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Durability of building stones is an important issue in sustainable development. Crystallization of soluble salts is recognized as one of the most destructive weathering agents of building stones. For this reason, durability of Ghaleh-khargushi rhyodacite and Gorid andesite from Iran was investigated against sodium sulfate crystallization aging test. Petrographic and physico-mechanical properties and pore size distribution of these stones were examined before and after the aging test. The characteristics of the microcracks were quantified with fluorescence-impregnated thin sections. Durability and physico-mechanical characteristics of Ghaleh-khargushi rhyodacite are mainly influenced by preferentially oriented preexisting microcracks. Stress induced by salt crystallization led to the widening of preexisting microcracks in Ghaleh-khargushi rhyodacite, as confirmed by the pore size distributions before and after the aging test. The preexisting microcracks of Gorid andesite were attributed to the mechanical stress induced by contraction of lava during cooling. The number of transcrystalline microcracks was significantly increased after the aging test. The degree of plagioclase microcracking was proportional to its size. Durability of the studied stones depends on initial physico-mechanical properties, pore size distribution, and orientation of microcracks. Initial effective porosity is found to be a good indicator of the stones’ durability. Salt crystallization resulted in an increase in the effective porosity with a parallel decrease in the wave velocities. Surface microroughness parameters increased with the development of salt crystallization-induced microcracking. Gorid andesite showed higher quality and durability than Ghaleh-khargushi rhyodacite.  相似文献   
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Natural Resources Research - This contribution proposes a spatially weighted factor analysis (SWFA) to recognize effectively the underlying mineralization-related feature(s) in geochemical signals....  相似文献   
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A sensitive, reliable, and environmentally friendly method for simple separation and preconcentration of Ag(I) traces in aqueous samples is presented prior to their flame atomic absorption spectrometric determinations. At pH 7.0, Ag(I) was separated with 2‐(2‐methoxyphenyl)benzimidazole (MPBI) as a new complexing agent and floated after adding sodium dodecyl sulfate (SDS) as a foaming reagent. The floated layer was then dissolved in proper amount of concentrated nitric acid in methanol and introduced to the flame atomic absorption spectrometer (FAAS). The effects of pH, concentration of MPBI, type and amount of surfactant as the floating agent, type and amount of eluting agent, and influence of foreign ions on the recovery of the analyte ion were investigated. Also, using a nonlinear curve fitting method, the formation constant of 1.62 × 106 was obtained for Ag(I)–MPBI complex. The analytical curve was linear in the range of 1.8 × 10?7–1.7 × 10?6 mol/L for determination of Ag(I). The relative standard deviation (RSD; N = 10) corresponding to 0.7 × 10?6 mol/L of Ag(I), the limit of detection (10 blanks), and the enrichment factor were obtained as 1.7%, 2.9 × 10?8 mol/L, and 43.0, respectively. The proposed procedure was then applied successfully for determination of silver ions in different water samples.  相似文献   
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ABSTRACT

Nowadays, mathematical models are widely used to predict climate processes, but little has been done to compare the models. In this study, multiple linear regression (MLR), multi-layer perceptron (MLP) network and adaptive neuro-fuzzy inference system (ANFIS) models were compared for precipitation forecasting. The large-scale climate signals were considered as inputs to the applied models. After selecting the most effective climate indices, the effects of large-scale climate signals on the seasonal standardized precipitation index (SPI) of the Maharlu-Bakhtaran catchment, Iran, simultaneously and with a delay, was analysed using a cross-correlation function. Hence, the SPI time series was forecasted up to four time intervals using MLR, MLP and ANFIS. The results showed that most of the indices were significant with SPI of different lag times. Comparison of the SPI forecast results by MLR, MLP and ANFIS models showed better performance for the MLP network than the other two models (RMSE = 0.86, MAE = 0.74 for the first step ahead of SPI forecasting).
Editor D. Koutsoyiannis; Associate editor F. Pappenberger  相似文献   
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A weight vector representing the relative importance of various characteristics of ground motions (GMs) and a conditioning intensity measure (IM) are required to be able to use the generalized conditional IM framework for the purpose of GM selection. An inappropriate weight vector may result in the biased distributions of some important characteristics of GMs and, consequently, the bias in the structural responses. This article aims to provide the analyst with the understanding of which properties of GMs are important in capturing the accurate structural responses, to specifically assign a suitable weight to them and to select an appropriate conditioning IM as well. To this end, 4 reinforced concrete buildings, located at the site in which the seismic hazard is dominated by shallow crustal earthquakes, are considered. The findings reveal that the appropriate weight vectors depend on the characteristics of the employed structural systems. In addition, the role played by each IM in capturing the true structural responses changes over different earthquake intensity levels implying that different weight vectors are required over different earthquake levels. Furthermore, this study shows that, even in case of shorter‐duration GMs from shallow events, GM duration should be incorporated in GM selection as it has effects on the peak‐based structural responses in the earthquake levels beyond the level of 2%‐in‐50‐years. Specifically, the findings reveal that in case of shallow events, unlike large magnitude earthquakes, the shorter the duration of GM the more rapid release of energy and, consequently, the larger the peak‐based structural responses.  相似文献   
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Decorrelation or reduction theory deals with identifying appropriate lattice bases that aid in accelerating integer search to find the optimal integer solution of the weighted integer least squares problem. Orthogonality defect has been widely used to measure the degree of orthogonality of the reduced lattice bases for many years. This contribution presents an upper bound for the number of integer candidates in the integer search process. This upper bound is shown to be a product of three factors: (1) the orthogonality defect, (2) the absolute value of the determinant of the inverse of the generator matrix of the lattice, and (3) the radius of the search space raised to the power of the dimension of the integer ambiguity vector. Four well-known decorrelation algorithms, namely LLL, LAMBDA, MLAMBDA, and Seysen, are compared. Many simulated data with varying condition numbers and dimensions as well as real GPS data show that the Seysen reduction algorithm reduces the condition number much better than the other algorithms. Also, the number of integer candidates, before and after the reduction process, is counted for all algorithms. Comparing the number of integer candidates, condition numbers, and orthogonality defect reveals that reducing the condition number and the orthogonality defect may not necessarily result in decreasing the number of integer candidates in the search process. Therefore, contrary to the common belief, reducing the orthogonality defect and condition number do not always result in faster integer least squares estimation. The results indicate that LAMBDA and MLAMBDA perform much better in reducing the number of integer candidates than the other two algorithms, despite having a larger orthogonality defect and condition number in some cases. Therefore, these two algorithms can speed up the integer least squares estimation problem in general and the integer ambiguity resolution problem in particular.  相似文献   
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Large-scale annual climate indices were used to forecast annual drought conditions in the Maharlu-Bakhtegan watershed,located in Iran,using a neuro-fuzzy model.The Standardized Precipitation Index(SPI) was used as a proxy for drought conditions.Among the 45 climate indices considered,eight identified as most relevant were the Atlantic Multidecadal Oscillation(AMO),Atlantic Meridional Mode(AMM),the Bivariate ENSO Time series(BEST),the East Central Tropical Pacific Surface Temperature(NINO 3.4),the Central Tropical Pacific Surface Temperature(NINO 4),the North Tropical Atlantic Index(NTA),the Southern Oscillation Index(SOI),and the Tropical Northern Atlantic Index(TNA).These indices accounted for 81% of the variance in the Principal Components Analysis(PCA) method.The Atlantic surface temperature(SST:Atlantic) had an inverse relationship with SPI,and the AMM index had the highest correlation.Drought forecasts of neuro-fuzzy model demonstrate better prediction at a two-year lag compared to a stepwise regression model.  相似文献   
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