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Abstract— We report the discovery of four large (>50 μm) cosmic spherules (CSs) and a single scoriaceous micrometeorite (SMM) that contain evidence for the separation of immiscible Fe-Ni-S liquids during atmospheric entry heating. The particles contain segregated Fe-rich regions dominated by either Ni-S-bearing Fe-oxides or iron sulphides and have textural relations that suggest these separated from the silicate portions of the particles as metallic liquids. The oxides, which may be hydrous, are thought to result from alteration of metal and sulphide. The compositions of the silicate portions of the CSs are equivalent to spherules without Fe-rich regions, implying that metallic liquids are exsolved during the heating of most spherules, but completely separate. The single SMM has a very different composition from other scoriaceous particles, and the occurrence of an exsolved metallic liquid probably indicates extreme reduction during entry heating. The pyrolysis of carbonaceous materials is the most likely explanation for reduction and suggests that the precursor material of this particle was unusually C-rich. This SMM might be, therefore, an appropriate candidate for a large melted anhydrous or smectite interplanetary dust particle (IDP). The exsolution of immiscible Fe-Ni-S liquids during entry heating will result in systematic changes in the compositions of the remaining silicate melt.  相似文献   
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Abundant dinocysts in a high-resolution core from Voldafjorden, western Norway, reflect changes in sea surface-water conditions during the last c. 11 300 BP. The period from c. 11 300 to 10 800 BP (Late Allerφd) was characterized by cool temperate surface-waters, high annual temperature variation and relatively strong stratification of the water column, which is characteristic of fjord environments. Due to the stratification of the surface waters, the uppermost layer may have warmed considerably. This generated a principal difference in temperature conditions between land and sea, with slightly higher temperatures in the marine environments. The period from c. 10 800 to 10 000 BP is characterized by very harsh conditions, with sea surface-water temperatures close to freezing and long lasting seasonal sea-ice cover. Similar temperature changes at the beginning and end of the Younger Dryas are characteristic for NW Europe, but those in Voldafjorden differ from those in the open sea and in the Norwegian Channel by being significantly larger. The stratification of the water column during the Late Allerφd was probably broken down because of incipient inflow of temperate normal saline waters, which caused a marked sea surface-water warming, at c. 10 000 BP. Surface-water conditions close to those of today were gradually established between c. 10000 and 9500 BP. However, these interglacial conditions were abruptly interrupted by a significant drop in winter sea surface-water temperature and salinity occurring around 9700 BP. From c. 9500 to 7000 BP the influence of temperate normal saline water masses increased stepwise until full interglacial conditions were established around c. 7000 BP. The change in the dinocyst assemblage around 7000 BP in Voldafjorden was probably related to the onset of the modern Norwegian Coastal Current, previously documented in cores from the Skagerrak and the Mid-Norwegian Continental Shelf. The last c. 7000 BP is characterized by relatively stable surface-water conditions, possibly interrupted by periods of cooling or decreased inflow of temperate normal saline water. Like several other dinoflagellate cyst records from the Norwegian-Greenland Sea, O. centrocarpum peak values are between 4000 and 5000 BP, suggesting a regional-scale oceanographic change.  相似文献   
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This paper presents an historical analysis (1974–97) of associations between land-cover change and socio-economic factors for three villages in a former bantustan region of South Africa. The notion of social–ecological systems is used as the conceptual framework for this analysis, in which the former bantustan region of Bushbuckridge is posited as a cultural landscape. The local landscape showed distinctive modifications over the study period, broad trends including the growth of human settlements and the decrease in woodland cover. However, changes were not uniform across sites, and the direction and magnitude of changes in land cover were often nonlinear and site-specific. Analysis of associations between biophysical and socio-economic changes at different scales revealed a range of important interacting forces such as population growth, drought, shortages of land, grazing and wood resources, weakening institutional governance of natural resources, and the diversification of livelihood strategies, including the sale of fuelwood, concurrent with declining employment security and cattle ownership. Evidence suggests a possible erosion of resilience in these social–ecological systems at various scales, with important implications for socio-economic development and sustainable resource management.  相似文献   
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Abstract— The abundances and isotopic compositions of N and Ar have been measured by stepped combustion of the Allan Hills 84001 (ALH 84001) Martian orthopyroxenite. Material described as shocked is N-poor ([N] ~ 0.34 ppm; δ15N ~ +23%); although during stepped combustion, 15N-enriched N (δ15N ~ +143%) is released in a narrow temperature interval between 700 °C and 800 °C (along with 13C-enriched C (δ13C ~ +19%) and 40Ar). Cosmogenic species are found to be negligible at this temperature; thus, the iso-topically heavy component is identified, in part, as Martian atmospheric gas trapped relatively recently in the history of ALH 84001. The N and Ar data show that ALH 84001 contains species from the Martian lithosphere, a component interpreted as ancient trapped atmosphere (in addition to the modern atmospheric species), and excess 40Ar from K decay. Deconvolution of radiogenic 40Ar from other Ar components, on the basis of end-member 36Ar/14N and 40Ar/36Ar ratios, has enabled calculation of a K-Ar age for ALH 84001 as 3.5–4.6 Ga, depending on assumed K abundance. If the component believed to be Martian palaeoatmos-phere was introduced to ALH 84001 at the time the K-Ar age was set, then the composition of the atmosphere at this time is constrained to: δ15N ≥ +200%, 40Ar/36Ar ≤ 300 and 36Ar/14N ≥ 17 × 10?5. In terms of the petrogenetic history of the meteorite, ALH 84001 crystallised soon after differentiation of the planet, may have been shocked and thermally metamorphosed in an early period of bombardment, and then subjected to a second event. This later process did not reset the K-Ar system but perhaps was responsible for introducing (recent) atmospheric gases into ALH 84001; and it might mark the time at which ALH 84001 suffered fluid alteration resulting in the formation of the plagioclase and carbonate mineral assemblages.  相似文献   
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