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1.
In order to assess in fish the maternal transfer of alkylphenolic compounds to the progeny, the identification and quantification of the labelled compounds present in oocytes and embryos was conducted after dietary exposure of mature female mosquitofish to 14C-4n-nonylphenol during vitellogenesis and embryogenesis respectively. Radioactivity found in bile and liver extracts accounted for 0.9-0.6 and 0.2-0.1% of ingested radioactivity for females exposed during vitellogenesis and embryogenesis respectively. The amount of extractable radioactivity present in oocytes and embryos was 0.19 and 0.07% of the ingested dose respectively. The radio-HPLC profiles obtained from bile, liver, oocyte and embryo extracts were similar. They showed the presence of 4n-NP-glucuronide as the major metabolite and traces of unchanged 4n-NP. The other metabolites corresponded to 8-hydroxynonylphenol, 9-(4-hydroxyphenyl)-nonanoic acid and para-hydroxybenzoic acid which is the final product of the alkyl chain oxidation. Our results indicate that exposure of ovoviviparous female fish to 4-NP during vitellogenesis and embryogenesis leads to the contamination of the progeny by 4-NP and its metabolites. 相似文献
2.
François Baudin Nicolas Tribovillard Fatima Laggoun-Défarge Eric Lichtfouse Olivier Monod & Silvia Gardin 《Sedimentology》1999,46(4):589-602
The Upper Jurassic Akkuyu Formation of south-western Turkey consists of pale-coloured carbonate facies, but includes a peculiar ‘black band’ at its base. In order to characterize the depositional environment of this level, a sedimentological, organic and inorganic geochemical study was performed on 30 samples. Three units are distinguished. Unit 1 consists of black marlstones, very rich in organic carbon (22–30%) with HI (hydrogen index) values around 600. The organic matter is an amorphous homogeneous material even at nanoscopic scale. This unit is also characterized by a very high concentration of V ( >1000 p.p.m.) and a δ13Corg value around ?26·5‰. Unit 2 shows thin-bedded black limestones with chert layers. Its organic content varies from 2% to 6%. As in unit 1, the HI values are uniformly high (600), and gas chromatography shows a high quantity of hopanes. The V concentration is also high (≈400 p.p.m.). The unit has a high Sr/Ca ratio, an organic carbon isotopic ratio close to ?28·7‰ and diffuse, nanoscopically amorphous organic material that is closely associated with pyrite. Unit 3 corresponds to the white limestones overlying the ‘black band’. This calcitic facies is almost devoid of organic carbon (<0·1%). The δ13Corg values are similar to those of unit 1 (?25·5‰ to ?26‰). Deposition occurred in a basinal environment surrounded by a carbonate platform. Primary productivity was high but not exceptional; terrestrial organic inputs were scarce. Bottom waters were probably euxinic during the deposition of unit 1. The presence of both hopane-rich and sulphur-rich nanoscopically amorphous organic matter may be the result of strong sulphate-reducing bacterial activity. Coupled with low amounts of iron, this led to intense vulcanization of the organic matter and thus good preservation. With the onset of unit 2 deposition, environmental conditions became less extreme, perhaps because of cooler water temperatures. Finally, the depositional conditions became oxic, leading to the accumulation of pale-coloured organic-poor limestones of unit 3. 相似文献
3.
Marie Coen-Aubert Olivier Monod Yves Plusquellec Francis Tourneur 《Geodinamica Acta》2013,26(1-2):68-93
A section near the Kilgen Lake (Adana Province) has yielded a fauna of rugose and tabulate corals including Disphyllum cf. rugosum (Wedekind, 1922), D. cf. curtum Hill, 1954, Wapitiphyllum sp., Thamnopora sp., and Alveolites sp. This coral assemblage is consistent with the previous Frasnian age assigned to the limestones of the Gümü?ali Formation. The rather well-preserved material provides new data on the structure and microstructure of Disphyllum and allows to describe in Thamnopora unusual calicinal morphology (septal ridges, median teeth, and pseudopercula) as well as new structures linked to the lateral increase (basal low wall, apical cul-de-sac). 相似文献
4.
G. Flouriot G. Monod Y. Valotaire A. Devaux J.-P. Cravedi 《Marine environmental research》1995,39(1-4)
Rainbow trout hepatocytes were isolated by a two step perfusion technique and maintained either in monolayer culture for 5 days or in aggregate culture for 30 days. Cytochrome P450 content decreased from day 0 to day 5 in both culture systems, and then was preserved at the same level after one month in aggregated cells. 7-Ethoxyresorufin O-deethylase (EROD) and UDP-glucuronosyl transferase were not significantly different in freshly isolated cells and in 30-day aggregated hepatocytes, whereas a substantial increase in glutathione S-transferase was observed. Two-day exposure of cells to β-naphthoflavone led to a significant increase in EROD activity in both culture systems, especially after one month of aggregation (10-fold increase). According to these results, aggregate culture of rainbow trout hepatocytes seems to be a promising in vitro model to investigate the biotransformation pathways in fish and their regulation by endogenous and exogenous compounds. 相似文献
5.
The purpose of the present study was to assess the in vitro effect of some imidazole (prochloraz, imazalil) and triazole (epoxiconazole) agricultural fungicides on gonadotropin-induced oocyte maturation in rainbow trout. Results show that prochloraz, epoxiconazole and imazalil strongly potentiated the induction of oocyte maturation by gonadotropin in a dose-dependent manner. Furthermore, 10−5 M prochloraz and epoxiconazole alone induced oocyte maturation. The mRNA biosynthesis inhibitor, actinomycin
, completely inhibited oocyte maturation induced by fungicides, suggesting that the gonadotropin-like effect of these chemicals is at least dependent on de novo gene expression. 相似文献
6.
Abstract The pre-Oligocene structure of southwest Mexico, south of the trans-Mexico volcanic axis, is investigated from Taxco (Guerrero state, abbreviation: Gro) to the Pacific coast. Three volcano-sedimentary units are recognized; from east to west the calc-alkaline Teloloapan, tholeiitic Arcelia and calc-alkaline Zihuatanejo suites. Structural and stratigraphic data show that the Teloloapan volcanic arc, active during ?Late Jurassic and early Cretaceous, was built upon continental basement. The Teloloapan lavas are overlain by the Albian–Cenomanian Morelos platform carbonates and followed by the Upper Cretaceous Mexcala flysch. In contrast, the Arcelia pillow lavas are associated with sandstones and cherts of Albian-?Cenomanian age. The Zihuatanejo arc was also installed upon continental basement and its magmatic activity was in part coeval with Arcelia magmatism. Unlike the almost undeformed Zihuatanejo volcanic rocks, all the other volcanic units are involved in east-vergent thrusting and recumbent folding associated with ductile tectonics, as well as the Late Cretaceous Mexcala flysch overlying the Morelos platform carbonates. Contrasting with previous views, the present results do not support a major mid-Cretaceous thrusting event in the study area. The new geodynamic interpretation proposed here considers that the Arcelia rocks were formed in a marginal basin situated east of the Zihuatanejo arc. Closure of this basin in Paleocene times is responsible for the east vergent thrust tectonics in SW Mexico. 相似文献
7.
S. Franois I. Sowka A. Monod B. Temime-Roussel J.M. Laugier H. Wortham 《Atmospheric Research》2005,74(1-4):525-545
An online automated instrument was developed for atmospheric measurements of hydroperoxides with separation and quantification of H2O2 and several organic hydroperoxides. Samples were trapped in aqueous solutions in a scrubbing glass coil. Analyses were performed on an HPLC column followed by para-hydroxyphenylacetic acid (POPHA) acetic acid and peroxidase derivatization and fluorescence detection. Analytical and sampling tests were performed on different parameters to obtain optimum signal-to-noise ratios, high resolution and collection efficiencies higher than 95% for H2O2 and organic hydroperoxides. The obtained performances show large improvements compared to previous studies. The sampling and analytical devices can be coupled providing an online analyzer. The device was used during two field campaigns in the Marseilles area in June 2001 (offline analyzer) and in July 2002 (online analyzer) at rural sites at low and high altitudes, respectively, during the ESCOMPTE and BOND campaigns. During the ESCOMPTE campaign, H2O2 was detected occasionally, and no organic hydroperoxides was observed. During the BOND campaign, substantial amounts of H2O2 and 1−HEHP+MHP were often detected, and two other organic hydroperoxides were occasionally detected. These observations are discussed. 相似文献
8.
Erdal Kosun André Poisson Attila Çiner Roland Wernli Olivier Monod 《Journal of Asian Earth Sciences》2009,34(3):466-479
The Çatallar Basin is one of the Miocene basins located in the southern part of the Bey Da?lar? Massif (SW Turkey). This basin has been reinvestigated and new stratigraphic and sedimentological data are now presented. The Çatallar Basin lies in paraconformity on the Bey Da?lar? carbonate platform of Late Cretaceous to Palaeogene age. It consists of an impersistent, shallow-marine carbonate base (Karabay?r formation, Late Oligocene to Early Burdigalian) followed by an onlapping detrital sequence including the Akçay and Ba?beleni formations (Langhian to Serravallian). The Akçay formation mainly contains turbidites in which several debris-flows and olistostromes are intercalated. The lowest debris flows derive from the local carbonate platforms of Cretaceous and Palaeogene age. Higher, the debris flows and olistostromes contain large carbonate blocks deriving from nearby sources (Bey Da?lar? platform carbonates), whereas the accompanying pebbles originate from the allochthonous ophiolitic units located farther to the north (Lycian Nappes) or to the east (Antalya Nappes). The origin of these ophiolitic detritus is a matter of debate. The new data obtained in this study favour a northern origin. 相似文献
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10.
Triassic blueschists and eclogites from northwest Turkey: vestiges of the Paleo-Tethyan subduction 总被引：1，自引：0，他引：1
Triassic eclogite and blueschist facies rocks occur as a thrust sheet, 25-km long and over 2-km thick, in an Eocene fold-and-thrust belt in northwest Turkey along the
zmir–Ankara suture. The thrust sheet consists mainly of metabasites with minor marble, phyllite and metachert, and rare lenses of serpentinite. The common blueschist facies mineral assemblage in the metabasites is sodic amphibole+epidote+albite+chlorite+phengite±garnet. Sodic amphibole commonly shows replacement by barroisite, and there is continuous petrographic transition from blueschist–metabasites to barroisite-bearing epidote–amphibolites. Eclogite with the mineral assemblage of garnet+sodic pyroxene+sodic–calcic amphibole+epidote is found only in one locality. P–T conditions of the epidote–blueschist facies metamorphism are estimated as 450±50 °C and 11±2 kbar. The blueschist formation was followed by a decrease in pressure and increase in temperature, leading to the development of barroisite-bearing epidote–amphibolites. Phengite, sodic amphibole and barroisite Ar/Ar ages from three metabasic rocks range between 215 and 205 Ma, and indicate Late Triassic high-pressure metamorphism. The Triassic blueschists in northwest Turkey constitute part of a much larger allochthonous tectonic unit of Triassic mafic volcanic rocks. They probably represent the upper layers of a Triassic oceanic plateau, which was accreted to the Laurasian margin during the latest Triassic. The close spatial association of the Triassic and Cretaceous blueschists along the
zmir–Ankara suture suggests that the suture represents a long-lived plate boundary of Late Palaeozoic to early Tertiary age. 相似文献