High-frequency monitoring of hydrological and biogeochemical fluxes in forested catchments of southern Chile     

Cristián Frêne  Juan J. Armesto  Freddy Véliz  Fernando D. Alfaro  Kathleen C. Weathers 《水文研究》2021,35(5):e14175

The variability of rainfall-dependent streamflow at catchment scale modulates many ecosystem processes in wet temperate forests. Runoff in small mountain catchments is characterized by a quick response to rainfall pulses which affects biogeochemical fluxes to all downstream systems. In wet-temperate climates, water erosion is the most important natural factor driving downstream soil and nutrient losses from upland ecosystems. Most hydrochemical studies have focused on water flux measurements at hourly scales, along with weekly or monthly samples for water chemistry. Here, we assessed how water and element flows from broad-leaved, evergreen forested catchments in southwestern South America, are influenced by different successional stages, quantifying runoff, sediment transport and nutrient fluxes during hourly rainfall events of different intensities. Hydrograph comparisons among different successional stages indicated that forested catchments differed in their responses to high intensity rainfall, with greater runoff in areas covered by secondary forests (SF), compared to old-growth forest cover (OG) and dense scrub vegetation (CH). Further, throughfall water was greatly nutrient enriched for all forest types. Suspended sediment loads varied between successional stages. SF catchments exported 455 kg of sediments per ha, followed by OG with 91 kg/ha and CH with 14 kg/ha, corresponding to 11 rainfall events measured from December 2013 to April 2014. Total nitrogen (TN) and phosphorus (TP) concentrations in stream water also varied with rainfall intensity. In seven rainfall events sampled during the study period, CH catchments exported less nutrients (46 kg/ha TN and 7 kg/ha TP) than SF catchments (718 kg/ha TN and 107 kg/ha TP), while OG catchments exported intermediate sediment loads (201 kg/ha TN and 23 kg/ha TP). Further, we found significant effects of successional stage attributes (vegetation structure and soil physical properties) and catchment morphometry on runoff and sediment concentrations, and greater nutrients retention in OG and CH catchments. We conclude that in these southern hemisphere, broad-leaved evergreen temperate forests, hydrological processes are driven by multiple interacting phenomena, including climate, vegetation, soils, topography, and disturbance history.  相似文献   

Predicting quantiles of water quality from catchment characteristics     

Danlu Guo  Shuci Liu  Dhananjay Singh  Andrew W. Western 《水文研究》2021,35(1):e13996

Water quality is often highly variable both in space and time, which poses challenges for modelling the more extreme concentrations. This study developed an alternative approach to predicting water quality quantiles at individual locations. We focused on river water quality data that were collected over 25 years, at 102 catchments across the State of Victoria, Australia. We analysed and modelled spatial patterns of the 10th, 25th, 50th, 75th and 90th percentiles of the concentrations of sediments, nutrients and salt, with six common constituents: total suspended solids (TSS), total phosphorus (TP), filterable reactive phosphorus (FRP), total Kjeldahl nitrogen (TKN), nitrate-nitrite (NO_x), and electrical conductivity (EC). To predict the spatial variation of each quantile for each constituent, we developed statistical regression models and exhaustively searched through 50 catchment characteristics to identify the best set of predictors for that quantile. The models predict the spatial variation in individual quantiles of TSS, TKN and EC well (66%–96% spatial variation explained), while those for TP, FRP and NO_x have lower performance (37%–73% spatial variation explained). The most common factors that influence the spatial variations of the different constituents and quantiles are: annual temperature, percentage of cropping land area in catchment and channel slope. The statistical models developed can be used to predict how low- and high-concentration quantiles change with landscape characteristics, and thus provide a useful tool for catchment managers to inform planning and policy making with changing climate and land use conditions.  相似文献   

Variations in the natural abundance of 15N in estuarine suspended particulate matter: A specific indicator of biological processing     

N.J.P. Owens 《Estuarine, Coastal and Shelf Science》1985,20(4):505-510

In this study, the ¹⁴N:¹⁵N ratio of suspended particulate material collected from the Tamar river estuary, south-west England, is described. Three populations of particles, distinguishable by their ¹⁵N content, were observed. This investigation has shown that populations of estuarine particles are generated by biological transformations in situ and that the ¹⁵N content of estuarine particles does not merely reflect hydrodynamic mixing of the freshwater and seawater source particulate material.  相似文献   

A dated cave sediment record of Pleistocene transgressions on Berry Head,Southwest England     

Christopher J. Proctor  Peter L. Smart 《第四纪科学杂志》1991,6(3):233-244

Berry Head, a limestone headland in Torbay, southwest England, exhibits a series of subaerial marine erosion platforms and raised beaches spanning an altitude range of 97 m. Solution caves on the headland show preferred horizontal development at elevations that are correlated with the marine erosion platforms, and developed in a marine/freshwater mixing zone whose position was controlled by high sea-level still-stands. Corbridge Cave in Berry Head Quarry lies below the raised beaches in Torbay, and contains evidence of three marine transgressions in the form of fine-grained marine ponding deposits with a marine microfauna. Uranium-series dating of intercalated speleothems indicates that a transgression during oxygen isotope stage 5e reached an elevation of 5.8 m OD, while an earlier transgression (probably during stage 7) reached at least 7.2 m OD. These findings are used to constrain possible interpretations of the aminostratigraphy of raised beaches in Southwest Britain, and a correlation of the Unnamed Stage of Bowen, Sykes, Reeves, Miller, Andrews, Brew and Hare with oxygen isotope stage 5e is proposed.  相似文献   

River sediments,great floods and centennial‐scale Holocene climate change     

Mark G. Macklin  John Lewin 《第四纪科学杂志》2003,18(2):101-105

A new analysis of all 346 published ¹⁴C dated Holocene alluvial units in Britain offers a unique insight into the regional impacts of global change and shows how surprisingly sensitive British rivers have been to relatively modest but repeated changes in climate. Fourteen major but probably brief periods of flooding are identified bracketed within the periods 400–1070, 1940–3940, 7520–8100 and at ca. 10 420 cal. yr BP. There is a strong correspondence between climatic deteriorations inferred from mire wet shifts and major periods of flooding, especially at ca. 8000 cal. yr BP and since ca. 4000 cal. yr BP. The unusually long and complete British record also demonstrates that alterations in land cover have resulted in a step change in river basin sensitivity to variations in climate. This has very important implications for assessing and mitigating the impact of increasing severe flooding. In small and medium‐sized river basins land use is likely to play a key role in either moderating or amplifying the climatic signal. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

MONITORING THE DIFFUSION OF SUSPENDED SEDIMENTS AND STABILITY OF TIDAL RADIAL SAND RIDGES AREA USING MULTI-SATELLITE REMOTE SENSING DATA     

黄海军  何宜军 《中国海洋湖沼学报》2001,19(4):361-367

Nine Landsat TM tapes and images and MSS images, 10 NOAA tapes and images and 1 SAR image from 1973 to 1997 were used to analyse the diffusion of suspended sediments and the change of tidal radial sand ridges in the northern part of the Changjiang River delta, the South Yellow Sea. The results showed that the diffusion of suspended sediments was controlled by the tide, net current, and submarine topography in this area. The distribution of suspended sediments had close relationship with thesubmarine topography. The old Huanghe River delta and the Changjiang River comprise the main sediment supply for the formation of radial sand ridges, whose evolution can be divided into three stages since the Huangbe River changed its course and flowed northward into the Bohai Sea.  相似文献   

The solubility of iron sulphides in synthetic and natural waters at ambient temperature   总被引：1，自引：1，他引：0  

W. Davison 《Aquatic Sciences - Research Across Boundaries》1991,53(4):309-329

A critical evaluation of literature values for the solubility products, K _sp ^NBS = [Fe²⁺][HS^–] Fe²⁺ HS^– (H _NBS ⁺ )^–1, of various iron sulphide phases results in consensus values for the pKs of 2.95 ± 0.1 for amorphous ferrous sulphide, 3.6 ± 0.2 for mackinawite, 4.4 ± 0.1 for greigite, 5.1 ± 0.1 for pyrrhotite, 5.25 ± 0.2 for troilite and 16.4 ± 1.2 for pyrite.Where the analogous ion activity products have been measured in anoxic freshwaters in which there is evidence for the presence of solid phase FeS, the values lie within the range of 2.6–3.22, indicating that amorphous iron sulphide is the controlling phase. The single value for a groundwater of 2.65 (2.98 considering carbonate complexation) agrees. In seawater four values range between 3.85 to 4.2, indicating that mackinawite or greigite may be the controlling phase. The single low value of 2.94 is in a situation where particularly high fluxes of Fe (II) and S (–II) may result in the preferential precipitation of amorphous iron sulphide. Formation of framboidal pyrite in these sulphidic environments may occur in micro-niches and does not appear to influence bulk concentrations. Calculations show that the formation of Fe₂S₂ species probably accounts for very little of the iron or sulphide in most natural waters. Previously reported stability constants for the formation of Fe (HS)₂ and (Fe (HS)₃)^– are shown to be suspect, and these species are also thought to be negligible in natural waters. In completely anoxic pore waters polysulphides also have a negligible effect on speciation, but in tidal sediments they may reach appreciable concentrations and lead to the direct formation of pyrite. Concentrations of iron and sulphide in pore waters can be controlled by the more soluble iron sulphide phase. The change in the IAP with depth within the sediment may reflect ageing of the solid phase or a greater flux of Fe (II) and S (–II) nearer the sediment surface. This possible kinetic influence on the value of IAPs has implications for their use in geochemical studies involving phase formation.  相似文献   

Alluvial architecture of the Holocene Rhine–Meuse delta (the Netherlands)     

MARC J.P. GOUW 《Sedimentology》2008,55(5):1487-1516

Ancient fluvial successions often act as hydrocarbon reservoirs. Sub‐surface data on the alluvial architecture of fluvial successions are often incomplete and modelling is performed to reconstruct the stratigraphy. However, all alluvial architecture models suffer from the scarcity of field data to test and calibrate them. The purposes of this study were to quantify the alluvial architecture of the Holocene Rhine–Meuse delta (the Netherlands) and to determine spatio‐temporal trends in the architecture. Five north–south orientated cross‐sections, perpendicular to the general flow direction, were compiled for the fluvial‐dominated part of the delta. These sections were used to calculate the width/thickness ratios of fluvial sandbodies (SBW/SBT) and the proportions of channel‐belt deposits (CDP), clastic overbank deposits (ODP) and organic material (OP) in the succession. Furthermore, the connectedness ratio (CR) between channel belts was calculated for each cross‐section. Distinct spatial and temporal trends in the alluvial architecture were found. SBW/SBT ratios decrease by a factor of ca 4 in a downstream direction. CDP decreases from ca 0·7 (upstream) to ca 0·3 (downstream). OP increases from less than 0·05 in the upstream part of the delta to more than 0·25 in the downstream delta. ODP is approximately constant (0·4). CR is ca 0·25 upstream, which is approximately two times larger than in the downstream part of the delta. Furthermore, CDP in the downstream Rhine–Meuse delta increases after 3000 cal yr BP. These trends are attributed to variations in available accommodation space, floodplain geometry and channel‐belt size. For instance, channel belts tend to narrow in a downstream direction, which reduces SBW/SBT, CDP and CR. Tectonics cause local deviations in the general architectural trends. In addition, the positive correlation between avulsion frequency and the ratio of local to regional aggradation rate probably influenced alluvial architecture in the Rhine–Meuse delta. The Rhine–Meuse data set can be a great resource when developing more sophisticated models for alluvial architecture simulation, which eventually could lead to better characterizations of hydrocarbon reservoirs. To aid such usage of the Rhine–Meuse data set, constraints for relevant parameters are provided at the end of the paper.  相似文献   

Structural characterization of deep-water deposits in a foreland basin, Silla Syncline (Chilean Patagonia), with applications to depositional processes     

Joseph Gonzales  Atilla Aydin 《Journal of Structural Geology》2008,30(9):1095-1108

Based on our detailed structural characterization, we examine possible relationships between thrust faults and strike-slip faults and thrust-cored folds and depositional units in the Silla Syncline, a 4 km wide fold composed of fine-grained mudstone, coarse sandstone and conglomerate deposits of the Cerro Toro Formation in the Magallanes foreland basin, Chilean Patagonia. The syncline is bounded on its western flank by an asymmetric anticline and on its eastern flank by a broad zone of thrust faults and associated folds, which are oriented sub-parallel to the syncline axis. Deposition of the coarse-grained units of the Silla Syncline appears to have taken place in this structurally defined trough controlled primarily by thrust fault related growth structures flanking the syncline.The syncline and surrounding area have also been deformed by two sets of strike-slip faults, one right-lateral and one left-lateral. The strike-slip and thrust faulting operated contemporaneously for much of their active periods, although it appears that thrust faulting, confined within the fine-grained units, initiated slightly earlier than strike-slip faulting. In addition, younger igneous intrusions at high angle to bedding generally localize along the strike-slip faults. The cross-cutting relationships among the intrusions, strike-slip faults, and flexural slip faults show that all these structures were active during the same period, which extends beyond mid-Miocene.These conclusions support the premise that structures in deep-water sediments are important for understanding not only the deformation of a foreland basin, but also its depositional architecture.  相似文献   

Multiple discriminant analysis of the Drava River alluvial plain sediments     

Zoran Peh  Robert Šajn  Josip Halamić  Lidija Galović 《Environmental Geology》2008,55(7):1519-1535

Three discriminant function models are raised and cross-compared in order to distinguish geochemical patterns characteristic for the Drava River floodplain sediments. Based on data representing total element concentrations in samples collected from alluvium (A), terrace (T), and unconsolidated bedrock (B) at the border of a floodplain, four element clusters emerged accounting for discrimination between the referred groups of sediments. The most prominent is contaminant/carbonate cluster characteristic for alluvium. The other two are: silicate cluster typical for unconsolidated geological substrate (Neogene sedimentary rocks); and naturally dispersed heavy metal cluster separating terrace from the former two groups. Models introducing depth intervals and single profiles as grouping criteria reveal identical sediment-heavy metal matrices. The second important issue of this paper is possibility of reclassification of samples originally assigned to one of the a priori defined groups of sediments, based on established geochemical pattern. The mapped geological units can be reconsidered by the post hoc assignments to a different group if geological border between alluvium and terrace or between terrace and bedrock can not be established geologically with absolute certainty.  相似文献