Since most coalfields in China are commonly characterized by high gas content and low permeability, there is an urgent need to improve coal seam permeability and further enhance coal bed methane (CBM) extraction efficiency. As an emerging fracturing technology, the CO₂ gas fracturing (CGF) technology has been widely used because of its advantages of low cost, environmental protection and high fragmentation efficiency. In order to improve the fracturing ability of CGF technique and optimize the release orifices of discharge head, computational fluid dynamics model was used in this paper to simulate the flow fields of dynamic pressure of gas jet released from the orifices with different structures and other geometrical parameters. The results show that the orifice structure has a great influence on the flow field of gas jet, but little influence on the magnitude of the dynamic pressure. Besides, the maximum dynamic pressure of gas jet linearly decreases with the increase in the number of release orifices. Based on a series of simulation results, the discharge head which has single group of orifices with structure c, diameter of 24 mm can be identified as the best choice for fieldwork. Then, two field experiments were conducted in Pingdingshan and Changping coal mines to evaluate the enhanced CBM extraction efficiency by CGF. The results indicate that the CGF can effectively create a large number of cracks in a large range around the fracturing borehole in the coal seam and further significantly improve the permeability. And the CBM extraction efficiency can be improved to a higher level from a lower level and maintained for a long time. Besides, the effective influence radii caused by CGF in Pingdingshan and Changping coal mines are 15.19 m and 12.5 m, respectively. Compared with other fracturing techniques, the CGF technique has a promising application prospect.