Origin and evolution of alkali basaltic magma in the Okinawa Trough     

Zhang Jiaqiang  Sun Yongfu  Jiang Xiaoli 《海洋学报(英文版)》2000,19(3):115-129

I~IOXThe Okinawa Trough is an extending back--arc basin between the East China Sea Shelf andthe Ry'Ukyu Island Arc of Japan. There are widespreadly distributing acid pumice in the troughand a little basalt just in some area of the extending center. There have been some detailed rePOrtsabout the mineralogy and petrochemical feature of the subalkali tholeiite and alkali trachyte in thetrough (Zhai and Gan, 1995; Li et al., 1997; Qin and Zhai, 1988). This paper mainly reportselectron mic…  相似文献   

Petrological feature of spinel lherzolite xenolith from Oki-Dogo Island: An implication for variety of the upper mantle peridotite beneath southwestern Japan     

Natsue Abe  Masao Takami  Shoji Arai 《Island Arc》2003,12(2):219-232

Abstract   Spinel lherzolite is a minor component of the deep-seated xenolith suite in the Oki-Dogo alkaline basalts, whereas other types of ultramafic (e.g. pyroxenite and dunite) and mafic (e.g. granulite and gabbro) xenoliths are abundant. All spinel lherzolite xenoliths have spinel with a low Cr number (Cr#; < 0.26). They are anhydrous and are free of modal metasomatism. Their mineral assemblages and microtextures, combined with the high NiO content in olivine, suggest that they are of residual origin. But the Mg numbers of silicate minerals are lower (e.g. down to Fo₈₆) in some spinel lherzolites than in typical upper mantle residual peridotites. The clinopyroxene in the spinel lherzolite shows U-shaped chondrite-normalized rare-earth element (REE) patterns. The abundance of Fe-rich ultramafic and mafic cumulate xenoliths in Oki-Dogo alkali basalts suggests that the later formation of those Fe-rich cumulates from alkaline magma was the cause of Fe- and light REE (LREE)-enrichment in residual peridotite. The similar REE patterns are observed in spinel peridotite xenoliths from Kurose and also in those from the South-west Japan arc, which are non-metasomatized in terms of major-element chemistry (e.g. Fo > 89), and are rarely associated with Fe-rich cumulus mafic and ultramafic xenoliths. This indicates that the LREE-enrichment in mantle rocks has been more prominent and prevalent than Fe and other major-element enrichment during the metasomatism.  相似文献   

玄武岩深源岩石包体及金伯利岩中的尖晶石     

董振信 《岩石矿物学杂志》1996,15(3):241-249

我国东部新生代玄武岩中深源岩石包体内的尖晶石类矿物属铬尖晶石和铁尖晶石，金伯利岩及其地幔岩包体和金刚石中的尖晶石类矿物主要为铝铬铁矿。玄武岩中橄榄岩类包体内的尖晶石比其辉石岩类包体中的尖晶石含Ｃｒ高，含Ａｌ低，这与Ｃｒ为相容元素、Ａｌ为不相容元素、玄武岩中橄榄岩类包体是上地幔部分熔融出玄武岩浆后的残留物及其上地幔岩石的捕虏体、而辉石岩类是玄武岩浆结晶的产物有关。玄武岩中深源岩石包体中的尖晶石明显地比金伯利岩中的粗晶、地幔岩石包体及金刚石中的尖晶石含Ｃｒ低，含Ａｌ高，其主要原因是前者比后者形成的压力低  相似文献   

The influence of Cr on the garnet–spinel transition in the Earth''s mantle: experiments in the system MgO–Cr₂O₃–SiO₂ and thermodynamic modelling     

Stephan Klemme   《Lithos》2004,77(1-4):639-646

The position of the transition from spinel peridotite to garnet peridotite in a simplified chemical composition has been determined experimentally at high pressures and high temperatures. The univariant reaction MgCr₂O₄+2Mg₂Si₂O₆=Mg₃Cr₂Si₃O₁₂+Mg₂SiO₄, has a negative slope in P–T space between 1200 °C and 1600 °C. The experimental results, combined with assessed thermodynamic data for MgCr₂O₄, MgSiO₃ and Mg₂SiO₄ give the entropy and enthalpy of formation of knorringite garnet (Mg₃Cr₂Si₃O₁₂). Thermodynamic calculations in simplified chemical compositions indicate that Cr shifts the garnet-in reaction to much higher pressures than previously anticipated. Moreover, in Cr-bearing systems a pressure–temperature field exists where garnet and spinel coexist. The width of this divariant field strongly depends on the Cr/(Cr+Al) of the system.  相似文献   

Mineral chemistry of spinel peridotite xenoliths from Baengnyeong Island, South Korea, and its implications for the paleogeotherm of the uppermost mantle     

Sung Hi  Choi  Sung-Tack  Kwon 《Island Arc》2005,14(3):236-253

Abstract   The mantle-derived xenoliths entrained in the Pliocene basanite from Baengnyeong Island, South Korea, are spinel lherzolites and spinel harzburgites. The overall compositional range of the Baengnyeong xenoliths matches that of the post-Archean xenoliths of lithospheric mantle origin from eastern China, but without any compositional evidence for a refractory Archean mantle root. Mineral compositions of the xenoliths have been used to estimate the equilibrium temperatures and pressures, and to construct a paleogeothermal gradient of the source region. The xenolith-derived paleogeotherm is constrained from about 820°C at 7.3 kbar to 1000°C at 20.6 kbar. Like those from the post-Archean Chinese xenoliths of lithospheric mantle origin, the Baengnyeong geotherm is considerably elevated relative to the conductive models at the depth of the crust–mantle boundary, reflecting a thermal perturbation probably related to lithospheric thinning. There is no significant P / T difference between harzburgite and lherzolite, which suggests that the harzburgites are interlayered with lherzolites within the depth interval beneath Baengnyeong Island.  相似文献   

Atomistic simulation of Mg2SiO4 and Mg2GeO4 spinels: a new model     

M. Blanchard  K. Wright  J. D. Gale 《Physics and Chemistry of Minerals》2005,32(5-6):332-338

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上扬子会泽地区早三叠世飞仙关组砂岩物源特征:来自重矿物铬尖晶石和碎屑锆石的限定   总被引：1，自引：0，他引：1  

张英利  王宗起  王刚  李谦  林健飞 《地质论评》2016,62(1):54-72

上扬子会泽地区早三叠世飞仙关组主要为河流相的紫红色砂岩,物源主要来自于西部和西北部。碎屑重矿物组合表明物源主要来自于岩浆岩,且重矿物中发现大量碎屑铬尖晶石和锆石。本文运用电子探针微区成分分析和碎屑锆石U-Pb测年方法,对上扬子早三叠世飞仙关组砂岩中铬尖晶石和碎屑锆石进行分析。铬尖晶石电子探针化学成分分析显示,其具有高铬、低Fe~(3+)和高TiO_2含量的特征,源岩分析指示这些铬尖晶石来源于与洋岛/板内、岛弧以及大火成岩省相关的火成岩。同时,碎屑锆石LA-ICP-MS U-Pb年龄测定表明,飞仙关组的物源主要来自于248~272Ma和715~997Ma的岩浆岩。铬尖晶石和碎屑锆石综合分析表明,248~272Ma的物源岩石具有大火成岩省玄武岩特征,主要为峨眉山玄武岩及同期基性侵入岩;715~997M的物源为洋岛/板内玄武岩类,主要为研究区周缘与新元古代苏雄组及其同期的岩浆岩;铬尖晶石指示的岛弧性质物源则可能源自1000~1100Ma的岩浆岩。同时,碎屑锆石还指示古元古代和早寒武世发育岩浆作用,且存在古老的新太古代结晶基底。这些资料为上扬子地区构造演化提供了沉积学的证据。  相似文献   

Petrology and PGE Abundances of High‐Cr and High‐Al Podiform Chromitites and Peridotites from the Bulqiza Ultramafic Massif,Eastern Mirdita Ophiolite,Albania     

QIU Tian  YANG Jingsui  MILUSHI Ibrahim  WU Weiwei  MEKSHIQI Nezir  XIONG Fahui  ZHANG Cong  SHEN Tingting 《《地质学报》英文版》2018,92(3):1063-1081

The Bulqiza ultramafic massif, which is part of the eastern Mirdita ophiolite of northern Albania, is world renowned for its high-Cr chromitite deposits. High-Cr chromitites hosted in the mantle section are the crystallized products of boninitic melts in a supra-subduction zone (SSZ). However, economically important high-Al chromitites are also present in massive dunite of the mantle-crust transition zone (MTZ). Chromian-spinel in the high-Al chromitites and dunites of the MTZ have much lower Cr# values (100Cr/(Cr+Al)) (47.7–55.1 and 46.5–51.7, respectively) than those in the high-Cr chromitites (78.2–80.4), harzburgites (72.6–77.9) and mantle dunites (79.4–84.3). The chemical differences in these two types of chromitites are reflected in the behaviors of their platinum-group elements (PGE). The high-Cr chromitites are rich in IPGE relative to PPGE with 0.10–0.45 PPGE/IPGE ratios, whereas the high-Al chromitites have relatively higher PPGE/IPGE ratios between 1.20 and 7.80. The calculated melts in equilibrium with the high-Cr chromitites are boninitic-like, and those associated with the high-Al chromitites are MORB-like but with hydrous, oxidized and TiO2-poor features. We propose that the coexistence of both types of chromitites in the Bulqiza ultramafic massif may indicates a change in magma composition from MORB-like to boninitic-like in a proto-forearc setting during subduction initiation.  相似文献   

含部分晶须的钛酸锂的制备及其性能表征     

邓昭平  倪师军  李思平  夏新蕊  王鹏威 《矿物岩石》2006,26(4):98-100

L i4T i5O12是一种循环性能好、有很好的充放电平台、理论比容量较大、不与电解液反应的新型负极材料,研究探索以偏钛酸和碳酸锂为主要原料制备含部分晶须的尖晶石型晶型L i4T i5O12的一种方法。通过此工艺在1 000℃煅烧8 h后在样品中约20%的晶须出现,晶须的直径≤0.5μm,晶须的长度约为7μm。  相似文献   

第一原理计算过渡金属掺杂尖晶石型LiMn2O4的电子结构   总被引：1，自引：0，他引：1  

宁连才  吴金平  周成刚  姚淑娟  程寒松 《地球科学》2006,31(3):317-320

尽管对过渡金属掺杂锰酸锂后放电平台的升高现象有众多实验研究,但对其机理的研究却鲜见报道.采用第一原理的密度泛函理论,计算了过渡金属M(M=Ti、Cr、Fe、Co、Ni、Cu、Zn)掺杂尖晶石型LiMn2O4的电子结构,并以此分析放电平台的升高机理.电子态密度分析发现由于M-3d能带的诱导作用,出现了新的O-2p能带,而锂脱出时获得的电子,主要是由费米能级附近O-2p能带提供的.当过渡金属M由Ti变化到Zn时,M-3d能带逐渐向低能量的方向移动,新的O-2p能带出现的位置也随之下移,当Li脱出时,需要更多的能量才能从低能量的O-2p能带上获得电子,因而体系能够获得较高的嵌入电压.  相似文献