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Nd and Sr isotope analyses are presented for gangue mineral samples from the giant carbonate-hosted Navan Zn–Pb deposit, Ireland, and for rocks from which Navan metals may have been derived. Analysis of gangue minerals spanning the Navan paragenetic sequence reveals systematic evolution in the composition of the mineralising fluid. Early fluid represented by replacive dolomite exhibits the lowest initial 87Sr/86Sr ratio (0.7083–0.7086), closest to that of the host limestone and to Lower Carboniferous seawater, and the highest 143Nd/144Nd ratio (0.51161–0.51176). Later generations of dolomite, barite and calcite, which encompass sulphide precipitation, have higher initial 87Sr/86Sr ratios (maximum 0.7105) and lower initial 143Nd/144Nd ratios (minimum 0.51157). All samples have initial Nd isotope ratios that are too low to have been acquired only from the host limestone. Drill core samples of presumed Ordovician volcanic and sedimentary rocks from beneath the Navan orebody have 143Nd/144Nd and 87Sr/86Sr ratios at the time of mineralisation of 0.51184–0.51217 and 0.7086–0.7138, respectively. The data are interpreted to indicate mixing of sulphide-rich, limestone-buffered brine, with a metal-bearing hydrothermal fluid, which had passed through sub-Carboniferous rocks, consistent with published fluid inclusion and S isotope data. The 143Nd/144Nd ratio of this basement-derived fluid is too low to have been imparted by flow through the Devonian Old Red Sandstone, as required in models of regional fluid flow in response to Hercynian uplift. Irrespective of whether such regional fluid flow occurred, the hydrothermal Nd must have been derived from sub-Devonian rocks. These conclusions broadly support the hydrothermal convection cell model in which brines, ultimately of surface origin, penetrated to a depth of several kilometres, leaching metals from the rocks through which they passed. The data also support increasing depth of penetration of convection cells with time. Metals were subsequently precipitated in carbonate rocks at sites of mixing with cooler, sulphide-rich fluids. However, comparison of the Navan hydrothermal gangue Nd–Sr isotope data with data from Lower Palaeozoic rocks strongly suggests that the latter cannot alone account for the “basement” signature. As the Navan deposit lies immediately north of the Iapetus Suture, this suggests that the Laurentian margin includes Precambrian basement. 相似文献
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A recently exposed section across a ?rst‐order valley buried beneath the regional blanket peat on hillside slopes in the upper Liffey valley, Co. Wicklow, is described. The section shows two alluvia within a shallow valley form underlain by an extensive boulder and stone line over regional till and weathered granite. 14C dates from wood in the alluvia indicate the older alluvium to have formed between 4324 ± 53 BP and 4126 ± 45 BP and the younger between 3217 ± 53 BP and 2975 ± 53 BP . The basal layer of the overlying peat yielded a date of 2208 ± 61 BP . The younger alluvium shows the effects of soil paludi?cation prior to the peat expansion. Dated pollen analyses elsewhere in the upper catchment con?rm the spread of blanket peat over most areas above 350 m after 4000–3600 BP . The buried valley was contributing sediments to the mid‐Holocene ?oodplains in the upper Liffey valley prior to the extension of blanket peat over the catchment after which sediment yields from it and the other catchment slopes declined. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
5.
C. R. Aldwell 《Environmental Geology》1996,27(2):82-84
Because of its copious and reliable rainfall, Ireland has an abundance of springs. Many of the larger ones issue from the Carboniferous limestone that occurs in over 40% of the country. The spring water is mainly a calcium bicarbonate type with a temperature of about 10°C. In the 18th century, warm and cold springs were developed as spas in various parts of Ireland. The popularity of these springs was short and most were in major decline by 1850. Today only one cold spa at Lisdoonvarna, Co. Clare is still operating. Springs in Ireland were places of religious significance for the pre-Christian Druidic religion. In the Christian period they became holy wells, under the patronage of various saints. Cures for many different ailments were attributed to water from these wells. 相似文献
6.
Michael J. Simms 《地球表面变化过程与地形》2004,29(4):477-494
Denudation mechanisms differ fundamentally between limestone and silicate rock types, which are subject to very different rate thresholds and enhancers/inhibitors. Silicates are removed largely by erosion, the mechanical entrainment and transport of particles. This is a relatively high energy, and highly episodic, process which occurs only when a minimum threshold ?ow velocity is exceeded; it is inhibited by vegetation cover and favoured by strongly seasonal runoff. Limestone is removed largely by chemical dissolution at a rate directly proportional to runoff. Dissolution is a relatively low energy process that can occur at any ?ow velocity or in static water; in general it is enhanced by vegetation cover and non‐seasonality of runoff. These contrasting factors in the denudation of silicates versus limestone can produce strikingly uneven rates of surface lowering across a landscape, sometimes akin to the well known ‘tortoise and hare race’, where the slow and steady denudation of limestones may in the long term exceed the sometimes rapid, but often localized and episodic, erosion of silicates. Prolonged exposure of limestone to a humid temperate climate in a tectonically stable environment produces low‐relief corrosion plains in which limestone uplands are anomalous and, in most instances, due to recent unroo?ng from beneath a siliciclastic cover. In a highly seasonal or semi‐arid climate almost the exact inverse may develop, with ‘?ashy’ runoff and sparse vegetation favouring erosion rather than dissolution. Even under a constant humid climate progressive unroo?ng of a thick limestone unit within folded siliciclastics may lead to a topographic inversion over time, with the limestone outcrop always forming a topographic low ?anked by siliciclastic uplands. Valleys will be initiated on anticlinal crests, where the limestone is ?rst unroofed, but progressive lowering of the limestone causes these valleys to migrate to their ?nal position in the synclinal troughs. In humid climates isostatic compensation in response to slow, but continuous, denudation of extensive limestone outcrops may be a signi?cant factor in the development of relief on adjacent, more slowly eroding, silicate outcrops. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
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Legal factors play an underrated but significant role as constraints on conservation management. In this paper, based on observations in both Northern Ireland and the Republic of Ireland, mode of land tenure is assessed to determine its influence on the conservation management of coastal dunes. The tenure types considered are: private ownership, corporate private ownership, tenancy, secured tenancy, leasing, common (joint) ownership, uncertain ownership, public ownership and its subset military ownership. It is suggested that multiple private ownership is least likely to favour effective conservation management. Public ownership by a statutory conservation authority and corporate private ownership by a conservation-orientated NGO are regarded as the optimum tenure types for conservation management of coastal dunes. 相似文献
9.
Extensive and economically-important lithium pegmatites have been described from the eastern flank of the large S-type peraluminous Leinster Granite batholith in southeast Ireland. This flank area is also the locus of a major dip-slip ductile shear zone which was active during emplacement of the Tullow Lowlands pluton of the batholith. All the known bedrock occurrences of lithium pegmatite are contained within this marginal deformation zone. Most previous studies have suggested derivation of the lithium pegmatites by fractionation from the Leinster Granite itself, though none are conclusive. More recently, an anatectic model has been proposed whereby the pegmatites were derived by melting of Li-rich sediments adjacent to the batholithic contact. Our investigation has been concerned with a detailed study of the Rb-Sr isotope systematics and trace element geochemistry of the pegmatites and their host granitoids in an attempt to resolve the problem of pegmatite genesis. The results suggest a strong geochemical and temporal coherence between the Leinster Granite and the lithium pegmatites. A model is proposed in which Li enrichment in residual magmas may be linked to the development of muscovite instead of biotite in the Leinster Granite itself. The Li excluded from entry to biotite then accumulates in highly mobile, low-viscosity pegmatitic fluids which migrate into the marginal shear zone of the Tullow Lowlands pluton where they crystallize at considerably lower temperatures. 相似文献
10.
Daniel W. J. Bosence 《Geological Journal》1980,15(2):91-111
Five sedimentary facies are described from SCUBA diving examination and sampling of Mannin Bay, Ireland. A Bank facies is built up by the unattached coralline algae Lithothamnium corallioides and Phymatolithon calcareum. This autochthonous facies occurs in shallow sheltered environments. In exposed areas a rippled Clean Algal Gravel facies is found composed of coralline and molluscan debris. In intermediate energy areas a Muddy Algal Gravel facies is found with small amounts of live corallines. Sheltered creeks have a Mud facies which is partly carbonate and partly terrigenous. The shallow water coralline algal sediments are overlapped by a Fine Sand facies of mixed biogenic composition. Each facies is characterized by particular phenotypic growth forms of the unattached corallines. Rates of organic calcium carbonate production are obtained which are found to be similar to rates from shallow tropical non-reef environments. The carbonate sediments of Mannin Bay are compared with similar sediments from Kilkerrin Bay. Ireland, from Brittany and from Falmouth Harbour. From these comparisons, facies models are proposed for these carbonate sediments. The major factor controlling facies distribution is coastal morphology. The present day shelf is considered to be too exposed to preserve complete sequences of the shallow water sediments. 相似文献