Predicting quantiles of water quality from catchment characteristics     

Danlu Guo  Shuci Liu  Dhananjay Singh  Andrew W. Western 《水文研究》2021,35(1):e13996

Water quality is often highly variable both in space and time, which poses challenges for modelling the more extreme concentrations. This study developed an alternative approach to predicting water quality quantiles at individual locations. We focused on river water quality data that were collected over 25 years, at 102 catchments across the State of Victoria, Australia. We analysed and modelled spatial patterns of the 10th, 25th, 50th, 75th and 90th percentiles of the concentrations of sediments, nutrients and salt, with six common constituents: total suspended solids (TSS), total phosphorus (TP), filterable reactive phosphorus (FRP), total Kjeldahl nitrogen (TKN), nitrate-nitrite (NO_x), and electrical conductivity (EC). To predict the spatial variation of each quantile for each constituent, we developed statistical regression models and exhaustively searched through 50 catchment characteristics to identify the best set of predictors for that quantile. The models predict the spatial variation in individual quantiles of TSS, TKN and EC well (66%–96% spatial variation explained), while those for TP, FRP and NO_x have lower performance (37%–73% spatial variation explained). The most common factors that influence the spatial variations of the different constituents and quantiles are: annual temperature, percentage of cropping land area in catchment and channel slope. The statistical models developed can be used to predict how low- and high-concentration quantiles change with landscape characteristics, and thus provide a useful tool for catchment managers to inform planning and policy making with changing climate and land use conditions.  相似文献   

A modified numerical model for moisture-salt transport in unsaturated sandy soil under evaporation     

Wei Wen  YuanMing Lai  ZheMin You 《寒旱区科学》2020,12(3):125-133

Soil salinization, caused by salt migration and accumulation underneath the soil surface, will corrode structures. To analyze the moisture-salt migration and salt precipitation in soil under evaporation conditions, a mathematical model consisting of a series of theoretical equations is briefly presented. The filling effect of precipitated salts on tortuosity factor and evaporation rate are taken into account in relevant equations. Besides, a transition equation to link the solute transport equation before and after salt precipitation is proposed. Meanwhile, a new relative humidity equation deduced from Pitzer ions model is used to modify the vapor transport flux equation. The results show that the calculated values are in good agreement with the published experimental data, especially for the simulation of volume water content and evaporation rate of Toyoura sand, which confirm the reliability and applicability of the proposed model.  相似文献   

平凉隐伏岩溶水环境同位素研究     

马致远  马蒂尔·亨德尔 《地球科学与环境学报》2003,25(4):60-66

地下水资源可持续利用的一个急待解决的重要问题,是对地下水补给和更新能力的评价.利用环境同位素技术研究地下水的补给和可更新性是当前较为新颖的方法之一.在西北干旱、半干旱的隐伏岩溶地区,地下水埋藏条件复杂,常规的地质勘探方法所能提供的水文地质信息有限,环境同位素方法在研究地下水的补给及可更新能力方面发挥了优势,可对传统方法进行补充和验证.其结果表明,研究区隐伏岩溶水形成较早,且有大量现代水的混入,平均混入量为54%.说明区内隐伏岩溶水的补给和更新能力较好.环境同位素分析结果还显示,大岔河隐伏岩溶水为一相对独立、半开放的水文地质单元,其补给来源部分为流域内大气降水、地表水的补给,部分为东南部三道沟岩溶地下水的补给;根据环境同位素EPM模型计算,地下水的滞留时间为36 a.地下水储存量为1.314×108 m3; 储水系数为7.29×10-3.这一结果与传统勘探方法的计算结果基本吻合,说明环境同位素方法的实用性.  相似文献   

新疆阿尔泰哈巴河一带古生代火山岩的形成与演化     

Zhang Chuanling 《地球科学与环境学报》1997,(1)

文中详细地论述了新疆阿尔泰哈巴河一带古生代火山岩的地质、岩石化学、稀土元素地球化学特征。将其分为三个类型，认为火山岩是在陆缘裂陷槽的区域构造背景下发生和演化的。对各类型火山岩岩浆来源，上升模式也做了初步讨论。  相似文献   

NaCl胁迫下杂交稻农艺性状配合力及遗传力分析     

方良俊 《广东海洋大学学报》2006,26(3):91-94

采用4×4不完全双列杂交设计,在NaCl胁迫下对杂交水稻主要农艺性状进行了配合力和遗传力分析.结果表明,在调查的10个性状中有4个性状受NaCl胁迫影响差异较大,母本的千粒重及父本的粒厚一般配力差异显著,杂交组合的株高、粒厚、结实率及千粒重特殊配合力差异极显著,其中杂交组合N28S×中花14具有较高的配合力,受NaCl胁迫影响较低。株高及千粒重的广义遗传力和狭义遗传力均较高,可作为杂交水稻耐盐性的选育依据。  相似文献   

西南极纳尔逊岛Stansbury半岛火山岩地质特征初论          下载免费PDF全文

郑祥身 《极地研究》1990,2(4):28-35

纳尔逊岛Stansbury半岛被玄武质、玄武安山质熔岩和火山碎屑岩以及沉积火山碎屑岩所覆盖。区域火山岩地层对比证明其是在形成长城站地区火山岩的同一火山作用下发育起来的。据地质接触关系和岩石组合特点,初步认为该半岛火山岩地层可以进一步划分为三个岩性段,分别形成于两期火山作用。该半岛的主要构造线方向平行于菲尔德斯海峡,这在地貌特征及次火山岩的分布上得到了证实。  相似文献   

Sources and sinks of sea salt in a newfoundland blanket bog     

Jonathan S. Price 《水文研究》1994,8(2):167-177

Over an oceanic peatland, the concentration of Na in fog averaged 38.1 mgl^?1 compared with 1.8 mgl^?1 in rain, resulting in a significant flux of mineral elements to the surface. Between 16 May and 20 June 1990 the average mass flux of Na to the bog surface by fog, rain, and dry deposition was 21.9, 10.4 and 7.0 mg m^?2 d^?1. There was little long-term storage of Na within the peatland system, where Na losses measured in stream runoff averaged 34.8 mg m² d^?1, and deep groundwater losses 4 mg m^?2 d^?1. Calcium and Mg were preferentially retained in the organic soil, whereas K was relatively mobile. Potassium tended to become concentrated in the unsaturated zone. Stream runoff had a consistently higher pH than groundwater, corresponding to higher Ca and Mg concentrations, which may have been from mineral sources in the headwater ponds. Otherwise, the stream water chemistry was closely related to groundwater in the upper layers of the peat deposit.  相似文献   

Observations on the ecological importance of salt marshes in the Cumberland Basin,a macrotidal estuary in the Bay of Fundy     

Donald C. Gordon  Peter J. Cranford  Con Desplanque 《Estuarine, Coastal and Shelf Science》1985,20(2):205-227

The Cumberland Basin, a 118 km² estuary at the head of the Bay of Fundy which has an average tidal range of about 11m, contains large tracts of salt marsh (15% of the area below highest high water). Low marsh (below about 0·9 m above mean high water) is composed almost exclusively of Spartina alterniflora while the vegetation on high marsh is more diverse but dominated by Spartina patens. Because of its higher elevation, high marsh is flooded infrequently for short periods by only extreme high tides. Low marsh is inundated much more frequently by water as much as 4m deep for periods as long as 4 h per tide. Temporal variability in the occurrence of extreme tides influences the flooding frequency of high marsh for any given month and year. Using a modification of Smalley's method, the mean annual net aerial primary production (NAPP) of low and high marsh is estimated to be 272 and 172 g C m^?2, respectively. Vegetation turnover times average 1·0 and 2·0 y for low and high marsh, respectively. Because of abundant tidal energy, much of the low marsh production appears to be exported and distributed widely about the estuary. Since high levels of turbidity suppress phytoplankton production, salt marshes produce approximately half of the carbon fixed photosynthetically in the Cumberland Basin. It is concluded that salt marshes play a major ecological role in the Cumberland Basin.  相似文献   

Arsenic incorporation in a salt marsh ecosystem     

James G. Sanders  Richard W. Osman 《Estuarine, Coastal and Shelf Science》1985,20(4):387-392

Replicate portions of a Delaware salt marsh were enclosed in cylindrical microcosms and exposed to elevated levels of inorganic arsenic (arsenate). All biotic and abiotic components in dosed cylinders rapidly incorporated arsenic. Spartina blades showed the greatest arsenic enrichment, with dosed plants incorporating arsenic concentrations an order of magnitude higher than controls. Spartina detritus and sediments also exhibited greatly elevated arsenic concentrations. Virtually all of the arsenic was incorporated into plant tissue or strongly sorbed to cell surfaces. Thus, elevated arsenic concentrations in estuarine waters will be reflected in living and non-living components of a salt marsh ecosystem, implying that increased arsenic will be available to organisms within the marsh ecosystem.  相似文献   

On salinity regimes and the vertical structure of residual flows in narrow tidal estuaries     

D. Prandle 《Estuarine, Coastal and Shelf Science》1985,20(5):615-635

An examination is made of the circulation in narrow estuaries subject to a predominant tidal forcing. Velocity structures are derived separately for residual flow components associated with (a) river flow, (b) wind stress, (c) a well-mixed longitudinal density gradient and (d) a fully stratified saline wedge. Dimensionless parameters are introduced to indicate the magnitude of each component and these parameters are evaluated for 9 major estuaries, thereby revealing their sensitivity to each component.For a channel of constant breadth and depth, formulae are deduced for the length of saline intrusion, L. Comparisons with observed data show that such formulae may be used with confidence to predict changes in L arising from variations in river flow, tidal range or channel depths.The level of stratification is shown to be related to a product of two parameters, one associated with velocity structure and a second involving the square of the ‘flow ratio’ $\text{u}\text{u}\text{?}$ (i.e. residual velocity/amplitude of the tidal velocity). This relationship provides a simple classification system for estuarine stratification which can be used to indicate the sensitivity of any particular estuary to changing conditions.  相似文献