Temperature effects on non-bridging oxygen and aluminum coordination number in calcium aluminosilicate glasses and melts     

Jonathan F. Stebbins  Emily V. Dubinsky  Koji Kanehashi  Kimberly E. Kelsey 《Geochimica et cosmochimica acta》2008,72(3):910-925

Configurational changes with temperature are important for the thermodynamic and transport properties of most aluminosilicate melts, but in general are not well understood. Here, we present high-resolution ²⁷Al and ¹⁷O NMR data on several calcium aluminosilicate glasses prepared with varying quench rates and thus with fictive temperatures that span ranges up to about 200 K. In all compositions the content of five-coordinated aluminum increases with fictive temperature, in agreement with recent high temperature NMR data on melts. In a glass of CaAl₂Si₂O₈ (“anorthite”) composition, the content of non-bridging oxygens also increases with temperature; however this effect was not observed in a sample with a much higher CaO/Al₂O₃ ratio. We present a consistent notation for reactions among structural species in these systems that clarify why in some cases, high-coordinated network cations may appear on the same side of the reaction, while in others they occur on the opposite sides: the key difference is in accounting for all coordination changes for oxygens. Mixing of non-bridging oxygens and of high-coordinated aluminum make significant contributions to the overall configurational entropy and heat capacity of the melts, as does the mixing of various bridging oxygens and of tetrahedral network cations. Other, less well known, types of increase in disorder with temperature may be important as well.  相似文献   

Implementation of an expert system for the design of single-point, subsurface oceanographic moorings     

Santhosh Kumaran  Richard A. Skop 《Ocean Engineering》1990,17(4)

The design of single-point, subsurface moorings is carried out a present by a design engineer with the help of some computer programs. These computer programs are used for analyzing the mooring, but the setting-up of the initial mooring configuration and the subsequent modifications on the basis of the results of the analysis are carried out by the design engineer.An expert system for mooring design is developed to eliminate the human expert from the design process and thus to enable a novice to design a mooring by himself. Using the expert system, an optimum least-weight in air design can be developed in much less time than is usually required in conventional procedures. Perhaps the most significant advantage is that the system can serve as a vehicle for effective transfer of present day expertise for future applications.The system is developed and implemented on an IBM PC/AT. It has a user-friendly, interactive, menu-driven input procedure and a sophisticated output facility. The design process is totally automated and the requirement to consult a human expert is easily eliminated. The system has tremendous flexibility and a knowledge engineer can easily adapt it to the specific requirements of a particular user. The concept of machine learning is introduced by recording the failure data and using this information in the later decision-making processes. A CAD package, AUTOCAD, is used to generate the drawings and an interface is developed between the CAD package and the expert system so that the former is transparent to the user.  相似文献   

Effect of fluid-sediment reaction on hydrothermal fluxes of major elements, eastern flank of the Juan de Fuca Ridge     

Emily R. Giambalvo  Carl I. SteefelAndrew T. Fisher  Nina D. RosenbergC.Geoffrey Wheat 《Geochimica et cosmochimica acta》2002,66(10):1739-1757

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Characterizing and classifying urban watersheds with compositional and structural attributes     

Joseph M. Delesantro  Jonathan M. Duncan  Diego Riveros-Iregui  Joanna R. Blaszczak  Emily S. Bernhardt  Dean L. Urban  Lawrence E. Band 《水文研究》2021,35(9):e14339

Current land-use classifications used to assess urbanization effects on stream water quality date back to the 1980s when limited information was available to characterize watershed attributes that mediate non-point source pollution. With high resolution remote sensing and widely used GIS tools, there has been a vast increase in the availability and precision of geospatial data of built environments. In this study, we leverage geospatial data to expand the characterization of developed landscapes and create a typology that allows us to better understand the impact of complex developed landscapes across the rural to urban gradient. We assess the ability of the developed landscape typology to reveal patterns in stream water chemistry previously undetected by traditional land-cover based classification. We examine the distribution of land-cover, infrastructure, topography and geology across 3876 National Hydrography Dataset Plus catchments in the Piedmont region of North Carolina, USA. From this dataset, we generate metrics to evaluate the abundance, density and position of landscape features relative to streams, catchment outlets and topographic wetness metrics. While impervious surfaces are a key distinguishing feature of the urban landscape, sanitary infrastructure, population density and geology are better predictors of baseflow stream water chemistry. Unsupervised clustering was used to generate a distinct developed landscape typology based on the expanded, high-resolution landscape feature information. Using stream chemistry data from 37 developed headwater catchments, we compared the baseflow water chemistry grouped by traditional land-cover based classes of urbanization (rural, low, medium and high density) to our composition and structure-based classification (a nine-class typology). The typology based on 22 metrics of developed landscape composition and structure explained over 50% of the variation in NO₃⁻-N, TDN, DOC, Cl⁻, and Br⁻ concentration, while the ISC-based classification only significantly explained 23% of the variation in TDN. These results demonstrate the importance of infrastructure, population and geology in defining developed landscapes and improving discrete classes for water management.  相似文献   

New Modes of Environmental Governance in Greater Sage-Grouse Conservation in Oregon     

Katherine Wollstein  Emily Jane Davis 《社会与自然资源》2020,33(5):555-573

Abstract

Natural resource challenges often span administrative jurisdictions and include actors and processes operating at different spatial and political scales. We applied concepts of new environmental governance to analyze Oregon’s approach to greater sage-grouse conservation. Through one in-depth case study in Lake County, we traced features of new environmental governance (cross-scale interactions, decentralization, and capacities of actors) through different governance levels. Interviews and qualitative analysis revealed that decentralization of administrative functions facilitated cross-scale interactions and relied on intermediaries, gap-filling, and perceptions of legitimacy at lower levels. State and agency guidelines steered the effort and were accompanied by financial and technical resources from multiple arenas, which increased local capacity. This study adds to the understandings of environmental governance for implementing multi-actor, multi-level conservation arrangements in resource-dependent communities. Further exploration of connections between higher levels and local contexts will reveal important, new ways to link policies with on-the-ground outcomes.  相似文献   

Engagement in the Third U.S. National Climate Assessment: commitment,capacity, and communication for impact     

Emily Cloyd  Susanne C. Moser  Edward Maibach  Julie Maldonado  Tinqiao Chen 《Climatic change》2016,136(1):39-55

This paper examines the dynamics of energy investments and clean energy Research and Development (R&D) using a scenario-based modeling approach. Starting from the global scenarios proposed in the RoSE model ensemble experiment, we analyze the dynamics of investments under different assumptions regarding economic and population growth as well as availability of fossil fuel resources, in the absence of a climate policy. Our analysis indicates that economic growth and the speed of income convergence across countries matters for improvements in energy efficiency, both via dedicated R&D investments but mostly through capital-energy substitution. In contrast, fossil fuel prices, by changing the relative competitiveness of energy sources, create an economic opportunity for radical innovation in the energy sector. Indeed, our results suggest that fossil fuel availability is the key driver of investments in low carbon energy innovation. However, this innovation, by itself, is not sufficient to induce emission reductions compatible with climate stabilization objectives.  相似文献   

On the relation of vegetation and southwest monsoon rainfall over Western Ghats,India     

T. V. Lakshmi Kumar  Koteswara Rao  R. Uma  Humberto Barbosa  K. V. K. R. K. Patnaik  Emily Prabha Jothi 《Natural Hazards》2016,80(1):425-444

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Tide-Induced Variations in the Fatty Acid Composition of Estuarine Particulate Organic Matter     

Emily S. Antonio  Nicole B. Richoux 《Estuaries and Coasts》2016,39(4):1072-1083

The particulate organic matter (POM) in hydrodynamically variable habitats such as the lower reaches of estuaries can change in its content and quality on very short time scales (example, hourly), and these changes can potentially influence higher-level consumers in river-estuary-marine systems. Estuarine water samples were collected hourly for 12 h downstream in a small river to evaluate the fatty acid composition of POM over a tidal cycle. Fatty acid constituents of POM collected during the flood tide were dominated by the saturated, higher plant and bacterial fatty acids, whereas unsaturated, polyunsaturated, essential, and diatom-associated fatty acids dominated the POM collected during the ebb tide. Elevated algal biomass (as indicated by high chlorophyll a concentrations), diatom, and freshness indices in the POM indicated enhanced fresh autochthonous-origin materials that dominated the mixed organic pool during the ebb tide compared to more degraded detritus during the flood tide. Tidal retention of organic matter and algal primary production were the most influential factors that differentiated the fatty acid composition of estuarine POM over the short time scale. The results of this study have important implications on the quality of POM at the time of sampling, especially in estuaries where mixed organic pools have multiple inputs and are strongly influenced by tidal cycles.  相似文献   

An analysis of failure mechanism constraints on pre-failure rock block deformation using TLS and roto-translation methods     

Emily Rowe  D. Jean Hutchinson  Ryan A. Kromer 《Landslides》2018,15(3):409-421

Rockfall hazards increase the risk of train derailment along railway corridors in western Canada. In this study, repeated terrestrial laser scanning (TLS) datasets were collected every 2–3 months at three different sites along the Thompson and Fraser River corridors in British Columbia, referred to as the Goldpan, White Canyon, and Mile 109 sites. A total of 207 rockfall events occurring across all three sites between November 11, 2014 and October 18, 2016 were recorded in a database. For each of these rockfalls, pre-failure deformation was measured using a method of three-dimensional roto-translation block tracking. Each rockfall was classified by its deformation behaviour and further categorised based on failure mechanism, volume, lithology, and the roughness condition of the failure plane. Results reveal that detectable levels of deformation were measured in 33% of the total number of rockfall events using the present methods. Rotation deformation was most commonly observed in toppling failures with relatively steep joint orientations. Conversely, planar sliding blocks generally exhibited the least measurable deformation, with the majority not showing any precursory translation or rotation. It is postulated that overhanging rockfall configurations may suppress the expression of deformation in rockfall source blocks, though additional research is required to confirm this.  相似文献   

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)     

Emily Keeble  David I. Whiteside  Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献