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Dhofar 1671 is a relatively new meteorite that previous studies suggest belongs to the Rumuruti chondrite class. Major and REE compositions are generally in agreement with average values of the R chondrites (RCs). Moderately volatile elements such as Se and Zn abundances are lower than the R chondrite values that are similar to those in ordinary chondrites (OCs). Porphyritic olivine pyroxene (POP), radial pyroxene (RP), and barred olivine (BO) chondrules are embedded in a proportionately equal volume of matrix, one of the characteristic features of RCs. Microprobe analyses demonstrate compositional zoning in chondrule and matrix olivines showing Fa‐poor interior and Fa‐rich outer zones. Precise oxygen isotope data for chondrules and matrix obtained by laser‐assisted fluorination show a genetic isotopic relationship between OCs and RCs. On the basis of our data, we propose a strong affinity between these groups and suggest that OC chondrule precursors could have interacted with a 17O‐rich matrix to form RC chondrules (i.e., ?17O shifts from ~1‰ to ~3‰). These interactions could have occurred at the same time as “exotic” clasts in brecciated samples formed such as NWA 10214 (LL3–6), Parnallee (LL3), PCA91241 (R3.8–6), and Dhofar 1671 (R3.6). We also infer that the source of the oxidation and 17O enrichment is the matrix, which may have been enriched in 17O‐rich water. The abundance of matrix in RCs relative to OCs, ensured that these rocks would be apparently more oxidized and appreciably 17O‐enriched. In situ analysis of Dhofar 1671 is recommended to further strengthen the link between OCs and RCs.  相似文献   
2.
Deforestation and associated ecological disturbances are the issues of global concern.Researchers have investigated a number of driving forces which accelerate the rate of deforestation at local and regional levels.These include poverty,population growth,market demand and prices,political instability,agricultural expansion and changes in property right and ownership regimes.This paper seeks to explore the impacts of population growth,changing tenure system and other socioeconomic factors on the forest cover of Roghani Valley,located in Hindu Raj Mountains,Northern Pakistan.The present study is mainly based on information collected through participatory observation,selfadministered interviews and questionnaire survey.Geographical Information System（GIS） database is also used for mapping and quantification.The results reveal that in the past three to four decades the study area has been subjected to severe deforestation and about half of the forest area has been converted into barren land.Thus,the area under natural forests decreased from 2099 to 1444 hectares in four decades.This large-scale deforestation is attributed to both proximate and under lying causes particularly traditional land tenure system and demographic development.Consequently,forest resources have been degraded and a number of plant species have disappeared from the forests of the study area while several others are in the process of disappearance.  相似文献   
3.
We report precise triple oxygen isotope data of bulk materials and separated fractions of several Shergotty–Nakhla–Chassigny (SNC) meteorites using enhanced laser‐assisted fluorination technique. This study shows that SNCs have remarkably identical Δ17O and a narrow range in δ18O values suggesting that these meteorites have assimilated negligibly small surface materials (<5%), which is undetectable in the oxygen isotope compositions reported here. Also, fractionation factors in coexisting silicate mineral pairs (px‐ol and mask‐ol) further demonstrate isotopic equilibrium at magmatic temperatures. We present a mass‐dependent fractionation line for bulk materials with a slope of 0.526 ± 0.016 (1SE) comparable to the slope obtained in an earlier study (0.526 ± 0.013; Franchi et al. 1999). We also present a new Martian fractionation line for SNCs constructed from separated fractions (i.e., pyroxene, olivine, and maskelynite) with a slope of 0.532 ± 0.009 (1SE). The identical fractionation lines run above and parallel to our terrestrial fractionation line with Δ17O = 0.318 ± 0.016‰ (SD) for bulk materials and 0.316 ± 0.009‰ (SD) for separated fractions. The conformity in slopes and Δ17O between bulk materials and separated fractions confirm oxygen isotope homogeneity in the Martian mantle though recent studies suggest that the Martian lithosphere may potentially have multiple oxygen isotope reservoirs.  相似文献   
4.
Oxygen isotope measurements of olivine in main group (MG) pallasites by traditional laser fluorination method are associated with some uncertainties including terrestrial weathering, incomplete olivine reaction, and sample state. We improved our laser fluorination approach by pretreating olivine grains with acid to remove terrestrial weathering products and by modifying the sample holder for an efficient and complete laser reaction. Our experiments on Brahin olivine demonstrate that acid-washing successfully removes the terrestrial weathering with <0.1‰ variation in δ18O value and, at the same time, improving the ∆17O value significantly. We also achieved a complete olivine fluorination by employing a custom-designed sample holder with “V”-shaped profile having rounded bottom because incomplete/partial reaction of olivine gives comparatively lighter δ18O values. Using these new techniques, we present precise triple oxygen isotope data (N = 72) of 25 olivine samples separated from main group pallasites. The data are, on average, ~0.5‰ heavier in δ18O relative to the values published in the literature for the same samples. Critically, the ∆17O values of MG pallasites and to some extent their Fo-contents suggest that there are at least two populations of olivine. Based on our improved data set, we propose that MG pallasites potentially have high-∆17O- and low-∆17O-bearing subgroups that are statistically distinct. The subgroups present average ∆17O values of −0.166 ± 0.003 (2SE; N = 16) and −0.220 ± 0.003 (2SE; N = 9), respectively. Furthermore, the high-∆17O-bearing subgroup samples trend toward lower Fo-contents compared to the other subgroup. Taken together, our data provide evidence that argues against a single parent body origin for MG pallasites.  相似文献   
5.
Precise triple oxygen isotope compositions of 32 Allende bulk chondrules (ABCs) are determined using laser‐assisted fluorination mass spectrometry. Various chemically characterized chondrule types show ranges in δ18O that vary from ?4.80‰ to +1.10‰ (porphyritic olivine; PO, N = 15), ?3.10‰ to +1.50‰ (porphyritic olivine pyroxene; POP, N = 9), ?3.40‰ to +2.60‰ (barred olivine; BO, N = 4), and ?3.60‰ to +1.30‰ (porphyritic pyroxene; PP, N = 3). Oxygen isotope data of these chondrules yield a regression line referred to as the Allende bulk chondrule line (ABC line, slope = 0.86 ± 0.02). Most of our data fall closer to the primitive chondrule minerals line (PCM line, slope = 0.987 ± 0.013) and the carbonaceous chondrite anhydrous mineral line (CCAM line, slope = 0.94 ± 0.02) than the Allende anhydrous mineral line (AAML, slope = 1.00 ± 0.01) with a maximum δ18O value (+2.60‰) observed in a BO chondrule and a minimum δ18O value (?4.80‰) shown by a PO chondrule. Similarly, these chondrules depict variable ?17O values that range from ?5.65‰ to ?3.25‰ (PO), ?4.60‰ to ?2.80‰ (POP), ?4.95‰ to ?3.00‰ (BO), ?5.30‰ to ?3.20‰ (PP), and ?4.90‰ (CC). A simple model is proposed for the Allende CV3 chondrite with reference to the AAML and PCM line to illustrate the isotopic variations occurred due to the aqueous alteration processes. The estimated temperature ranging from 10 to 130 °C (mean ~60 °C) implies that the secondary mineralization in Allende happened in a warmer and relatively dry environment compared to Murchison. We further propose that thermal metamorphism could have dehydrated the Allende matrix at temperatures between >150 °C and <600 °C.  相似文献   
6.
Similar to other areas of Pakistan, land resources in Khyber Pakhtunkhwa （KP） is kept under various ownership regimes for socio-economic and ecological benefits. For the last three to four decades, communal lands and resources are subjected to high rate of degradation and deterioration, which is leading to multifarious socio-economical and ecological implications. This paper intends to look into factors that are responsible for the degradation of communal land and the adaptability of the management mechanisms developed by the local inhabitants to conserve these resources. Moreover, this study also explores the sustainability of these adopted strategies in present circumstances. Data regarding socio-economic parameters of the inhabitants and their interactions with communal lands were collected through questionnaire cum interview method. As long-term climatic data for the area do not exist therefore focus group discussions were conducted to document the changing trend in rainfall regimes and temperature variations for the last about four decades. Results indicate that communal lands are highly vulnerable to degradation due to biophysical and anthropogenic factors. Local inhabitants have developed suitable measures to control the situation, however, accelerated socio-economic transformations in the area have weakened the role of local institutions and that led to further degradation of these resources. Nevertheless, a number of locally formulated rules have been revived and implemented and it is hoped that these threatened resources would be conserved.  相似文献   
7.
Mean bulk chemical data of recently found H5 and L6 ordinary chondrites from the deserts of Oman generally reflect isochemical features which are consistent with the progressive thermal metamorphism of a common, unequilibrated starting material. Relative differences in abundances range from 0.5–10% in REE (Eu = 14%), 6–13% in siderophile elements (Co = 48%), and >10% in lithophile elements (exceptions are Ba, Sr, Zr, Hf, U = >30%) between H5 and L6 groups. These differences may have accounted for variable temperature conditions during metamorphism on their parent bodies. The CI/Mg‐normalized mean abundances of refractory lithophile elements (Al, Ca, Sm, Yb, Lu, V) show no resolvable differences between H5 and L6 suggesting that both groups have experienced the same fractionation. The REE diagram shows subtle enrichment in LREE with a flat HREE pattern. Furthermore, overall mean REE abundances are ~0.6 × CI with enriched La abundance (~0.9 × CI) in both groups. Precise oxygen isotope compositions demonstrate the attainment of isotopic equilibrium by progressive thermal metamorphism following a mass‐dependent isotope fractionation trend. Both groups show a ~slope‐1/2 line on a three‐isotope plot with subtle negative deviation in ?17O associated with δ18O enrichment relative to δ17O. These deviations are interpreted as the result of liberation of water from phyllosilicates and evaporation of a fraction of the water during thermal metamorphism. The resultant isotope fractionations caused by the water loss are analogous to those occurring between silicate melt and gas phase during CAI and chondrule formation in chondrites and are controlled by cooling rates and exchange efficiency.  相似文献   
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