属于2类烃源岩,分别生烃和二氧化碳气。总体认为南黄海盆地白垩系具有一定资源前景,值得开展深入分析。 相似文献
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