Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Analytical study of ground motion caused by seismic wave propagation across faulted rock masses          下载免费PDF全文

J.C. Li  N.N. Li  S.B. Chai  H.B. Li 《国际地质力学数值与分析法杂志》2018,42(1):95-109

Studying seismic wave propagation across rock masses and the induced ground motion is an important topic, which receives considerable attention in design and construction of underground cavern/tunnel constructions and mining activities. The current study investigates wave propagation across a rock mass with one fault and the induced ground motion using a recursive approach. The rocks beside the fault are assumed as viscoelastic media with seismic quality factors, Q_p and Q_s. Two kinds of interactions between stress waves and a discontinuity and between stress waves and a free surface are analyzed, respectively. As the result of the wave superposition, the mathematical expressions for induced ground vibration are deduced. The proposed approach is then compared with the existing analysis for special cases. Finally, parametric studies are carried out, which includes the influences of fault stiffness, incident angle, and frequency of incident waves on the peak particle velocities of the ground motions.  相似文献   

The Roche Limit     

I. P. Williams 《Celestial Mechanics and Dynamical Astronomy》2003,87(1-2):13-25

The role of tides in deforming and possibly disrupting a secondary body orbiting about a primary body has been known for a considerable time. This was first inspired by the observations of ocean tides on Earth and then seen as playing an important role in the formation and evolution of the Earth–Moon system. Finally, in the beginning of the 20th century it was generally thought to have a significant role in the formation of the solar system through the tidal disruption of the Sun. Here, an overview of the historical developments of the ideas concerned with tidal disruption of a secondary body that can lead to mass loss is given. Some discussion of possible extensions to consider more realistic situations where the secondary body may not be moving on a circular orbit and may not rotate so as to maintain the phase-on configuration to the primary body is also given.  相似文献   

板翅式换热器综合性能优化的设计方法     

高俊忠  陈维汉 《广东海洋大学学报》2003,23(6):45-49

应用给定换热器结构材料而使换热量最大的两侧换热表面的最佳匹配准则和使可用能损失率最小的最佳运行参数准则。利用两个准则间的关系 ,采用迭代的方式完成换热器的优化设计 ,使换热器的设计达到材料省、换热效果好及运行费用低的目的 ,且能在设计阶段实现。  相似文献   

Synthetic SH seismograms in a laterally varying medium by the discrete wavenumber method   总被引：1，自引：0，他引：1  

Michel Campillo  Michel Bouchon 《Geophysical Journal International》1985,83(1):307-317

Summary. We present a new method to calculate the SH wavefield produced by a seismic source in a half-space with an irregular buried interface. The diffracting interface is represented by a distribution of body forces. The Green's functions needed to solve the boundary conditions are evaluated using the discrete wavenumber method. Our approach relies on the introduction of a periodicity in the source-medium configuration and on the discretization of the interface at regular spacing. The technique developed is applicable to boundaries of arbitrary shapes and is valid at all frequencies. Some examples of calculation in simple configurations are presented showing the capabilities of the method.  相似文献   

中国大陆科学钻探先导孔零偏VSP资料解释   总被引：3，自引：3，他引：0  

姜修道  朱光明  朱龙生  张文波  李桂花 《地球科学与环境学报》2004,26(1):55-60

用六级三分量检波器在中国大陆科学钻探先导孔中实施了零偏VSP测量.数据处理结果表明,中国大陆科学钻探孔区超高压变质岩石的地震波速度主要介于4500～7000m/s之间,显著高于一般的沉积岩地区,而且随深度变化不明显.声波测井速度系统地稍低于VSP层速度,可能是由于井壁处岩石的完整性受到破坏而造成的.地震波速度与岩石密度和岩性存在明确的对应关系,榴辉岩的密度和地震波速度均显著高于片麻岩类岩石;由榴辉岩退变生成的斜长角闪岩类岩石,其密度和地震波速度均呈现出较大的变化,主要与其退变质程度有关;超基性岩中的裂隙系统导致其密度和地震波速度大幅度下降.由于榴辉岩与其他岩石类型之间存在较大的波阻抗差异,因此用零偏VSP资料标定该区地震波的地质层位是有效的.关于地震波反射的原因,通过综合研究地震波(包括反射纵波、上行转换横波、井筒波)的特征、岩石速度和密度分布以及井径变化,认为主要是岩性分界面、韧性剪切带和断裂(带),但还有一些因素尚待进一步研究.  相似文献   

柴达木盆地东北缘古元古代变质镁铁—超镁铁质岩的地质特征及成因探讨     

王毅志  梁超云 《青海国土经略》2001,(Z1)

1:5万区域地质调查工作中,在柴达木陆块北缘首次发现古元古代变质镁铁—超镁铁质岩,获得成岩年龄为1952±15Ma,其岩石化学、地球化学特征反映出岩浆来源于亏损地幔,反映出该地区克拉通在古元古代(19亿年)发生了一次强烈的裂解(洋)事件,对于研究柴达木盆地北缘元古代结晶基底地质构造演化及进一步探讨柴达木盆地的起源及构造演化过程提供了重要地质线索。  相似文献   

关于网络用户经济效益评测模型的研究     

岳正华  李黎 《成都信息工程学院学报》2001,16(2):141-144

着重讨论了网络用户经济效益的内涵以及用户的投入量和产出量，并提出了评价网络用户经济效益的指标体系，包括成本降低率，成本利润增长率、产品开发时间约率、市场占有增长率等系列指标。  相似文献   

Viscosity of the upper mantle from laboratory creep and anelasticity measurements in peridotite at high pressure and temperature     

Hiroki Sato 《Geophysical Journal International》1991,105(3):587-599

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Wolf-Rayet stars     

K. A. van der Hucht 《Astronomy and Astrophysics Review》1992,4(2):123-159

Summary Recent literature on Population I Wolf-Rayet star research extending from the Milky Way to blue compact dwarf galaxies is reviewed, broken down into inventory, basic parameters and galactic distribution, atmospheres, binaries, intrinsic variability, mass loss, enrichment and evolution. Also the incidence of Wolf-Rayet stars with variable non-thermal radio emission, excess X-ray fluxes, and episodic/periodic IR excesses is reviewed. These phenomena appear to be associated with wind-wind interaction in wide long-period WR+OB binaries and with wind-compact object interaction in WR+c binaries, with orbit sizes of the order of magnitude of the WR radio photosphere sizes or larger.  相似文献