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1.
Current land-use classifications used to assess urbanization effects on stream water quality date back to the 1980s when limited information was available to characterize watershed attributes that mediate non-point source pollution. With high resolution remote sensing and widely used GIS tools, there has been a vast increase in the availability and precision of geospatial data of built environments. In this study, we leverage geospatial data to expand the characterization of developed landscapes and create a typology that allows us to better understand the impact of complex developed landscapes across the rural to urban gradient. We assess the ability of the developed landscape typology to reveal patterns in stream water chemistry previously undetected by traditional land-cover based classification. We examine the distribution of land-cover, infrastructure, topography and geology across 3876 National Hydrography Dataset Plus catchments in the Piedmont region of North Carolina, USA. From this dataset, we generate metrics to evaluate the abundance, density and position of landscape features relative to streams, catchment outlets and topographic wetness metrics. While impervious surfaces are a key distinguishing feature of the urban landscape, sanitary infrastructure, population density and geology are better predictors of baseflow stream water chemistry. Unsupervised clustering was used to generate a distinct developed landscape typology based on the expanded, high-resolution landscape feature information. Using stream chemistry data from 37 developed headwater catchments, we compared the baseflow water chemistry grouped by traditional land-cover based classes of urbanization (rural, low, medium and high density) to our composition and structure-based classification (a nine-class typology). The typology based on 22 metrics of developed landscape composition and structure explained over 50% of the variation in NO3-N, TDN, DOC, Cl, and Br concentration, while the ISC-based classification only significantly explained 23% of the variation in TDN. These results demonstrate the importance of infrastructure, population and geology in defining developed landscapes and improving discrete classes for water management.  相似文献   
2.
Contemporary deposition (artificial marker horizon, 3.5 years) and long-term accumulation rates (210Pb profiles, ~150 years) of sediment and associated carbon (C), nitrogen (N), and phosphorus (P) were measured in wetlands along the tidal Savannah and Waccamaw rivers in the southeastern USA. Four sites along each river spanned an upstream-to-downstream salinification gradient, from upriver tidal freshwater forested wetland (TFFW), through moderately and highly salt-impacted forested wetlands, to oligohaline marsh downriver. Contemporary deposition rates (sediment, C, N, and P) were greatest in oligohaline marsh and lowest in TFFW along both rivers. Greater rates of deposition in oligohaline and salt-stressed forested wetlands were associated with a shift to greater clay and metal content that is likely associated with a change from low availability of watershed-derived sediment to TFFW and to greater availability of a coastal sediment source to oligohaline wetlands. Long-term accumulation rates along the Waccamaw River had the opposite spatial pattern compared to contemporary deposition, with greater rates in TFFW that declined to oligohaline marsh. Long-term sediment and elemental mass accumulation rates also were 3–9× lower than contemporary deposition rates. In comparison to other studies, sediment and associated nutrient accumulation in TFFW are lower than downriver/estuarine freshwater, oligohaline, and salt marshes, suggesting a reduced capacity for surface sedimentation (short-term) as well as shallow soil processes (long-term sedimentation) to offset sea level rise in TFFW. Nonetheless, their potentially large spatial extent suggests that TFFW have a large impact on the transport and fate of sediment and nutrients in tidal rivers and estuaries.  相似文献   
3.
Geographic Information Systems (GIS) are well suited to support environmental modeling for dealing with space. However, some of the limitations of current GIS are the lack of tools for comprehensive documentation of the models, the inadequate representation of fields, and the deficient methodology for comprehensive management of uncertainty. Using Digital Terrain Modeling and Analysis as an example, this paper proposes an enhanced approach to overcome these drawbacks. It suggests implementing sophisticated functionality for modeling and analysis of fields in special-purpose modules outside monolithic GIS. These modules include three components: (1) an extensive framework for metainformation that allows a sound assessment of the fitness-for-use of digital field representations for environmental modeling applications, (2) an explicit digital representation of the field phenomenon equipped with the appropriate tools for the derivation of data, and (3) the methods to assess the quality of derived data. A standardized interface enables communication between the module and other software components. The presented modular approach combines the functionality of common GIS with highly specialized modeling and analysis tools encapsulating expert knowledge about the represented phenomena.  相似文献   
4.
Rising northern hemispheric mean air temperatures reduce the amount of winter lake ice. These changes in lake ice cover must be understood in terms of resulting effects on lake ecosystems. Accurate predictions of lake ice phenology are essential to assess resulting impact. We applied the one-dimensional physical lake model FLake to analyse past variability in ice cover timing, intensity and duration of Berlin-Brandenburg lakes. The observed ice phenology in two lakes in the period 1961–2007 was reconstructed by FLake reasonably well and with higher accuracy than by state-of-the-art linear regression models. Additional modelling results of FLake for 38 Berlin-Brandenburg lakes, observed in the winter of 2008/09, were quite satisfactory and adequately reproduced the effects of varying lake morphology and trophic state. Observations and model results showed that deeper and clearer lakes had more ice-free winters, later ice cover freezing and earlier ice cover thawing dates, resulting in shorter ice-covered periods and fewer ice-covered days than shallow and less clear lakes. The 1947–2007 model hindcasts were implemented using FLake for eight Berlin-Brandenburg lakes without ice phenology observations. Results demonstrated past trends of later ice start and earlier ice end, shorter ice cover duration and an increase in ice-free winters.  相似文献   
5.
Diffusion of divalent cations in garnet: multi-couple experiments   总被引:1,自引:1,他引:0  
We demonstrate the possibility of studying several diffusion couples in a single run, i.e. under almost similar PTt– conditions, allowing direct comparison of the diffusion rates in different diffusion couples. Thus the duration of experimental study and the risk of failure of expensive experimental equipment can be decreased considerably. The diffusion experiments were carried out in piston-cylinder apparatus. Gem-quality garnets of almandine, spessartine and grossular compositions together with inclusion-rich eclogitic garnets were embedded in a powder of natural pyrope and annealed together under dry conditions at P = 1.9–3.2 GPa and T = 1,070–1,400°C. Diffusion profiles were measured by electron microprobe and fitted numerically on the basis of multicomponent diffusion theory. The datasets derived from different diffusion couples yields parameters of the Arrhenius equation for Ca, Mg and Fe in natural eclogitic garnets and Mg, Mn and Fe in gem-quality garnets. We have also studied the effect of grain-boundary diffusion in the sintered pyrope matrix on interdiffusion on the basis of 2D modeling. Under conditions analogous to those of our experimental runs, we show that observed irregularities in some measured diffusion profiles (not applied for the diffusion modeling) can be directly related to the superposition of local grain-boundary diffusion on dominant volume diffusion.  相似文献   
6.
Recent debates about the state of geography raise valuable questions about how the discipline can and should change in response to shifting institutional realities. Focusing on the breadth and interdisciplinarity of geography, these discussions often overlook the role of pedagogy—particularly graduate training—in adapting the discipline to new institutional landscapes. Drawing on experiences as current and recent geography doctoral students, we identify institutional seedlings of opportunity that can be cultivated toward a spectrum of alternative doctoral training models. These alternatives offer significant opportunities to better prepare early-career geographers for success and to solidify geography's position as a leader in interdisciplinary research.  相似文献   
7.
Ion waves excited by charged dust beams streaming across or along the geomagnetic field in the ionosphere may be generated by plasma instabilities during aerosol release experiments. The injection speed of the dust and gas is comparable to or larger than the ion thermal speed in the background plasma. The dust grains can get charged by plasma collection from the ambient ionosphere, and can thus act as a charged beam that excites instabilities in the background plasma. The theory is applied to relatively early time scales of the order of in the dust-gas cloud expansion, with wave frequencies that are larger than the ion gyrofrequency, and collisions with neutrals are included.  相似文献   
8.
To determine the effects of the Chesapeake Bay outflow plume on the coastal ocean, nutrient concentrations and climatology were evaluated in conjunction with nitrogen (N) and carbon (C) uptake rates during a 3-year field study. Sixteen cruises included all seasons and captured high- and low-flow freshwater input scenarios. Event-scale disturbances in freshwater flow and wind speed and direction strongly influenced the location and type of plume present and thus the biological uptake of N and C. As expected, volumetric primary productivity rates did not always correlate with chlorophyll a concentrations, suggesting that high freshwater flow does not translate into high productivity in the coastal zone; rather, high productivity was observed during periods where recycling processes may have dominated. Results suggest that timing of meteorological events, with respect to upwelling or downwelling favorable conditions, plays a crucial role in determining the impact of the estuarine plume on the coastal ocean.  相似文献   
9.
The speeds of historical cool-season extratropical cyclones along the U.S. east coast, hereafter East Coast Winter Storms (ECWS), occurring during the period from 1951 to 2006 were computed. Average storm speed was 13.8 ms−1 with stronger storms generally moving faster than weaker storms and faster storms forming during the midwinter months (December–March). There was no clear trend in ECWS speed during the time period, although considerable season-to-season variability was present. The monthly and seasonal variations in storm speed could not be attributed to the El Ni?o-Southern Oscillation or North Atlantic Oscillation (NAO) alone. However, the speed of ECWS was considerably slower when both El Ni?o and the negative phase of NAO occurred simultaneously. Characteristic patterns in the upper levels of the atmosphere, specifically 300 hPa zonal winds and 500 hPa geopotential heights, were present during periods when ECWS speeds were among the slowest (and separately fastest). For slow storm speed, these patterns also prevailed during months in which El Ni?o and negative NAO phase occurred. These patterns were also present during months with extended runs of high oceanic storm surge. This provides a qualitative link between the atmospheric conditions associated with slow storms and potentially high coastal storm surge impacts. Among the prime consequences of ECWS speed are extended periods of high storm surge, mainly due to slow-moving storms. The sustained high tidal levels often lead to substantial damage caused by coastal flooding, overwash, and beach erosion.  相似文献   
10.
Nutrient concentrations, primary productivity, and nitrogen uptake rates were measured in coastal waters of the Mid-Atlantic Bight over a two-year period that included measurements from all four seasons. In order to assess carbon productivity and nitrogen demand within the context of the physical environment, the region was divided into three distinct hydrographic regimes: the Chesapeake and Delaware Bay outflow plumes (PL), the southern Mid-Atlantic shelf influenced by the Gulf Stream (SS), and the mid-shelf area to the north of the Chesapeake Bay mouth (MS). Annual areal rates of total nitrogen (N) uptake were similar across all regions (10.9 ± 2.1 mol N m−2 y−1). However, annual areal rates of net primary productivity were higher in the outflow plume region (43 mol C m−2 y−1), than along the Mid-Atlantic shelf and in areas influenced by the Gulf Stream (41 and 34 mol C m−2 y−1, respectively). Rates of net primary productivity were not well correlated with Chl a concentrations and were uncoupled with net N uptake rates. Seasonally averaged annual areal rates of net primary productivity for the Mid-Atlantic Bight measured in this study were higher than those calculated in previous decades and provide important validation information for biogeochemical models and satellite remote sensing algorithms developed for the region.  相似文献   
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