Experimental solidification of anhydrous latitic and trachytic melts at different cooling rates: The role of nucleation kinetics   总被引：1，自引：0，他引：1  

Gianluca Iezzi  Silvio Mollo  Guido Ventura  Andrea Cavallo  Claudia Romano 《Chemical Geology》2008,253(3-4):91-101

Two sets of cooling experiments were run at atmospheric conditions for two anhydrous starting latitic and trachytic melts: 1) five cooling rates (25, 12.5, 3, 0.5, and 0.125 °C/min) between 1300° and 800 °C, and 2) a 0.5 °C/min cooling rate from 1300 °C with quench temperatures at 1200°, 1100°, 1000° and 900 °C. Trachytic run-products are invariably glassy. Nucleation is also suppressed in the latitic run-products at the three highest cooling rates. Conversely, in the 0.5 and 0.125 °C/min runs, latites have a crystal content of  90 vol.%. The phases are: plagioclase, clinopyroxene, glass and iron-bearing oxide (in order of abundance). The variable quench temperatures, investigated by coupling experiments with Pt wire and Pt capsule sample containers in set 2, again did not produce crystallization of trachyte, whereas latitic samples are characterized by  10 vol.% of oxides, pyroxenes and plagioclase (in order of appearance), at temperature < 1000 °C. Effects of (preferential) heterogeneous nucleation on sample holders, of superheating degree, and chemical species loss during cooling are absent for both melt compositions. The difference of solidification paths between these two silicate melts can be ascribed only to their small chemical differences. In comparison with calculated equilibrium conditions all the experimental latitic and trachytic run-products revealed strong kinetic effects, interpretable in the light of the nucleation theory. The glass-forming ability (GFA) of trachyte is higher, whereas their critical cooling rate (Rc) is lower (< 0.125 °C/min), in comparison to latitic melts (Rc > 0.5 °C/min). The experimental results carried out in this study can be applied to lava flows and domes; trachytic lavas are able to flow for longer period with respect to latitic ones in a metastable condition. Glass-rich terrestrial lavas, i.e. obsidians, can be the result of sluggish nucleation kinetics due to the relative high polymerisation of evolved silicate melts.  相似文献   

亚洲赤道地区大气动能的纬向传播   总被引：7，自引：1，他引：7  

高辉  陈隆勋  何金海  陶诗言  金祖辉 《气象学报》2005,63(1):22-29

基于 1980～ 1997年 85 0hPa逐日NCEP/NCAR再分析资料讨论了亚洲赤道地区 (0°～ 5°N)大气动能的纬向传播特征。结果表明 ,在亚洲季风区内 ,赤道地区大气动能 (K)的最强中心位于 75°～ 90°E ,次强中心在索马里急流区 (5 0°E附近 )。在 0°～ 5°N ,90°E以东 ,平均的大气动能扰动和赤道上经向风扰动主要起源于西太平洋 ,并向西经南海传播到孟加拉湾。而在孟加拉湾动能中心与索马里急流区之间 ,动能传播方向比较复杂。以上事实说明赤道地区东亚季风系统确实是存在的 ,与印度季风系统中扰动的传播方向不同 ,东亚季风系统中动能和经向风扰动在东西方向上主要受西太平洋的影响。在亚洲赤道季风区 ,这两个系统的交界处约在 95°～ 10 0°E附近 ,比过去界定的偏西 5～ 10个经度。  相似文献   

Kinetic energy–rainfall intensity relationship for Central Cebu, Philippines for soil erosion studies     

Ricardo L. Fornis  Hans R. Vermeulen  Jan D. Nieuwenhuis 《Journal of Hydrology》2005,300(1-4):20-32

In the study of soil erosion, specifically on detachment of soil particles by raindrop impact, kinetic energy is a commonly suggested indicator of the raindrop's ability to detach soil particles from the soil mass. Since direct measurement of kinetic energy requires sophisticated and costly instruments, the alternative approach is to estimate it from rainfall intensity. The present study aims at establishing a relationship between rainfall intensity and kinetic energy for rainfalls in Central Cebu, Philippines as a preface of a wider regional investigation.

Drop size distributions of rainfalls were measured using the disdrometer RD-80. There are two forms of kinetic energy considered here. One is kinetic energy per unit area per unit time (KE_R, J m⁻² h⁻¹) and the other is kinetic energy per unit area per unit depth (KE, J m⁻² mm⁻¹). Relationships between kinetic energy per unit area per unit time (KE_R) and rainfall intensity (I) were obtained using linear and power relations. The exponential model and the logarithmic model were fitted to the KE–I data to obtain corresponding relationships between kinetic energy per unit area per unit depth of rainfall (KE) and rainfall intensity (I). The equation obtained from the exponential model produced smaller standard error of estimates than the logarithmic model.  相似文献   

一次梅雨暴雨的动能谱特征分析及收支诊断     

尹韩笑  张立凤  王羱  张明阳  余世旺 《大气科学》2019,43(5):1143-1157

利用WRF模式和NCEP再分析资料,对一次梅雨暴雨个例进行了数值模拟,基于高分辨率的模拟结果计算了水平动能谱、涡旋动能谱及辐散动能谱,诊断了动能收支谱方程。结果表明:在暴雨发展阶段,各个高度上都有中尺度动能增长,其显著增加始于中尺度低端,这导致了在中尺度波段出现谱转折特征,但在不同高度转折尺度不同;对流层高层涡旋动能大于辐散动能,平流层低层反之;不同降水阶段、不同高度和不同尺度上动能的来源不同,对流层高层,中尺度动能倾向由非线性项和气压项贡献;平流层低层,气压项的作用更为明显。  相似文献   

Kinetic energy budget and moisture flux convergence analysis during interaction between two cyclonic systems: Case study     

《Dynamics of Atmospheres and Oceans》2019

An analysis of the kinetic energy budget during a case of interaction between middle latitude and extratropical cyclones has been made in this work. Horizontal flux convergence constitutes a major energy sink. Generation of kinetic energy via cross-contour flow is a persistent source throughout the growth and decay periods. Dissipation of kinetic energy from subgrid to grid scales is an important source during the pre-storm period; it acts as a sink during the growth and decay periods. The major contribution to kinetic energy comes from a persistent upper tropospheric jet stream activity throughout the period of the cyclone development. The characteristics of moisture-flux components (divergent and rotational) along with precipitable water content for different tropospheric layers throughout the life cycle of our cyclone are also studied in this work. It is found that most of required humidity for our cyclone are initiated from Arabian Sea and then to some extent are reinforced over Gulf of Aden and east of central Africa and then by passing over Red sea enter to the south and south east of Mediterranean Sea. The rotational component of the moisture transport brings moisture from two regions; the first which is considered the main region is the Indian Ocean, Arabian Sea, Gulf of Aden and north east of Sudan. The second source region is the Atlantic and Mediterranean Sea. In the middle troposphere, the primary moisture source is found over central Africa, which in turn is traced to the Atlantic Ocean, the Indian Ocean, and the Arabian Sea. The upper-level moisture fluxes are weak and play a minor role over the area of interaction between two cyclones.  相似文献   

GRAPES全球集合预报系统模式扰动随机动能补偿方案初步探究   总被引：10，自引：5，他引：5  

彭飞  李晓莉  陈静  李红祺 《气象学报》2019,77(2):180-195

为了体现次网格尺度能量升尺度转换过程中存在的不确定性, 文中将随机动能补偿(Stochastic Kinetic Energy Backscatter, SKEB)方案应用于GRAPES(Global/Regional Assimilation and Prediction System)全球集合预报系统(GRAPES-GEPS), 以更好地表征模式误差并且增大集合离散度。使用的SKEB方案基于具有一定时、空相关特征的随机型以及由数值扩散导致的局地动能耗散率来构造随机流函数强迫。并根据流函数与水平风速旋转分量的关系, 将SKEB方案中的流函数强迫转化为适用于GRAPES全球模式的水平风速扰动。结果表明, SKEB方案的使用一方面能够提高GRAPES对大气动能谱的模拟能力; 另一方面能够改善GRAPES-GEPS的集合离散度与集合平均误差的关系, 增加了集合离散度, 并在一定程度上减小了集合平均误差, 尤其是在热带地区这种改进更为显著。而且该方案使得热带地区连续分级概率评分(CRPS评分)显著减小。就降水预报而言, 从Brier评分与相对作用特征面积(AROC, Area under the Relative Operating Characteristics)的结果来看, SKEB方案有助于改善中国地区小雨[0.1 mm, 10 mm)、中雨[10 mm, 25 mm)与大雨[25 mm, 50 mm)量级降水的概率预报技巧, 而对暴雨[50 mm, ∞)量级降水预报技巧影响很小(24 h降水量)。总体上, 模式扰动随机动能补偿方案提高了GRAPES-GEPS的概率预报技巧。   相似文献   

小振幅海洋内波的演变、破碎和所致混合   总被引：1，自引：1，他引：0  

李丙瑞  范海梅  田纪伟  孙波  张占海 《海洋与湖沼》2010,41(6):807-815

利用基于谱方法和MPI并行运算的数值模式SpectralModel,直接数值模拟了三维小振幅海洋内波的演变、破碎和所致湍流混合,指出导致其不稳定而破碎的为PSI(parametric subharmonic instability)机制;对于内波破碎所致的湍流混合过程,分析了跨等密度面扩散系数kρ、混合效率γ、浮力通量谱、动能谱以及势能谱等统计性质:内波破碎前,kρ和γ保持低值水平,浮力通量谱值为负,且集中在低波数段;内波破碎后,kρ和γ迅速增大,最大值分别约为0.9×103m2/s和0.18,浮力通量谱值在低波数段为负值,在高波数段为正值,这是因为层化湍流中势能向小尺度运动传递和动能向小尺度运动传递相比更为有效。在内波破碎、强湍流混合阶段,势能谱存在一谱段满足kz3律,P(kz)=0.2N2kz3。此外,与二维模拟结果相比较,导致内波不稳定而破碎的均为PSI机制,kρ、浮力通量谱、势能谱变化趋势大体一致;但三维数值实验中,内波破碎时间提前,湍流衰减加快;KE谱在高波数部分下降速度相对减小,更接近于kz3。  相似文献   

Oxidation of copper(I) in seawater at nanomolar levels     

M. Gonzlez-Dvila  J.M. Santana-Casiano  A.G. Gonzlez  N. Prez  F.J. Millero 《Marine Chemistry》2009,115(1-2):118-124

The oxidation and reduction of nanomolar levels of copper in air-saturated seawater and NaCl solutions has been measured as a function of pH (7.17–8.49), temperature (5–35 °C) and ionic strength (0.1–0.7 M). The oxidation rates were fitted to an equation valid at different pH and ionic strength conditions in sodium chloride and seawater solutions:The reduction of Cu(II) was studied in both media for different initial concentrations of copper(II). When the initial Cu(II) concentration was 200 nM, the copper(I) productions were 20% and 9% for NaCl and seawater, respectively. The effect of speciation of copper(I) reduced from Cu(II) on the rates was studied. The Cu(I) speciation is dominated by the CuCl₂⁻ species. On the other hand, the neutral chloride CuCl species dominates the Cu(I) oxidation in the range of 0.1 M to 0.7 M chloride concentrations.  相似文献   

Book review of TURBULENCE – AN INTRODUCTION FOR SCIENTISTS AND ENGINEERS by P.A. Davidson,Oxford University Press, 2004, XIX + 657 pp., £90.00, $174.50 hardback (ISBN 0-19-852948-1), £35.00, $69.50 paperback (ISBN 0-19-852949-X).     

H. K. Moffatt 《地球物理与天体物理流体动力学》2013,107(1):95-97

Abstract

By T. G. Cowling. Adam Hilger Ltd, x + 136 pp. £10.00 (ISBN O 85274 300 9) July 1976.  相似文献   

Simulation of moist mountain waves with an anelastic model     

Juan Carlos Jusem  Albert Barcilon 《地球物理与天体物理流体动力学》2013,107(1-4):259-276

Abstract

A two-dimensional, nonlinear, time-dependent, non-hydrostatic, anelastic, numerical model is used to assess the effect of condensation on the evolution and structure of gravity waves generated by the passage of a stable, moist stream over topography. Precipation is ignored but water phase changes are taken into account explicitly.

The main effect of condensation is to damp the wave intensity and to reduce the wave drag, which can be diminished by as much as 50% compared to its value in dry simulations. This result agrees with some earlier analytical models and some more recent fully compressible numerical models.

This model also confirms that the presence of condensation delays the overturning of isentropes, and the formation of the critical layer that accompanies wave-breaking.  相似文献