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1.
The unexplored area of Azarhare in central Morocco is studied thanks to three sections composed of five lithological facies Main biostratigraphical and sedimentological results concern (1) the identification of Late Visean biozones, with important presence of problematic algae Ungdarella, (2) the regional extension of deposit sequences SD5, SD6 and SD7 previously defined, (3) and an analysis of the diagenetic kaolinite. To cite this article: A. Karim et al., C. R. Geoscience 337 (2005).  相似文献   
2.
Magnetic properties of sediments from a core (10 m long) in the southern basin of the Caspian Sea have been investigated. Varying concentrations of greigite (Fe3S4) dominate the magnetic fraction in Late Pleistocene sediments. The synsedimentary formation of greigite indicates that the Late Pleistocene Caspian Sea was a brackish or fresh-water, poorly ventilated basin and suggests a water level higher than at the present. The variation in magnetic parameters, with the detrital magnetite-bearing fraction remaining constant, is interpreted in terms of greigite grain-size variation and related to the slight variation in water salinity. The Holocene sediments are characterized by detrital magnetite. This indicates better ventilation of the basin and suggests lower water levels than in the Late Pleistocene. The gradual change in magnetic properties of the sediments between 90 and ≈60 cm depth, with decreasing quantities of greigite, indicates stepwise establishment of oxic conditions in the Holocene.  相似文献   
3.
Cored sediments from the Pigmy Basin, northern Gulf of Mexico, were analyzed in order to better constrain late deglacial and early Holocene paleoenvironmental and sedimentary changes in response to North American climate evolution. Mineralogical and geochemical proxies indicate the succession of two sedimentary regimes: dominantly detrital during the deglaciation (15–12.9 cal ka BP) whereas biogenic contribution relatively increased later on during the Younger Dryas and early Holocene (12.9 and 10 cal ka BP). Geochemical data reveal that the deglacial record mainly reflects variations of terrigenous supply via the Mississippi River rather than modifications of redox conditions in the basin. Specific variations of almost all the parameters measured in this paper are synchronous with the main deglacial meltwater episode (Meltwater Spike) described or modeled in previous marine or continental studies. During this episode, most parameters display “stair-step-like” – pattern variations highlighting three successive steps within the main meltwater flow. Variations in grain-size and clay mineral assemblage recorded in the Pigmy Basin indicate that the erosional regime was very strong on land during the first part of the Meltwater Spike, and then milder, inducing more subtle modifications in the sedimentary regime in this part of the Gulf. Specific geochemical and mineralogical signatures (notably, clay minerals and trace metal geochemistry) pinpoint a dominant origin from NW North America for detrital particles reflecting meltwater outflow from the south-western Laurentide Ice Sheet (LIS) margin during the most intense freshwater discharge. The observed decrease of the sedimentation rate from about 200 to 25 cm/ka at ca 12.9 ka evidenced a drastic decrease of erosional processes during late phase of discharge, consistently with the hypotheses of major reduction of meltwater flow. The major modification at 12.9 cal ka BP is interpreted to result from both modifications of the main Mississippi fluvial regime due to eastward and northward rerouting of meltwater flow at the onset of the Younger Dryas, and the increase of sea-surface temperature linked to insolation. Finally, slight grain-size modifications suggest that some freshwater discharges may have episodically reached the Gulf of Mexico after the Younger Dryas reflecting possible small adjustments of the postglacial hydrological regime.  相似文献   
4.
The Late Devonian was a period of drastic environmental changes, as exemplified by a major biotic crisis at the Frasnian–Famennian boundary (FFB) and the onset in Famennian times of glaciations across southern Gondwana. Worldwide evidence for the coeval development of the major Acadian–Eovariscan belt led us to propose a model relating the Late Frasnian–Famennian environmental perturbations to extensive continental uplift through two atmospheric CO2-depleting mechanisms: (1) the intensification of silicate weathering on the continental areas as attested by a major rise in the 87Sr/86Sr composition of sea water at the FFB; and (2) the massive burial of organic carbon (Kellwasser events) in partially confined basins due to the collisional-induced reduction of equatorial oceanic communications between the Palaeotethysian and Panthalassic oceans. This process is also suggested to have been controlled by an important primary productivity connected to an increased nutrient availability triggered by the enhanced continental run-off.  相似文献   
5.
The Upper Jurassic Akkuyu Formation of south-western Turkey consists of pale-coloured carbonate facies, but includes a peculiar ‘black band’ at its base. In order to characterize the depositional environment of this level, a sedimentological, organic and inorganic geochemical study was performed on 30 samples. Three units are distinguished. Unit 1 consists of black marlstones, very rich in organic carbon (22–30%) with HI (hydrogen index) values around 600. The organic matter is an amorphous homogeneous material even at nanoscopic scale. This unit is also characterized by a very high concentration of V ( >1000 p.p.m.) and a δ13Corg value around ?26·5‰. Unit 2 shows thin-bedded black limestones with chert layers. Its organic content varies from 2% to 6%. As in unit 1, the HI values are uniformly high (600), and gas chromatography shows a high quantity of hopanes. The V concentration is also high (≈400 p.p.m.). The unit has a high Sr/Ca ratio, an organic carbon isotopic ratio close to ?28·7‰ and diffuse, nanoscopically amorphous organic material that is closely associated with pyrite. Unit 3 corresponds to the white limestones overlying the ‘black band’. This calcitic facies is almost devoid of organic carbon (<0·1%). The δ13Corg values are similar to those of unit 1 (?25·5‰ to ?26‰). Deposition occurred in a basinal environment surrounded by a carbonate platform. Primary productivity was high but not exceptional; terrestrial organic inputs were scarce. Bottom waters were probably euxinic during the deposition of unit 1. The presence of both hopane-rich and sulphur-rich nanoscopically amorphous organic matter may be the result of strong sulphate-reducing bacterial activity. Coupled with low amounts of iron, this led to intense vulcanization of the organic matter and thus good preservation. With the onset of unit 2 deposition, environmental conditions became less extreme, perhaps because of cooler water temperatures. Finally, the depositional conditions became oxic, leading to the accumulation of pale-coloured organic-poor limestones of unit 3.  相似文献   
6.
Testate amoebae are increasingly used for environmental monitoring as well as paleoenvironmental reconstructions. Paleoecological interpretations of testate amoebae assemblages depend on the understanding of the ecological processes operating today. We then ask the question of the link between testate structure and its environment. This study analyses both the grain size and mineralogical assemblage of tests of common species belonging to the genus Centropyxis and Difflugia. It is concluded that grain size is a limiting factor for test construction, whereas mineral composition is not. Hence, when analyzing agglutinated testate amoebae for paleoenvironmental reconstructions, it should be taken into account the mean grain size of the sediment. A non-appropriate grain-size probably inhibits the development of a testate amoebae specific assemblage.  相似文献   
7.
The late-Kimmeridgian Southern Jura (France) is a carbonate platform where laminated limestones accumulated locally (notably at Orbagnoux). The two types of laminations encountered result either from particle settling in a very quiet environment or from bacterial mat growth. In the latter case, as revealed by acid etching, the dark-coloured laminae result from filamentous cyanobacteria developments, whereas the light-coloured laminae appear, surprisingly, to comprise packed peloids. These peloids are interpreted as originating from the in vivo or shortly post mortem calcification of sheaths of coccoid cyanobacteria in an environment loaded by temporary excess alkalinity (and possible H2S emissions). Thus, a simple etching treatment reveals the unsuspected, albeit prominent, role of cyanobacteria in the genesis of the limestones from Orbagnoux. As such facies are widespread in Late Jurassic records, the role of cyanobacteria in their formation deserves re-evaluation.  相似文献   
8.
The early Miocene Pedregoso Formation is one of the numerous formations rich in organic matter within the stratigraphic record of the Urumaco Trough, in the central area of the Falcón Basin. Due to its lithological characteristics and stratigraphic position, this formation is of great interest regarding the basin's petroliferous systems. The evaluation of various inorganic and organic geochemical parameters indicates that the organic matter is primarily of marine origin, deposited in a marine carbonate environment typical of reefal systems, under oxic-to-dysoxic conditions. The low variability in the TOC concentrations and in the distributions of the biomarkers extracted from the samples suggests that the paleoenvironmental conditions and the organic-matter supply remained approximately constant throughout the sedimentation of this unit. The Pedregoso type-II organic matter (marine origin) and initial organic richness value (∼1.8%) suggest that this unit has probably generated hydrocarbons within the Urumaco Trough. However, present-day thermal maturity parameters reveal that the Pedregoso organic matter is overmature (dry gas window), indicating that this unit is only capable to generate gas. In addition, the geothermal gradient, maturity parameters, and the maximum paleotemperature estimated in this study suggest that the Pedregoso Formation reached a maximum burial depth the ∼6.5 km, consistent with the value obtained from data of stratigraphic thickness in the Urumaco Trough. This implies that the thermal anomaly that affected the basin during the Late Eocene–Early Miocene did not reach the central part of the basin, and therefore, the organic matter maturation in this unit is due to the sedimentary burial.  相似文献   
9.
Francolite (carbonate-fluor-apatite) is known to form in sediments where intense organic-matter decay occurs, but under oxic-to-suboxic conditions, because the alkalinity rise accompanying bacterial sulfate reduction (anoxic conditions) increases francolite solubility, hence preventing its supersaturation and precipitation. However, lagoonal, organic matter-rich, cryptalgal carbonates of Jurassic age located in the French Jura Mountains contain francolite that formed during early diagenesis, under anoxic-sulfidic and highly alkaline conditions. To explain this paradoxical situation, we propose the following “chain of reactions”: the presence of abundant biomass in the sediment would supply the “raw material” to the reactional system, i.e., the initial P budget, released through organic decay. The development of cryptalgal, bacterial mats at the sediment–water interface would have limited exchanges between the water column and the pore space, hampering pore water renewal and favoring the early onset of sulfate-reducing reactions. The onset of sulfate reduction would increase pore water alkalinity, potentially preventing francolite precipitation. In addition, the presence of sulfide ions would induce organic matter sulfurization, resulting in a relative pH rise. Alkalinity and pH rises would trigger the development of conditions leading to carbonate supersaturation, inducing bacterial-structure calcification. The sudden fall in alkalinity induced by early calcification would allow francolite precipitation, despite sulfidic conditions.  相似文献   
10.
Germanium and silicon, dissolved in seawater, are considered to be incorporated into biogenic opal with no or little fractionation, which permitted to use diatoms as reliable recorders of seawater Ge/Si. Does some fractionation occur during diagenesis, preventing the use of Ge/Si in ancient sediments? We examined the Ge/Si ratio of fossil sponges and flint nodules of the Cretaceous Chalk Formation of northern France. Though disputed, silica in this formation is considered to originate from sponges. No fractionation is observed between sponges and diagenetic flints, which allows us to observe whether Ge/Si bears a biogenic or detrital signature. We may thus confirm that sponges were the main silica supplier during the chalk deposition. The Ge/Si ratio may be used to identify a biogenic signature in cherts where the origin of silica is dubious.  相似文献   
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