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西藏西部与班公湖特提斯洋盆俯冲相关的火成岩年代学和地球化学 总被引：32，自引：1，他引：31
对青藏高原西北部班公湖缝合带开展了野外地质调查,初步查明区内缝合带至少包含日土和狮泉河-改则两条蛇绿岩带。在两条蛇绿岩带北侧发现各有两期岛弧型岩浆岩发育,且形成时间严格对应。岩石地球化学分析表明,班公湖缝合带岛弧型岩浆岩的共同特征是富集大离子不相容元素Rb、Th、K和Pb;强烈亏损高场强元素Nb、Ta和Ti;Ba在微量元素蛛网图中总是相对亏损,这些特征说明班公湖地区存在两条俯冲带。从演化序列看,俯冲初期岩石属中钾钙碱性系列,之后岛弧岩浆作用向高钾钙碱性系列演变。锆石U—PbLA—ICPMS定年结果表明,北面的日土俯冲带洋壳俯冲从辉长岩墙开始,时代为（165．5±1．9）Ma（MSWD=1．16）,在159Ma时岛弧岩浆作用规模增大,形成小型的花岗岩基;南面的狮泉河-改则俯冲带一开始俯冲（（166．4±2．0）Ma,MSWD=3．0）就有较大规模的石英闪长岩体侵入,之后岩浆作用减弱,到159．4Ma时只有一些小体积的花岗斑岩和闪长玢岩侵入。根据岛弧岩浆作用规模,认为班公湖中特提斯洋盆的俯冲一开始是以狮泉河俯冲带为主,之后狮泉河俯冲带的俯冲作用逐渐减弱。到晚侏罗世初（159Ma）北面的日土俯冲带成为洋壳俯冲的主体。鉴于两条岛弧火成岩带在空间配置上都位于由基性-超基性岩构成的蛇绿岩带北侧,地球化学上显示陆缘弧特征,因此,认为班公湖中特提斯洋盆应该是在中侏罗世晚期（约166Ma）沿日土和狮泉河两条俯冲带同时向北俯冲,构造属性上可能不是一个统一的大洋,而是包含了多个局限性洋盆。 相似文献
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The organic composition and organic‐inorganic interaction in paper mill sludge (PS) solvent extracts (hexane, ethyl acetate, acetone and ethanol) and humic fractions, humic acid (HA) and humin (HU) were studied by electron paramagnetic resonance spectroscopy (EPR), proton and carbon‐13 nuclear magnetic resonance spectroscopy (1H NMR; 13C NMR), Fourier‐transformed infrared spectroscopy (FTIR), and ultraviolet‐visible spectroscopy (UV‐vis). The strategy of fractionating the PS, sequentially, with organic solvents of increasing polarity is a reliable analytical procedure for humic substance sample separation because it results in more purified fractions. FTIR, 1H NMR and 13C NMR results showed that hexane extract consisted mainly of aliphatic hydrocarbon structures. Their contents in the extracts decreased as the polarity of the extracting solvent increased and the content of oxygen functional groups increased. Carboxylic and carboxylate functional groups were found in the acetone extract, and ester and ether functions were predominantly found in the ethanol extract. EPR spectra revealed some Fe3+ complexes with rhombic structure (g1 = 4.3; g2 = 9.0) in the humic fractions and in all solvent extracts, except hexane. Quasi‐octahedral Fe3+ complexes (g = 2.3; ΔHpp ≤ 400 G) were found in the HU fraction and in the acetone extract. The organic free radical content in the HA fraction was higher than the non‐fractionated PS sample and HU fraction. 相似文献
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Selected samples of dissolved organic matter (DOM) isolated by ultrafiltration (UDOM) have been analyzed by thermochemolysis in the presence of tetramethylammonium hydroxide (TMAH). This technique cleaves ester and ether bonds of bio‐ and geological macromolecules and releases monomer subunits and methylates them in situ as their methyl ethers and methyl esters. Compared with conventional pyrolysis, TMAH thermochemolysis avoids decarboxylation of preexisting carboxylic moieties and produces aromatic acids as their methyl esters. Various phenolic derivatives, which might originate from incorporated lignin‐derived structures, from the highly aliphatic and resistant biopolymer cutan and also from proteinaceous materials, were identified among the products produced from UDOM upon thermochemolysis. The presence of lignin derivatives in UDOM indicates input of organic matter derived from terrestrial sources. Various aromatic acids, perhaps representing the final steps in the oxidation of the side‐chain during microbial oxidation of lignin, were released upon TMAH thermochemolysis, suggesting they are structural constituents of the UDOM. Different ratios of lignin‐derived materials, commonly determined using the CuO oxidation method, such as the Δ value, indicative of the amount of lignin present, the acid/aldehyde ratio (Ad/Al)G, indicative of the extent of oxidative degradation of the lignin component, and the syringyl/guaiacyl (S/G) and p‐hydroxyphenyl/guaiacyl (P/G) ratios, indicative of the contribution for the different types of lignin, were determined. 相似文献
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Lang Ganghua 《中国海洋大学学报(自然科学版)》2000,30(Z1):122-128
在对养殖中国对虾和海捕中国对虾的类淋巴 器官进行组织培养时,发现迁出的细胞空泡化、细胞内颗粒较多。培养一周后由养殖中国对 虾类淋巴组织迁出的细胞开始大量脱落,而由海捕中国对虾类淋巴组织培养出的细胞可生长 30d左右。对未经培养的类淋巴组织及培养的类淋巴组织进行透射电镜观察,发现在养殖中 国对虾类淋巴组织的细胞中除了有球形病毒及球状和多面体状病毒包涵体外,在细胞质中还 含有大量类立克次氏体样原核生物,而且每个细胞中的类立克次氏体均由一单层膜包在一起 ;在海捕中国对虾类淋巴组织的细胞中也发现有球形病毒及球状病毒包涵体,另外还在少量 细胞中发现有类立克次氏体样原核生物存在。感染病毒的组织细胞呈现空泡化、核膜肿胀破 裂、核质固缩、高尔基体肿胀、线粒体嵴消失等病理变化。感染有类立克次氏体样原核生物 的细胞不同程度地呈现出细胞器消失、核染色质固缩等病理结构。 相似文献
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The degradation of dissolved organic matter (DOM) was studied in alkaline solution. The products were characterised using UV/vis spectroscopy, size‐exclusion chromatography (SEC), and by the analysis of low‐molecular‐weight organic acids (LMWOA). The degradation experiments were performed with water from a brown water lake or its isolated fulvic acid fraction and sodium hydroxide at different reaction times and temperatures. Depending on the wavelength and the reaction time, the UV/vis absorbance between 230 nm and 600 nm increased or decreased. The behaviour of model compounds during reactions in alkaline media was compared to the UV/vis spectroscopic behaviour of DOM. The release of LMWOA was described by kinetic data and compared to the data of model reactions. Evidence was given for the carboxylic esters playing a significant role in the release of LMWOA only during the beginning of the alkaline degradation. The results gained by SEC with on‐line UV and DOC detection showed that the average size of DOM was decreasing, and that a major part of the degradation products consisted of low‐molecular‐weight mono‐ and dicarboxylic acids. 相似文献
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In natural waters arsenic concentrations up to a few milligrams per litre were measured. The natural content of arsenic found in soils varies between 0.01 mg/kg and a few hundred milligrams per kilogram. Anthropogenic sources of arsenic in the environment are the smelting of ores, the burning of coal, and the use of arsenic compounds in many products and production processes in the past. A lot of arsenic compounds are toxic and cause acute and chronic poisoning. In aqueous environment the inorganic arsenic species arsenite (As(III)) and arsenate (As(V)) are the most abundant species. The mobility of these species is influenced by the pH value, the redox potential, and the presence of adsorbents such as oxides and hydroxides of Fe(III), Al(III), Mn(III/IV), humic substances, and clay minerals. 相似文献
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干旱半干旱区山地土壤水分动态变化 总被引：100，自引：1，他引：100
水分是干旱半干旱区山地植物生长的主要限制因子，在这些地区开展土壤水分动态变化研究对农业生产和生态恢复的重要性是不言而喻的。近年来土壤水分测定技术有了很大进步，中子水分仪和时城反射仪已成为常规测量仪器，新型仪器不断出现，总的趋势是仪器的精度和自动化水平不断提高。土壤水分有其时空变化规律，一方面土壤水分随季节变化而变化，另一方面土壤水分随土壤深度和水平位置的变化发生相应变化。降水是影响干旱半干旱区山地土壤水分的最重要因素，气温、太阳辐射等其它气象因子对土壤含水量也用一定影响。此外，坡向、坡度、坡位等地形因子以及土壤特性、地表植被、土地利用情况等对土壤含水量空间分布也有重要影响。总之土壤含水量的时空变化是各种环境因子综合作用的结果。目前土壤水分动态变化的研究重点是对其影响因子的研究。就我国而言，宜加强干旱河谷区土壤水分动态变化的研究，促进土壤水分动态变化研究工作全面深入地开展。 相似文献
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The purpose of the study is to gain a better understanding about the formation of THM (trihalomethanes), HAA (haloacetic acids), and AOX (adsorbable organic halogen) in river water (river Ruhr, Essen) through a chlorination kinetics approach. The effect of chlorination time and preozonation on the formation of THM, HAA, and AOX substances was studied. Preozonation can reduce the chlorine demand and the precursors for AOX and THM. THM generation was reduced further, when the ozone dosage consumed increased from 3.5 to 12.5 mg in the 1.4 L reaction vessel. AOX and TCAA (trichloroacetic acid) concentrations also decreased dramatically when 3.5 mg of ozone had reacted with the river water, but a higher dose of ozone did not further reduce AOX and TCAA formations. Besides, the characteristics of organic matter in raw water, ozonated water, and preozonated/chlorinated water was investigated. The results suggest the formation of low‐molecular‐weight acids with low UV absorbance when high‐molecular refractive matter is oxidized. 相似文献
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20世纪全球温度场趋势变化的区域特征分析 总被引：6，自引：0，他引：6
利用 1 90 0～ 1 998年全球 5°× 5°年平均表面温度场序列 ,提取具有不同温度变化型态的显著区域 ,探讨温度背景趋势的区域性及其对变暖显著性、稳定性的影响。同时结合对Hadley中心HadCM2海气耦合模式模拟结果的初步分析 ,研究温度背景趋势地域性差异的可能成因。结果表明 ,全球年际至世纪尺度温度变化距平场存在差异显著的 2 0个区域。温度场的背景趋势主要表现为两大类 ,背景增暖型和背景波动型 ,其中背景波动型以准 70a的波动变化为主 ,主要存在于北半球中高纬海域 ,并以北大西洋地区尤为显著 ;背景增暖最为稳定、显著的区域则是南印度洋中纬度地区。不同条件下海气耦合模式数值试验的结果也表明 ,南印度洋中纬度地区是温室效应等外强迫的稳定响应区域 ,温度背景趋势的地域性差异 ,一方面可能与温室效应等外强迫变化在不同区域的响应稳定性有关 ,另一方面也可能与海气系统年代际以上尺度耦合振荡的区域性有关。 相似文献