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1.
《Chemie der Erde / Geochemistry》2021,81(1):125677
The Lagoa Real uranium (U) province, referred to as Lagoa Real, is located in the state of Bahia, north-eastern Brazil. Lagoa Real has ∼112,000 metric tonnes and average grade of 2700 ppm of U3O8, being one of the largest U deposits in the world and the largest in Brazil. Despite its economic and strategic importance, there are gaps in the geological knowledge of the Lagoa Real U deposits. One of them is the lack of extensive whole-rock chemical data sets. Here, we present whole-rock chemical analyses for major and trace elements, including the rare-earth elements (REE), from barren country rocks to uraniferous ore shoot, systematically sampled from an exploratory drill hole. The chemical data indicate that albitite rocks, with and without uraniferous mineralisation, cannot result from sodic syenitic magmatism, as proposed by recent studies. Petrographical and geochemical evidence supports the previously suggested concept that the Lagoa Real albitite rocks resulted from sodic metasomatism of the granitic country rock, known as the São Timóteo granite. Their ore-mineral assemblages and geochemical characteristics are similar to albitite-hosted U deposits worldwide. 相似文献
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The Valhalla uranium deposit, located 40 km north of Mount Isa, Queensland, Australia, is an albitite-hosted, Mesoproterozoic
U deposit similar to albitite-hosted uranium deposits in the Ukraine, Sweden, Brazil and Guyana. Uranium mineralisation is
hosted by a thick package of interbedded fine-grained sandstones, arkoses and gritty siltstones that are bound by metabasalts
belonging to the ca. 1,780 Ma Eastern Creek Volcanics in the Western Succession of the Mount Isa basin. Alteration associated
with U mineralisation can be divided into an early, main and late stage. The early stage is dominated by laminated and intensely
altered rock comprising albite, reibeckite, calcite, (titano)magnetite ± brannerite. The main stage of mineralisation is dominated
by brecciated and intensely altered rocks that comprise laminated and intensely altered rock cemented by brannerite, apatite,
(uranoan)-zircon, uraninite, anatase, albite, reibeckite, calcite and hematite. The late stage of mineralisation comprises
uraninite, red hematite, dolomite, calcite, chlorite, quartz and Pb-, Fe-, Cu-sulfides. Brannerite has U–Pb and Pb–Pb ages
that indicate formation between 1,555 and 1,510 Ma, with significant Pb loss evident at ca. 1,200 Ma, coincident with the
assemblage of Rodinia. The oldest ages of the brannerite overlap with 40Ar/39Ar ages of 1,533 ± 9 Ma and 1,551 ± 7 Ma from early and main-stage reibeckite and are interpreted to represent the timing
of formation of the deposit. These ages coincide with the timing of peak metamorphism in the Mount Isa area during the Isan
Orogeny. Lithogeochemical assessment of whole rock data that includes mineralised and unmineralised samples from the greater
Mount Isa district reveals that mineralisation involved the removal of K, Ba and Si and the addition of Na, Ca, U, V, Zr,
P, Sr, F and Y. U/Th ratios indicate that the ore-forming fluid was oxidised, whereas the crystal chemistry of apatite and
reibeckite within the ore zone suggests that F− and were important ore-transporting complexes. δ18O values of co-existing calcite and reibeckite indicate that mineralisation occurred between 340 and 380°C and involved a
fluid having δ18Ofluid values between 6.5 and 8.6‰. Reibeckite δD values reveal that the ore fluid had a δDfluid value between −98 and −54‰. The mineral assemblages associated with early and main stages of alteration, plus δ18Ofluid and δDfluid values, and timing of the U mineralisation are all very similar to those associated with Na–Ca alteration in the Eastern
Succession of the Mount Isa basin, where a magmatic fluid is favoured for this style of alteration. However, isotopic data
from Valhalla is also consistent with that from the nearby Mount Isa Cu deposit where a basinal brine is proposed for the
transport of metals to the deposit. Based on the evidence to hand, the source fluids could have been derived from either or
both the metasediments that underlie the Eastern Creek Volcanics or magmatism that is manifest in the Mount Isa area as small
pegmatite dykes that intruded during the Isan Orogeny. 相似文献
4.
缅甸硬玉岩地区的热液型钠长石岩 总被引：2，自引：0，他引：2
产于俯冲带内的低温高压带的由单矿物构成的硬玉岩通常伴有钠长石岩,目前对于硬玉岩研究的关注度较高,而对于钠长石岩则相对较低,很少有相关论文报导.产于缅甸翡翠矿区的钠长石岩,经常与硬玉岩相伴而生,是良好的研究样品.钠长石岩的主要矿物成分是低温钠长石,其次含有硬玉、绿辉石、透辉石等辉石类矿物和钠透闪石、蓝透闪石、镁钠闪石等闪石类矿物,此外还有钠沸石等.钠长石沿着解理和裂隙交代硬玉,说明钠长石形成晚于硬玉岩.钠长岩中的主要组成矿物钠长石的形成温度小于300℃,且其形成压力小于0.5kb,推测是在硬玉岩抬升程中通过交代与沉淀作用形成.其内的透辉石有两种类型,一类可能是被交代的硬玉中的透辉石组分会渐进增加,最终形成透辉石.另一类是被绿辉石包裹的透辉石残留,其很有可能是早期来自地幔楔或者俯冲带岩石中的矿物残留,即异剥钙榴岩或辉石岩类,可以视作硬玉化绿辉石岩和硬玉化异剥钙榴岩的矿物学证据.热液型钠长石岩的存在进一步说明缅甸翡翠矿区钠化热液存在现象的普遍性与穿越性. 相似文献
5.
Francesca Castorina Umberto Masi Giorgio Padalino Marcella Palomba 《Mineralium Deposita》2006,41(4):323-338
Major- and trace-element contents and Sr–Nd isotope ratios were determined in albitite, albitized and unaltered late-Variscan granitoid samples from the world-class Na-feldspar deposits of central Sardinia, Italy. The albite deposit of high economic grade has geological, textural, and chemical features typical of metasomatic alteration affecting the host granitoids. Albitization, locally accompanied by chloritization and epidotization, was characterized by strong leaching of Mg, Fe, K, and geochemically similar trace elements, and by a significant increase of Na. Ca, and P were moderately leached in the most metasomatized rocks. Other major (Si, Ti, Ca) and trace elements (U, Th, Y, and Zr), along with light (LREE) and middle (MREE) rare-earth elements, behaved essentially immobile at the deposit scale. The Nd-isotope ratios (0.512098 to 0.512248) do not provide information on the emplacement age of the unaltered late-Variscan granitoids. On the other hand, their Sr-isotope ratios fit an errorchron of 274±29 Ma (1σ error), in fair agreement with all published ages of Sardinian Variscan granitoids. The very low Rb content of albitized rocks precludes application of the Rb–Sr radiometric system to determine the age of albitization. The Sm–Nd system is not applicable either, because the 143Nd/144Nd ratios of albitized rocks and unaltered granitoids overlap. The overlap confirms that Sm and Nd were substantially immobile during albitization. On the other hand, the measured 87Sr/86Sr ratios of the albitized rocks are appreciably lower than those of the unaltered host granitoids, whereas, their initial Sr-isotope ratios are higher. This seems to suggest that a) albitization was induced by non-magmatic fluids rich in radiogenic Sr, and b) albitization occurred shortly after the granitoid emplacement. This conclusion is supported by Nd isotopes, because unaltered granitoids and albitites fit the same reference isochron at 274 Ma. The fluids acquired radiogenic Sr by circulation through the Lower Paleozoic metasedimentary basement. Specifically, it is estimated that Sr supplied by the non-carbonatic basement represents about 22 wt% of total Sr in albitite. 相似文献
6.
Albitite often accompanies with various metal and gem mineral deposits and a large number of occurrences have been reported globally, including the South Qinling orogen, China. The Xiaozhen copper deposit is a typical deposit in the North Daba Mountain area of the South Qinling orogen whose distribution is controlled by albitite veins and fractures. As there are few studies on the petrogenesis of albitite in Xiaozhen copper deposit, this paper focuses on the petrogenesis of albitite and its mineralization age. Detailed fieldwork and mineral microscopic observations initially suggest that albitite from the Xiaozhen copper deposit is igneous in origin. Further zircon trace element geochemistry studies indicate that these zircons have high Th/U ratios(0.5), low La content, high(Sm/La)N and Ce/Ce*values, and a strong negative Eu anomaly, which are commonly seen in magmatic zircons. The chondrite–normalized rare earth element(REE) patterns are consistent with magmatic zircons from throughout the world, and they fall within or near the field of magmatic zircons on discriminant diagrams. The calculated average apparent Ti–in–zircon temperature for young zircons is 780°C, consistent with magmatic zircon crystallization temperatures. Therefore, zircon geochemistry indicates that the albitite origin is magmatic. SIMS U–Pb dating on nine magmatic zircons yielded a concordia age of 154.8±2.2 Ma, which represents the formation of albitite and the metallogenic age. More importantly, it is consistent with the ages of Yanshanian magmatism and metallogenesis in the South Qinling orogen, so formation of the Xiaozhen copper deposit may be a closely related geological event. 相似文献
7.
The A-type Harsora-Dadikar granites in the Alwar complex of northern Aravalli orogen,NW India provide evidence for subsolidus-requilibration of feldspars.They record three new discrete stages of albitisation,producing trondhjemite and albitite sequentially at the expense of original granite.Stage-Ⅰ metasomatism deanorthised the magmatic oligoclase and transformed the grey least-albitised granite to pinkish grey microcline-oligoclase granite.Stage-II converted the latter to trondhjemite by replacement of microcline to oligoclase.Stage-Ⅲ metasomatism led to the formation of albitite/albite granite from trondhjemite,where the metasomatically formed oligoclase was replaced by albite.This stage of metasomatism resulted in nearly complete disappearance of amphibole and biotite,producing a monomineralic rock(albitite),which is consistent with Korzhinskii theory of infiltration metasomatism.The reaction fronts delineating the Stage-Ⅱ and Stage-Ⅲ are sharp and easily discernible by their prominent color differences in Harsora on the outcrop scale.Chemically,the mineral transformations during three stages are manifested by the differential gains/losses in Na,K,Ca,Rb,Ba,Sr,Fe and Mg.The formation of albite,Cl-rich marialitic scapolite and Cl-rich amphibole in the albitised granites are suggestive of Naand Cl-brines as the metasomatising fluids.The fluid-rock interactions,which can significantly transform the pristine mineralogy of granitoids,should be carefully considered to avoid any misinterpretations about their petrological history. 相似文献
8.
陕西双王钠长石岩特征及金矿床形成期次分析 总被引：5，自引：1，他引：4
双王含金钠长石岩带主要为层状 ,产于泥盆系星红铺组粉砂质板岩中。钠长石岩带主要由层状钠长石岩及钠长石岩角砾岩组成。角砾岩角砾主要为层状钠长石岩碎裂形成。层状钠长石岩及钠长石岩角砾韵律纹层构造及条带状构造发育 ,矿物组合和热水沉积钠长石岩相同。钠长石岩主元素及微量元素特征表明钠长石岩具热水沉积的一般特征。角砾岩角砾棱角明显 ,具可拼接破裂构造或典型角砾状构造 ;钠长石岩角砾和早期胶结物矿物组成基本相同。胶结充填物中晶洞构造发育 ,显示同生液压致裂角砾的一般特征。据钠长石岩沉积特征构造及角砾特征 ,认为钠长石岩及金矿床主要是热水沉积 -隐爆作用形成的 ,可分为 4个形成阶段 ,金矿矿化主要和第 3、4阶段有关。 相似文献
9.
敦煌地块钠长碎裂岩型金矿床的地质特征 总被引：1，自引：0，他引：1
敦煌地块东段前长城系敦煌群是该台块最古老的结晶基底，为一套绿岩建造。金矿床赋存于敦煌群顶部第四岩组火山岩和稍晚的基性斜长角门石岩被强烈钠交代而形成的钠长岩体内，并严格受控于脆－韧性剪切带。与金矿化有关的钠交代原岩有基性侵入岩、中酸性火山岩、花岗岩（可能有）等，但其最终交代产物均为钠长岩和石英脉组合，为一种特殊的金矿类型。 相似文献
10.
《China Geology》2019,2(4):422-438
The U-Th-REE-Nb (Ta)-polymetallic mineralization is generally related to either the silica-undersaturated syenites, the silica-oversaturated alkaline/peralkaline granites or igneous carbonatites. In this study, the authors report a new mineralization type, which is related to the magmatic-hydrothermal albitite (with mineral assemblage predominated by albite with volume content > 90%), as exemplified by the Chachaxiangka deposit in Qinghai Province of China. The Chachaxiangka deposit is the first albitite-related U-Th-REE-Nb deposit recognized in China and the mineralization can be divided into 3 types: the vein-type, the disseminated veinlet type and breccia type, of which the former 2 are predominant. Three mineralization stages can be identified according to the detailed mineralogical analyses, including the magmatic stage, main hydrothermal mineralization stage and post-ore stage. By comprehensive analyses of the mineralogical, major and trace element compositions, the authors suggest that the albitite vein is magmatic-hydrothermal in origin and both the magmatic evolution and overprint of the hydrothermal fluids play important roles in the formation of the albitite and related polymetallic mineralization. Phase separation between the silicate melt and carbonate/phosphate melt might take place in the magmatic stage, yet the immiscibility between the silicate melt and chloride-dominated fluids is the most important mechanism for the REE mineralization and also causes the Nb-Th re-mobilization and enrichment. The red color of the albitite aplite vein is an eye-catching prospecting mark in the field and more mineralization can be expected at depth and in the surrounding areas. The discovery of the new albitite type U-Th-REE-Nb mineralization give rise to new ideas during future U-Th-REE-Nb exploration, not only in the Qaidam-Altun belt, but also other areas across China. 相似文献