A numerical investigation of the destruction of peroxy radical by Cu ion catalysed reactions on atmospheric particles     

Howard B. Ross  Kevin J. Noone 《Journal of Atmospheric Chemistry》1991,12(2):121-136

To determine if Cu mediated reactions on atmospheric particles are important to HO₂ chemistry in the ambient atmosphere, Cu molalities were calculated from measured Cu aerosol particle concentrations, mass and number size distribution data from a site in central Sweden. A comparison of characteristic times indicates that at low relative humidities the reaction is limited by the mass transport of gas phase HO₂ to the particle surface and not by the chemical kinetics of the aqueous reaction. Comparison of half-lives for particle reactions and the gas phase destruction of HO₂ to form H₂O₂ indicate that heterogeneous reactions on aerosol particles may have important consequences on the chemistry of HO₂ and H₂O₂ in the troposphere.  相似文献   

气溶胶的光学厚度与反射率比的处理方法   总被引：2，自引：0，他引：2  

高飞 《海洋技术学报》2003,22(1):25-28

气溶胶光学厚度与气溶胶反射率比都是大气校正所需的重要大气参数，同时也是海洋水色卫星主要的数据产品，它们的测量精度将直接到卫星数据产品正演的精度和卫星数据产品的应用。文章在简述气溶胶光学厚度与气溶胶反射率比的基本测量原理和处理方法的基础上，结合多次试验数据结果进行简要的评价。  相似文献   

Atmospheric input of trace elements to the western Pacific Ocean and the Kuroshio ocean area     

Qian Fenlan  Yu Hongjian  Lan Youchang  Chen Zhi  Zhou Mingyu  Farn Parungo  Wu Peiming 《海洋学报(英文版)》1996,15(1):69-84

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离子色谱分析在黄土和粉尘研究中的应用   总被引：1，自引：0，他引：1  

王丹  屈文军  张小曳  严立文  曹国良 《海洋地质与第四纪地质》2005,25(1):113-118

黄土中存在着大量的碱金属及碱土金属，以往的测试方法多为原子吸收和ICP—MS，离子色谱法在测试黄土样品的碱金属和碱土金属元素含量中应用不多。将黄土地质标准样品进行消解后用离子色谱进行测试，测试效果良好，重复测试的相对标准偏差小于5％，与推荐值的相对误差小于5％，准确度和精密度符舍相关的质量控制要求。本实验方法测试的离子含量都在仪器响应呈线性的最佳测试范围之内，标准曲线经回归后相关系数均达到0．9999。黄土样品的分析结果与粉尘气溶胶样品的离子分析结果对比表明，此方法对于探讨粉尘起源以及沙尘暴天气的研究具有重要意义。  相似文献   

南极中山站大气气溶胶的化学组成及其来源的判别   总被引：1，自引：1，他引：1  

黄自强  暨卫东  杨绪林  黄荣坦  汤荣坤  于涛  张功勋 《台湾海峡》2003,22(3):334-346

从1998年3月7日至1999年11月23日历时21个月，在南极中山站连续采集89个海洋气溶胶样品，本文提供全部样品的13种化学元素Cu、Pb、Zn、Cd、Fe、Al、Mn、Cr、V、K、Na、Ca、Mg含量的实测值．研究表明中山站气溶胶化学成份的含量具有季节性变化的特征．通过相关分析、因子分析、富集因子等方法判别不同时间段中山站气溶胶化学成份的来源。  相似文献   

Environmental records of carbonaceous fly-ash particles from fossil-fuel combustion   总被引：3，自引：0，他引：3  

Maria Wik  Ingemar Renberg 《Journal of Paleolimnology》1996,15(3):193-206

Analysis of fly-ash particles in lake sediments has become increasingly important in studies of environmental pollution and lake acidification history. Most fly-ash studies have concerned black spheroidal carbonaceous particles (SCP)(>5 m) produced from oil and coal combustion. This review paper provides a summary of this technique and its application, and focusses on our investigations in Sweden between 1979 and 1993. It consists of five parts: i) preparation and analysis methods, ii) historical trends in atmospheric deposition, iii) geographical surveys of atmospheric deposition, iv) sediment dating, and v) studies of sedimentation processes in lakes. Methods for preparation and analyses of SCP have been developed and applied to investigations using sediment, soil and snow samples. Stratigraphic trends of SCP concentrations in lake-sediment cores reflect the consumption history of fossil fuels. A characteristic temporal SCP pattern, with a marked concentration increase beginning after the 1940's and a peak in the early 1970's, has been recognized in most Swedish lakes and elsewhere in Europe. A survey of SCP concentrations in surface sediments of >100 lakes covering Sweden demonstrated that polluted areas in southern Sweden had >100 times higher SCP concentrations than clean areas in the north. The spatial distribution of SCP over Sweden is similar to the deposition pattern of long-range transported airborne pollutants, such as excess sulphate monitored by network stations. SCP also accumulate in soils, and soil analyses can be used for determining the integrated historical deposition of SCP at the local or regional scale. Finally, SCP have been used for indirect dating of sediment cores and as a marker to assess sediment distribution patterns within lake basins.  相似文献   

南极长城站地区现代环境地球化学特征          下载免费PDF全文

赵俊琳 《极地研究》1990,2(2):1-12

本文通过环境背景值、风化壳地球化学、对流层(大气气溶胶)地球化学和人为地球化学异常,初步探讨了南极长城站地区的现代环境地球化学特征。分析表明:环境要素固有的地球化学性质、区域环境条件和自然环境演变之间具有深刻的内在联系。  相似文献   

Characterization of polycyclic aromatic hydrocarbons （PAHs） in aerosols around Guiyang City, China     

《中国地球化学学报》2006,25(B08):181-181

  相似文献   

Speciation of sulfate components in size-fractionated aerosol particles using sulfur K-edge X-ray absorption near-edge structure （XANES）     

Yoshio Takahashi Yutaka Kanai Hikari Kamioka Atsuyuki Ohta Takuro Miyoshi Hiroshi Shimizu 《中国地球化学学报》2006,25(B08):222-222

Sulfates are a main constituent of aerosols, which sulfate aerosols, it is necessary to determine what can cause various environmental problems sulfate ions are contained in these aerosols In the evaluation of the influence of In this study, sulfur K-edge XANES was used to determine sulfate species present in size-fractionated aerosol particles based on the post-edge structure after the main absorption peak in the XANES region. Aerosol samples were collected as part of the Japan-China joint project, ＂Asian Dust Experiment on Climate Impact＂ using a low-volume Andersen-type air sampler. XANES was measured at Beamline BL-9A at Photon Factory, Japan. A comparison of the XANES spectra of reference sulfate materials and aerosol samples collected in Tsukuba in Japan clearly showed that （NH4）2SO4 was the main sulfur species in particles with a smaller diameter and gypsum was the main sulfur species in particles with a larger diameter. A simulation of the XANES spectra by reference materials allows us to obtain the quantitative mixing ratios of the different sulfate species present in the aerosol samples. The presence of minor sulfur species other than （NH4）2SO4 and gypsum at the surface of mineral aerosols is suggested in our simulations and by a surface-sensitive conversion electron/He-ion yield XANES. In the absence of a contribution from a large dust event, the mole concentration of gypsum in the mineral aerosol fraction determined by XANES is similar to that of Ca which is determined independently using ion chromatography. This shows that the Ca and sulfate in the mineral aerosols are present only as gypsum. Considering that calcite is the main Ca mineral in the original material arising from an arid and semi-arid area in China, it is strongly suggested that gypsum is formed in aerosol during its long-range transportation by a reaction between calcite and sulfate ions.  相似文献   

Environmental Changes at the Desert Margin: An Assessment of Recent Paleolimnological Records in Lake Qarun, Middle Egypt   总被引：1，自引：0，他引：1  

R. J. Flower  C Stickley  N. L. Rose  S Peglar  A. A. Fathi  P. G. Appleby 《Journal of Paleolimnology》2006,35(1):1-24

Lake Qarun has been profoundly affected by a combination of human activities and climatic changes during the past 5000 years. Instrumental records available for the 20th century show that during most of this period both lake water level and salinity increased and that by the late 1980s lake water salinity was approximately that of seawater. Sediment cores (c. 1 m long) were collected from this shallow (Z_max 8.4 m) saline lake in 1998 and the master core (QARU1) was used to examine the potential of paleolimnology for reconstructing the recent environmental history of the site. According to ¹³⁷Cs and ²¹⁰Pb radio-assay, the recent sediment accumulation rate in QARU1 was around 5 mm year⁻¹ during the latter half of the 20th century but radionuclide levels were low. Spheroidal carbonaceous particles (SCPs) were present in the upper c. 30 cm of QARU1 and indicates contamination by low level particulate pollution, probably beginning around 1950. The record of exotic pollen (Casuarina) indicated that sediment at 51–52 cm depth dated to around 1930. Otherwise the pollen spectra indicated a strongly disturbed landscape with high ruderals and increased tree planting particularly since c. 1950. Diatom records were strongly affected by taphonomic processes including reworking and differential preservation but typical marine diatoms increased after the 1920s. Instrumental records show that the lake became more saline at this time. Freshwater taxa were present at approximately similar abundances throughout the core. This distribution probably reflected a combination of processes. Reworking of ancient freshwater diatomites is one likely source for freshwater diatoms in QARU1 but some taxa must also be contributed via the freshwater inflows. Overall, the diatom stratigraphy indicated increasingly salinity since the 1920s but provided no firm evidence of lake eutrophication. Diatom inferred salinity reconstructions were in only partial agreement with instrumental records but inferred for the lower section of the core (pre 20th century to the 1960s) accord with measured water salinity values. Surficial sediments of Lake Qarun contain environmental change records for the 20th century period but high sediment accumulation rate and pollen reflect the high degree of human disturbance in the region. Because of poor preservation and evidence of reworking, the relationships between diatom records and past water quality changes require careful interpretation, especially in the upper section of the core. Nevertheless, early to mid 20th century measurements of increasing lake water salinity are well supported by sediment records, a change that is probably linked to ingress of saline ground water  相似文献