西湖茶园茶叶铅污染铅同位素示踪     

郦逸根  路远发 《物探与化探》2008,32(2):180-185

通过对西湖茶园的植物和土壤样品进行一系列的调查,以着力寻找茶叶的铅污染源。利用铅同位素技术对西湖茶园的土壤、茶叶和城区的燃煤、大气气溶胶、汽车尾气进行铅同位素示踪研究。研究表明,茶园土壤铅物质的可溶相具同源性和残查态偏于多源性。清洗后的茶叶铅含量显著降低,但其同位素组成不发生明显改变,显示出茶叶中的铅与叶面空气沉降物中的铅同源。不同介质铅同位素对比值平均值呈现表土、大气(气溶胶)、煤的w(²⁰⁶Pb)/w(²⁰⁷Pb)与茶叶趋于相近,汽油低之;表土、大气(气溶胶)、汽油的w(²⁰⁸Pb)/〔w(²⁰⁶Pb)+w(²⁰⁷Pb)〕与茶叶趋于相近,煤略高之。不同区域茶叶铅物质具同源性,与种植的农业地质背景无关。在煤燃烧、气化过程中,Pb进入大气,通过大气沉降或被茶树吸收或附着在茶叶叶面;汽车尾气的排放是茶树铅污染的重要原因之一。  相似文献   

广西佛子冲铅锌矿田成岩成矿时代研究   总被引：3，自引：0，他引：3  

翟丽娜  王建辉  韦昌山  江河  蔡锦辉 《华南地质与矿产》2008,(3):46-49

广西佛子冲铅锌矿田位于桂东南博白-岑溪多金属成矿带的NE端,区内发育燕山期花岗岩、花岗闪长岩、二长花岗斑岩和英安质凝灰熔岩等;其中花岗闪长岩和二长花岗斑岩与铅锌成矿关系密切,成矿岩体形成时代分别为156Ma和127Ma。  相似文献   

A surface complexation model for cadmium and lead adsorption onto diatom surface     

A. Glabert  O.S. Pokrovsky  C. Reguant  J. Schott  A. Boudou 《Journal of Geochemical Exploration》2006,88(1-3):110

This work is devoted to the physico-chemical study of cadmium and lead interaction with diatom–water interfaces for two marine planktonic (Thalassiosira weissflogii = TW, Skeletonema costatum = SC) and two freshwater periphytic species (Achnanthidium minutissimum = AMIN, Navicula minima = NMIN) by combining adsorption measurements with surface complexation modeling. Reversible adsorption experiments were performed at 20 °C after 3 h of exposure as a function of pH, metal concentration in solution, and ionic strength. While the shape of pH-dependent adsorption edge is similar among all four diatom species, the constant-pH adsorption isotherm and maximal binding capacities differ. These observations allowed us to construct a surface complexation model for cadmium and lead binding by diatom surfaces that postulates the constant capacitance of the electric double layer and considers Cd and Pb complexation with mainly carboxylic and, partially, silanol groups. Parameters of this model are in agreement with previous acid–base titration results and allow quantitative reproduction of all adsorption experiments.  相似文献   

3D numerical modelling of fluid flow in the Val-d’Or orogenic gold district: major crustal shear zones drain fluids from overpressured vein fields     

Georges Beaudoin  René Therrien  Catherine Savard 《Mineralium Deposita》2006,41(1):82-98

Fluid flow patterns have been determined using oxygen isotope isopleths in the Val-d’Or orogenic gold district. 3D numerical modelling of fluid flow and oxygen isotope exchange in the vein field shows that the fluid flow patterns can be reproduced if the lower boundary of the model is permeable, which represents middle or lower crustal rocks that are infiltrated by a metamorphic fluid generated at deeper levels. This boundary condition implies that the major crustal faults so conspicuous in vein fields do not act as the only major channel for upward fluid flow. The upper model boundary is impermeable except along the trace of major crustal faults where fluids are allowed to drain out of the vein field. This upper impermeable boundary condition represents a low-permeability layer in the crust that separates the overpressured fluid from the overlying hydrostatic fluid pressure regime. We propose that the role of major crustal faults in overpressured vein fields, independent of tectonic setting, is to drain hydrothermal fluids out of the vein field along a breach across an impermeable layer higher in the crust and above the vein field. This breach is crucial to allow flow out of the vein field and accumulation of metals in the fractures, and this breach has major implications for exploration for mineral resources. We propose that tectonic events that cause episodic metamorphic dehydration create a short-lived pulse of metamorphic fluid to rise along zones of transient permeability. This results in a fluid wave that propagates upward carrying metals to the mineralized area. Earthquakes along crustal shear zones cause dilation near jogs that draw fluids and deposit metals in an interconnected network of subsidiary shear zones. Fluid flow is arrested by an impermeable barrier separating the hydrostatic and lithostatic fluid pressure regimes. Fluids flow through the evolving and interconnected network of shear zones and by advection through the rock matrix. Episodic breaches in the impermeable barrier along the crustal shear zones allow fluid flow out of the vein field.  相似文献   

Pseudodynamic tests on rubber base isolators with numerical substructuring of the superstructure and strain‐rate effect compensation     

F. J. Molina  G. Verzeletti  G. Magonette  Ph. Buchet  V. Renda  M. Geradin  A. Parducci  M. Mezzi  A. Pacchiarotti  L. Federici  S. Mascelloni 《地震工程与结构动力学》2002,31(8):1563-1582

A pseudodynamic testing procedure has been applied by which the seismic response of a base‐isolated building is obtained by using as specimen the isolators, while the superstructure is numerically simulated. The procedure also takes advantage of the continuous pseudodynamic testing capabilities of the ELSA laboratory, which increase the accuracy of the results and reduce the strain‐rate effect of the rubber bearings. A simple proportional correction of the measured forces compensates the remaining strain‐rate effect due to the unrealistic speed of the test. The correction factor is obtained by means of a characterizing test on the specific rubber isolators. The developed method has been successfully applied to the prediction of the seismic response of a base‐isolated four‐storey building submitted to several specified accelerograms. The results for those earthquakes as well as the effects of some changes of the parameters of the system are discussed. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

河南南召水洞岭铜铅锌矿床地质特征及成因分析   总被引：8，自引：0，他引：8  

伏雄 《矿产与地质》2002,16(3):160-164

通过地质详查和综合研究相结合的手段 ,从水洞岭铜铅锌矿床的地质特征入手 ,分析矿床成因 ,提出矿床属海相火山喷发沉积 -弱改造型的成因观点  相似文献   

铅橡胶复合阻尼器的性能试验研究   总被引：4，自引：0，他引：4  

刘冰  周云  邓雪松  徐赵东 《地震工程与工程振动》2002,22(5):105-114

介绍作者提出的铅橡胶复合阻尼器的构造与耗能原理，通过不同形状，不同大小铅心的8个铅橡胶复合阻尼器的循环荷载试验，研究了频率、应变幅值、循环次数、铅芯直径、竖向压力等对铅橡胶复合阻尼器的影响规律。研究结果表明，铅橡胶复合阻尼器工作性能稳定，耗能性能和抗疲劳性能好。  相似文献   

滚 滑 复 合 轴 承 研 究     

田红平  张福润  杨楚民 《探矿工程》2003,30(1):60-62

针对牙轮钻头的滑动轴承和滚动轴承在实际工作中所存在的问题，提出一种牙轮钻头滚滑复合轴承，对滚滑复合轴承结构进行有限元对比分析、模拟对比试验和钻头现场验证实验，表明滚滑复合轴承是一种较先进的创新性轴承。  相似文献   

云南兰坪-思茅盆地脉状铜矿床铅、硫同位素地球化学与成矿物质来源研究   总被引：13，自引：5，他引：13  

吴南平蒋少涌  廖启林潘家永 戴宝章 《岩石学报》2003,19(4):799-807

云南兰坪-思茅盆地中一新生代砂页岩中赋存有许多脉状铜矿床。本文对盆地内从北至南三个典型脉状铜矿床(金满、水泄和白龙厂)进行了详细的铅、硫同位素研究，探讨了该类型矿床的成矿物质来源。分析表明。该类型矿床的铅同位素组成总体变化较小，且均位于上地壳铅演化线附近，说明成矿流体中铅具有稳定的上地壳来源。各矿床由于赋矿层位不同，矿石铅同位素组成表现出一定差异，如由兰坪盆地侏罗纪地层中的金满矿床到思茅盆地二叠纪地层中的白龙厂矿床，铅同位素比值(^207Pb/^204Pb)呈增高趋势，这表明这类矿床的铅主要来源于围岩地层，且地层越老，提供的铅就相对富含放射成因铅。矿床中脉石矿物重晶石、铁白云石等的锶同位素组成也表明，金满矿床成矿流体的^87Sr／^86Sr比值较高(0．70874—0．71232)，而白龙厂矿床的^87Sr／^86Sr比值较低(0．70829—0．70938)，接近于围岩灰岩的值(0．70755)。硫同位素研究表明，金满矿床中硫化物的δ^34S值变化最大，为-20．5‰- 7．0‰。水泄矿床中硫化物的δ^34S值变化最小，为-0．1‰- 4．2‰。而白龙厂矿床中硫化物的δ^34S值为-14．3‰--3．6‰。水泄和白龙厂矿床中重晶石的δ^34S值分别为 12．3‰- 19．0‰和 13．1‰，它们与盆地中蒸发岩层中石膏的δ^34S值( 10．8‰- 15．7‰)相近。分析表明，兰坪-思茅盆地中脉状铜矿的硫源主要来源于盆地热卤水萃取的地层中蒸发岩硫酸盐，它们通过有机质的热分解反应还原为沉淀硫化物所必需的低价硫。各矿床独特的硫同位素组成还表明它们的硫源受局部地层硫源和成矿流体物理化学性质所控制。本文提出大气降水起源的盆地热卤水通过对围岩中新生代地层的淋滤和萃取，获得了成矿所需的金属和硫，并在构造薄弱部位沉淀形成了本区的脉状铜矿床。  相似文献   

Nonlinear Rate Dependent Model of High Damping Rubber Bearing     

Robert Jankowski 《Bulletin of Earthquake Engineering》2003,1(3):397-403

The accurate analysis of the response of isolated structures requires the application of appropriate models of isolation devices. The purpose of this paper is to analyse a nonlinear strain rate dependent model of a high damping rubber bearing which simulates the horizontal behaviour of the device under specified vertical load using a nonlinear elastic spring-dashpot element. The effectiveness of the model is checked by fitting the experimental data concerning three different rubber bearings. The results of the study show that the model can simulate the bearing behaviour over a wide shear strain range with small simulation errors. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献