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1.
The petrography and chemical composition of minerals of quartz-rich diamondiferous rocks from the Kokchetav Massif, especially the zonation of garnet, were studied and compared with diamondiferous quartzofeldspathic rocks from the Saxonian Erzgebirge. Many compositional and textural features were found to be similar. For instance, microdiamonds are enclosed systematically in a specific intermediate growth zone of garnet in these rocks. On the basis of experimental data, a magmatic scenario was constructed to check if the quartz-rich diamondiferous rocks are of magmatic origin. By this, the P-T paths, derived here for the Kokchetav rocks, and the textural observations it is concluded that the minerals of the diamondiferous rocks have crystallized from silicate melts. These melts originated by anatexis of deeply submerged metasediments (Erzgebirge: at T as high as 1200°C, Kokchetav Massif: at 50-100°C lower T) and ascended from at least 200 km depth. Relics of the pre-anatectic evolution are still present, for instance, as garnet cores. After ascent and emplacement of the magma in deep portions of thickened continental crust (Kokchetav Massif: 45-50 km close to 800°C, Erzgebirge: 55-60 km at 30-50°C lower T) considerable quantities of (white and/or dark) micas formed by peritectic reactions from melt. For instance, garnets could be resorbed at this stage and biotite grew instead. After the magmatic stage, retrogression took place much stronger in the Kokchetav Massif. This was accompanied by deformation transforming broadly the magmatic texture of quartz-rich diamondiferous rocks from the Kokchetav Massif to a gneissic texture.  相似文献   
2.
Exhumation of high-pressure rocks of the Kokchetav massif: facts and models   总被引:1,自引:0,他引:1  
The exhumation of ultrahigh-pressure (UHP) metamorphic units from depths more than 100-120 km is one of the most intriguing questions in modern petrology and geodynamics. We use the diamondiferous Kumdy-Kol domain in the Kokchetav Massif to show that exhumation models should take into consideration initially high uplift velocities (from 20 down to 6 cm/year) and the absence of the deformation of UHP assemblages. The high rate of exhumation are indicated by ion microprobe (SHRIMP) dating of zircons from diamondiferous rocks and supported by the low degree of nitrogen aggregation in metamorphic diamonds.Diamondiferous rocks in the Kumdy-Kol domain occur as steeply dipping (60°-80°) thin slices (few hundred metres) within granite-gneiss. Using geological, petrological and isotopic-geochemical data, we show that partial melting of diamondiferous metamorphic rocks occurred; a very important factor which has not been taken into account in previous models.Deformation of diamondiferous rocks at Kumdy-Kol is insignificant; diamond inclusions in garnet are often intergrown with mica crystals carrying no traces of deformation. All these facts could be explained by partial melting of metapelites and granitic rocks in the Kumdy-Kol domain. The presence of melt is responsible for an essential reduction of viscosity and a density difference (Δρ) between crustal rocks and mantle material and reduced friction between the upwelling crustal block, the subducting and overriding plates. Besides Δρ, the exhumation rate seems to depend on internal pressure in the subducting continental crustal block which can be regarded as a viscous layer between subducting continental lithosphere and surrounding mantle.We construct different models for the three stages of exhumation: a model similar to “corner flow” for the first superfast exhumation stage, an intermediate stage of extension (most important from structural point of view) and a very low rate of exhumation in final diapir+erosional uplift.  相似文献   
3.
Oxygen isotopic compositions of silicates in eclogites and whiteschists from the Kokchetav massif were analyzed by whole‐grain CO2‐laser fluorination methods. Systematic analyses yield extremely low δ18O for eclogites, as low as ?3.9‰ for garnet; these values are comparable with those reported for the Dabie‐Sulu UHP eclogites. Oxygen isotopic compositions are heterogeneous in samples of eclogite, even on an outcrop scale. Schists have rather uniform oxygen isotope values compared to eclogites, and low δ18O is not observed. Isotope thermometry indicates that both eclogites and schists achieved high‐temperature isotopic equilibration at 500–800 °C. This implies that retrograde metamorphic recrystallization barely modified the peak‐metamorphic oxygen isotopic signatures. A possible geological environment to account for the low‐δ18O basaltic protolith is a continental rift, most likely subjected to the conditions of a cold climate. After the basalt interacted with low δ18O meteoric water, it was tectonically inserted into the surrounding sedimentary units prior to, or during subduction and UHP metamorphism.  相似文献   
4.
U–Pb geochronological, trace-element and Lu–Hf isotopic studies have been made on zircons from ultrahigh-pressure (UHP) mafic eclogite from the Kumdy-Kol area, one of the diamond-facies domains of the Kokchetav Massif (northern Kazakhstan). The peak eclogitic assemblage equilibrated at > 900 °C, whereas the bulk sample composition displays light rare-earth element (LREE) and Th depletion evident of partial melting. Zircons from the eclogite are represented by exclusively newly formed metamorphic grains and have U–Pb age spread over 533–459 Ma, thus ranging from the time of peak subduction burial to that of the late post-orogenic collapse. The major zircon group with concordant age estimates have a concordia age of 508.1 ±4.4 Ma, which corresponds to exhumation of the eclogite-bearing UHP crustal slice to granulite- or amphibolite-facies depths. This may indicate potentially incoherent exhumation of different crustal blocks within a single Kumdy-Kol UHP domain. Model Hf isotopic characteristics of zircons (εHf(t) +1.5 to +7.8, Neoproterozoic model Hf ages of 1.02–0.79 Ga) closely resemble the whole-rock values of the Kumdy-Kol eclogites and likely reflect in situ derivation of HFSE source for newly formed grains. The ages coupled with geochemical systematics of zircons confirm that predominantly late zircon growth occurred in Th–LREE-depleted eclogitic assemblage, that experienced incipient melting and monazite dissolution in melt at granulite-facies depths, followed by amphibolite-facies rehydration during late-stage exhumation-related retrogression.  相似文献   
5.
Abstract In the first extensive, systematic study of inclusions in zircons from ultrahigh-pressure (UHP) and high-pressure (HP) metamorphic rocks of the Kokchetav Massif of Kazakhstan (separated from 232 rock samples from all representative lithologies and geographic regions), we identified graphite, quartz, garnet, phengite, phlogopite, rutile, albite, K-feldspar, amphibole, zoisite, kyanite, calcite, dolomite, apatite, monazite, omphacite and jadeite, as well as the diagnostic UHP metamorphic minerals (i.e. microdiamond and coesite) by laser Raman spectroscopy. In some instances, coesite + quartz and diamond + graphite occur together in a single rock sample, and inclusion aggregates also comprise polycrystalline diamond crystals overgrowing graphite. Secondary electron microscope and cathodoluminescence studies reveal that many zircons display distinct zonation textures, which comprise core and wide mantle, each with distinctive inclusion microassemblages. Pre-UHP metamorphic minerals such as graphite, quartz, phengite and apatite are common in the core, whereas diamond, coesite, garnet and jadeite occupy the mantle. The inclusions in core are irrelevant to the UHP metamorphism. The zircon core is of detrital or relatively low-grade metamorphic origin, whereas the mantle is of HP to UHP metamorphic origin. The zonal arrangement of inclusions and the presence of coesite and diamond without back-reaction imply that aqueous fluids were low to absent within the zircons during both prograde and retrograde metamorphism, and that the zircon preserves a prograde pressure–temperature record of the Kokchetav metamorphism which, elsewhere, has been more or less obliterated in the host rock.  相似文献   
6.
Abstract High‐ to ultrahigh‐pressure metamorphic (HP–UHPM) rocks crop out over 150 km along an east–west axis in the Kokchetav Massif of northern Kazakhstan. They are disposed within the Massif as a 2 km thick, subhorizontal pile of sheet‐like nappes, predominantly composed of interlayered pelitic and psammitic schists and gneisses, amphibolite and orthogneiss, with discontinuous boudins and lenses of eclogite, dolomitic marble, whiteschist and garnet pyroxenite. On the basis of predominating lithologies, we subdivided the nappe group into four north‐dipping, fault‐bounded orogen‐parallel units (I–IV, from base to top). Constituent metabasic rocks exhibit a systematic progression of metamorphic grades, from high‐pressure amphibolite through quartz–eclogite and coesite–eclogite to diamond–eclogite facies. Coesite, diamond and other mineral inclusions within zircon offer the best means by which to clarify the regional extent of UHPM, as they are effectively sequestered from the effects of fluids during retrogression. Inclusion distribution and conventional geothermobarometric determinations demonstrate that the highest grade metamorphic rocks (Unit II: T = 780–1000°C, P = 37–60 kbar) are restricted to a medial position within the nappe group, and metamorphic grade decreases towards both the top (Unit III: T = 730–750°C, P = 11–14 kbar; Unit IV: T = 530°C, P = 7.5–9 kbar) and bottom (Unit I: T = 570–680°C; P = 7–13.5 kbar). Metamorphic zonal boundaries and internal structural fabrics are subhorizontal, and the latter exhibit opposing senses of shear at the bottom (top‐to‐the‐north) and top (top‐to‐the‐south) of the pile. The orogen‐scale architecture of the massif is sandwich‐like, with the HP–UHPM nappe group juxtaposed across large‐scale subhorizontal faults, against underlying low P–T metapelites (Daulet Suite) at the base, and overlying feebly metamorphosed clastic and carbonate rocks (Unit V). The available structural and petrologic data strongly suggest that the HP–UHPM rocks were extruded as a sequence of thin sheets, from a root zone in the south toward the foreland in the north, and juxtaposed into the adjacent lower‐grade units at shallow crustal levels of around 10 km. The nappe pile suffered considerable differential internal displacements, as the 2 km thick sequence contains rocks exhumed from depths of up to 200 km in the core, and around 30–40 km at the margins. Consequently, wedge extrusion, perhaps triggered by slab‐breakoff, is the most likely tectonic mechanism to exhume the Kokchetav HP–UHPM rocks.  相似文献   
7.
Abstract In northern Kazakhstan the WNW striking Kokchetav megamélange includes different crustal sequences with high‐pressure/ultrahigh‐pressure (HP/UHP) remnants of their 540–520 Ma subduction metamorphism. Two domains separated by the north‐east trending Chaglinka fault are distinguished. The western domain exhibits NE–SW structures within a single Kumdy–Kol megaunit of diamond‐bearing UHP metasediments and high‐temperature (HT) eclogites. The eastern domain consists of the composite Kulet megaunit with the Kulet UHP unit (coesite‐bearing metasediments, whiteschists and eclogites), the Enbek–Berlyk medium‐pressure (MP) unit (kyanite‐bearing, high‐alumina rocks with interleaved coronitic metagabbro), and ortho‐ and paragneisses with eclogites and amphibolites included. All eclogites in the eastern domain are of the relatively low temperature (LT) type. Sillimanite is common and appears after kyanite in the sheared MP unit. A regional and moderately ESE plunging linear fabric coincides with the fold‐axis of the foliation poles from the eastern domain. Whether this also reflects a regional top to the WNW transport, as inferred from the dextral strike‐slip on steeply to SSW dipping foliation, needs further study. Top to the WNW shear is shown by weakly inclined low pressure (LP) cordierite rocks that flank the eastern domain in the south. Some new 39Ar/40Ar mica cooling ages (519, 521 Ma) from the Kulet UHP micaschists reflect the same early stage evolutionary event as was previously shown for the Kumdy–Kol UHP rocks (515, 517 Ma) in the west. Similar 39Ar/40Ar ages (500, 517 Ma) are recorded by micas and amphibole that outline a top to NNW shear fabric in the non‐subducted Proterozoic basement, north of the megamélange. A 447 Ma overprint of the MP sequences is considered to reflect the strike‐slip deformation with sillimanite and the reworking of an early kyanite‐bearing tectonite. Biotites from the LP cordierite rocks yielded approximately 400 Ma 39Ar/40Ar ages. In case they reflect the WNW shear deformation, the latter is considered to be associated with a regional granite magmatism (420–460 Ma) extending south of the eastern domain. In their present different structural domains the Kulet and Kumdy–Kol UHP units display a similar early stage event. Subsequent LP deformation, which is likely to be associated with regional granite magmatism (420–460 Ma), is assumed to have obliterated any common or uniform early exhumation structure for the whole megamélange. The north‐east structured Kumdy–Kol domain is assumed to have preserved the most information about the early stage exhumation. This domain is at an angle to the regional WNW strike of the megamélange.  相似文献   
8.
Abstract To investigate the regional thermobaric structure of the diamondiferous Kokchetav ultrahigh‐pressure and high‐pressure (UHP–HP) massif and adjacent units, eclogite and other metabasites in the Kulet and Saldat–Kol regions, northern Kazakhstan, were examined. The UHP–HP massif is subdivided into four units, bounded by subhorizontal faults. Unit I is situated at the lowest level of the massif and consists of garnet–amphibolite and acidic gneiss with minor pelitic schist and orthogneiss. Unit II, which structurally overlies Unit I, is composed mainly of pelitic schist and gneiss, and whiteschist locally with abundant eclogite blocks. The primary minerals observed in Kulet and Saldat–Kol eclogites are omphacite, sodic augite, garnet, quartz, rutile and minor barroisite, hornblende, zoisite, clinozoisite and phengite. Rare kyanite occurs as inclusions in garnet. Coesite inclusions occur in garnet porphyroblasts in whiteschist from Kulet, which are closely associated with eclogite masses. Unit III consists of alternating orthogneiss and amphibolite with local eclogite masses. The structurally highest unit, Unit IV, is composed of quartzitic schist with minor pelitic, calcareous, and basic schist intercalations. Mineral assemblages and compositions, and occurrences of polymorphs of SiO2 (quartz or coesite) in metabasites and associated rocks in the Kulet and Saldat–Kol regions indicate that the metamorphic grades correspond to epidote–amphibolite, through high‐pressure amphibolite and quartz–eclogite, to coesite–eclogite facies conditions. Based on estimations by several geothermobarometers, eclogite from Unit II yielded the highest peak pressure and temperature conditions in the UHP–HP massif, with metamorphic pressure and temperature decreasing towards the upper and lower structural units. The observed thermobaric structure is subhorizontal. The UHP–HP massif is overlain by a weakly metamorphosed unit to the north and is underlain by the low‐pressure Daulet Suite to the south; boundaries are subhorizontal faults. There is a distinct pressure gap across these boundaries. These suggest that the highest grade unit, Unit II, has been selectively extruded from the greatest depths within the UHP–HP unit during the exhumation process, and that all of the UHP–HP unit has been tectonically intruded and juxtaposed into the adjacent lower grade units at shallower depths of about 10 km.  相似文献   
9.
The Kulet eclogite in the Kokchetav Massif, northern Kazakhstan, is identified as recording a prograde transformation from the amphibolite facies through transitional coronal eclogite to fully recrystallized eclogite (normal eclogite). In addition to minor bodies of normal eclogite with an assemblage of Grt + Omp + Qz + Rt ± Ph and fine‐grained granoblastic texture (type A), most are pale greyish green bodies consisting of both coronal and normal eclogites (type B). The coronal eclogite is characterized by coarse‐grained amphibole and zoisite of amphibolite facies, and the growth of garnet corona along phase boundaries between amphibole and other minerals as well as the presence of eclogitic domains. The Kulet eclogites experienced a four‐stage metamorphic evolution: (I) pre‐eclogite stage, (II) transition from amphibolite to eclogite, (III) a peak eclogite stage with prograde transformation from coronal eclogite to UHP eclogite and (IV) retrograde metamorphism. Previous studies made no mention of the presence of amphibole or zoisite in either the pre‐eclogite stage or coronal eclogite, and so did not identify the four‐stage evolution recognized here. P–T estimates using thermobarometry and Xprp and Xgrs isopleths of eclogitic garnet yield a clockwise P–T path and peak conditions of 27–33 kbar and 610–720 °C, and 27–35 kbar and 560–720 °C, respectively. P–T pseudosection calculations indicate that the coexistence of coronal and normal eclogites in a single body is chiefly due to different bulk compositions of eclogite. All eclogites have tholeiitic composition, and show flat or slightly LREE‐enriched patterns [(La/Lu)N = 1.1–9.6] and negative Ba, Sr and Sc and positive Th, U and Ti anomalies. However, normal eclogite has higher TiO2 (1.35–2.65 wt%) and FeO (12.11–16.72 wt%) and REE contents than those of coronal eclogite (TiO2 < 0.9 wt% and FeO < 12.11 wt%) with one exception. Most Kulet eclogites plot in the MORB and IAB fields in the 2Nb–Zr/4–Y and TiO2–FeO/MgO diagrams, although displacement from the MORB–OIB array indicates some degree of crustal involvement. All available data suggest that the protoliths of the Kulet eclogites were formed at a passive continent marginal basin setting. A schematic model involving subduction to 180–200 km at 537–527 Ma, followed by slab breakoff at 526–507 Ma, exhumation and recrystallization at crustal depths is applied to explain the four‐stage evolution of the Kulet eclogite.  相似文献   
10.
哈萨克斯坦北部Kumdy-Kol金刚石矿床地质与变质金刚石成因   总被引:1,自引:0,他引:1  
哈萨克斯坦北部Kokchetav地区的Kumdy Kol金刚石矿床是世界上惟一的变质金刚石矿床。对该金刚石矿床成因以及相关岩石的诸多研究成果不仅深化了对超高压变质岩的研究 ,而且推动了大陆动力学研究的进展。在该金刚石矿床中找到的岩相学证据证明 ,该金刚石矿床的主要含矿岩石大理岩曾经在俯冲带中循环到 >2 4 0km的深部。文章在介绍Kokchetav变质金刚石矿床的地质特征和大地构造背景的基础上 ,讨论了该变质金刚石矿床的形成过程以及变质金刚石的成因。Kokchetav变质金刚石主要表现出蜂窝状或草莓状的特征外形。这种蜂窝状或草莓状金刚石是快速生长条件下结晶的结果。结合最近的研究成果 ,笔者认为Kokchetav金刚石矿床中金刚石的形成与深俯冲大理岩中的白云石分解作用密切相关。白云石分解反应形成文石和菱镁矿组合 ,菱镁矿继续分解形成金刚石 (MgCO3 =金刚石 +MgO +O2 )。基于这个认识 ,Kokchetav金刚石矿床中碳 (金刚石和石墨 )的来源应该是碳酸盐岩  相似文献   
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