褐藻酸苄酯的合成与表征     

甘纯玑  蔡乐琤 《海洋科学》1990,14(2):45-47

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Trends in the solubility of iron,aluminium, manganese and phosphorus in aerosol collected over the Atlantic Ocean     

A.R. Baker  T.D. Jickells  M. Witt  K.L. Linge 《Marine Chemistry》2006

The solubility of iron, aluminium, manganese and phosphorus has been determined in aerosol samples collected between 49°N and 52°S during three cruises conducted in the Atlantic Ocean as part of the European Union funded IRONAGES programme. Solubilities (defined at pH 4.7) determined for Fe and Al in samples of Saharan dust were significantly lower (medians 1.7% and 3.0%, respectively) than the solubilities of these metals in aerosols from other source regions (whole dataset medians 5.2% and 9.0%, respectively). Mn solubility also varied with aerosol source, but the median solubility of Mn in Saharan dust was very similar to the median for the dataset as a whole (55% and 56%, respectively). The observed solubility of aerosol P was ∼ 32%, with P solubility in Saharan aerosol perhaps as low as 10%. Laboratory studies have indicated that aerosol Fe solubility is enhanced by acid processing. No relationship could be found between Fe solubility and the concentrations of acid species (non-seasalt SO₄²⁻, NO₃⁻) nor the net acidity of the aerosol, so we are unable to confirm that this process is significant in the atmosphere. In terms of the supply of soluble Fe to oceanic ecosystems on a global scale, the observed higher solubility for Fe in non-Saharan aerosols is probably not significant because the Sahara is easily the dominant source of Fe to the Atlantic. On a smaller scale however, higher solubility for aerosol Fe may alter our understanding of Fe cycling in regions such as the remote Southern Ocean.  相似文献   

Lichen-dominated soil crusts as arthropod habitat in warm deserts   总被引：2，自引：0，他引：2  

J.S. Lalley  H.A. Viles  J.R. Henschel  V. Lalley 《Journal of Arid Environments》2006,67(4):579-593

Soil crust lichens can be the dominant vegetation in arid lands, yet their importance as habitat to secondary producers is relatively unknown. This study examines the distribution of arthropod communities in the northern Namib Desert to evaluate whether a lichen-rich area is more or less productive than adjacent habitats in terms of the consumers each supports. Arthropods are diverse and highly endemic in the Namib Desert and lichens dominate this desert's extensive gravel plains. We sampled lichen-rich, dwarf shrub, and unvegetated sites and found distinct arthropod assemblages in the lichen-dominated sites, including species unique to lichen sites. Arthropod assemblages in two of the lichen sites were similar to those found in the dwarf shrub site. In a canonical correspondence analysis, crustose lichens and overall lichen cover were key in driving the variance in arthropod assemblages within the lichen sites. Furthermore, lichen morphotypes, overall lichen cover and species richness, were significantly correlated with the representation of arthropod subgroups and arthropod species richness. These findings provide evidence that lichen-dominated soil crusts in the Namib Desert are important supporters of secondary production, warranting more in-depth studies into the ecology and conservation of this lichen-rich habitat in warm deserts.  相似文献   

超临界流体中MoO3与WO3溶解度实验探讨   总被引：1，自引：1，他引：1  

龚庆杰  於崇文岑况 王玉荣 《岩石学报》2005,21(1):240-244

超临界地质流体以其独特的性质对金属成矿元素具有超强的萃取、层析和搬运能力,在热液矿床成矿机制研究中对揭示成矿物质的源、流和汇起着特殊和重要作用。本文利用分析纯H2MoO4在高温下脱水制备了MoO3(白色斜方晶系),在冷封式高压釜中实验测定了417℃超临界条件下,MoO3在纯水中的溶解度分别为7.3(29MPa)、14.2(45MPa)、21.6(55MPa)、27.7(78MPa)、32.5(100MPa)、和34.2(150MPa)mmol/l,热液中钼的存在形式为H2MoO4。依据前人的实验方案,补充测定了WO3在4.0%NaCl水溶液中于450%条件下的溶解度,其值分别为27.51(50MPa)和30.52(100MPa)mmol/l。结合前人研究结果发现,MoO3、WO3的溶解度在临界区域内具有超临界现象,在超临界条件下其溶解度与石英的超临界溶解度行为基本相似,表现为溶解度随体系温度和压力的升高而增大,这对揭示岩浆热液型和石英脉型钨、钼矿床的形成机制具有重要指导作用。  相似文献   

Formation of hydroxyl radicals catalyzed by clay surfaces     

D. Gournis  M. A. Karakassides  D. Petridis 《Physics and Chemistry of Minerals》2002,29(2):155-158

 The formation of superoxide and hydroxyl radicals at the surface of smectite clays due to oxygen reduction is demonstrated by electron paramagnetic resonance spectroscopy. The yield of hydroxyl radicals is mainly a function of particle size of the clays and depends, to a lesser extent, on the clay lattice iron. Synthetic laponite clay with small platelet size (∼20 nm) and without lattice iron is leading in the formation of hydroxyl radicals followed by montmorillonite (∼200 nm). Fluorohectorite (∼2000 nm) was inactive to hydroxyl radical formation by oxygen reduction. Received: 20 January 2001 / Accepted: 7 August 2001  相似文献   

Interpretation of charging on fracture or frictional slip surface of rocks     

Akihiro Takeuchi  Hiroyuki Nagahama 《Physics of the Earth and Planetary Interiors》2002,130(3-4):285-291

Fracturing and frictional sliding of quartz and granite under dry condition generates fractoluminescence, charged particle emission and electromagnetic radiation. Various kinds of experiments indicate that surface charge density on fracture or frictional slip surface of quartz and granite is 10⁻⁴ to 10⁻² C/m² which is larger than bound charges induced by the disappearance of piezoelectricity due to the release of stress. Hole and electron trapping centers, which is found in semiconductor devices with the Si–SiO₂ system, are causes of surface charging on fracture or frictional slip surface of quartz crystal. The quantity of the surface charge is enough to cause corona discharge that can generate earthquake lights. The mechanism considering the hole and electron trapping centers has a probability to explain why non-piezoelectric minerals or rocks generate electromagnetic phenomena. It can be one of origins of seismo-electromagnetic phenomena (SEP).  相似文献   

KCl-KNO3-CH3OH/H2O和KNO3-NH4NO3-CH3OH/H2O三元体系在25℃时的溶解度          下载免费PDF全文

刘亦凡  谢爱华  钟杰  董殿权 《盐湖研究》2003,11(1):66-69

测定了 2 5℃时KCl KNO3 CH3 OH H2 O和KNO3 NH4NO3 CH3 OH H2 O三元体系的溶解度 ,并与 2 5℃时相应体系在水中的溶解度进行了比较。  相似文献   

Determination of paleo-pressure for a natural gas pool formation based on PVT characteristics of fluid inclusions in reservoir rocks——A case study of Upper-Paleozoic deep basin gas trap of the Ordos Basin   总被引：1，自引：2，他引：1  

MI Jingkui    XIAO Xianming  LIU Dehan  & SHEN Jiagui .State Key Laboratory of Organic Geochemistry  Guangzhou Institute of Geochemistry  Chinese Academy of Sciences  Guangzhou  China  .Institute of Sedimentary Mineral  Resources  Department of Civil Engineering  Xiangtan Polytechnic University  Xiangtan  China 《中国科学D辑(英文版)》2004,(6)

~~Determination of paleo-pressure for a natural gas pool formation based on PVT characteristics of fluid inclusions in reservoir rocks——A case study of Upper-Paleozoic deep basin gas trap of the Ordos Basin~~  相似文献   

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts   总被引：4，自引：0，他引：4  

Robert L. Linnen   《Lithos》2005,80(1-4):267-280

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

The behavior of magneto-acoustic-gravity waves near the cusp resonance in a lossless,compressible, isothermal,stratified, electrically conducting and uniformly magnetized atmosphere. II: The valve effect     

Leon P. J. Kamp 《地球物理与天体物理流体动力学》2013,107(4):257-271

Abstract

In the present paper the behavior of (internal) magneto-acoustic-gravity waves near the cusp resonance in a lossless, compressible, isothermal, stratified, electrically conducting atmosphere that is permeated by a uniform, nearly horizontal magnetic field is re-addressed (Kamp, 1989). The previously analyzed linear conversion of long acoustic-gravity waves into short magneto-acoustic waves that carry off the energy from the resonance region along the magnetic field, is re-analyzed with boundary layer techniques that are based on the smallness of the vertical component of the magnetic field. More specifically the existence of the so-called valve effect for the generated magneto-acoustic mode near the critical level is explicitly demonstrated and shown to be governed by two rivalling effects.  相似文献