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In the Transangarian region of the Yenisey Ridge in eastern Siberia (Russia), Fe‐ and Al‐rich metapelitic schists of the Korda plate show field and petrological evidence of two superimposed metamorphic events. An early middle Proterozoic event with age of c.1100 Ma produced low‐pressure, andalusite‐bearing assemblages at c. 3.5–4 kbar and 540–560 °C. During a subsequent late Proterozoic event at c. 850 Ma, a medium‐pressure, regional metamorphic overprint produced kyanite‐bearing mineral assemblages that replaced minerals formed in the low‐pressure event. Based on the results of geothermobarometry and PT path calculations it can be shown that pressure increased from 4.5 to 6.7 kbar at a relatively constant temperature of 540–600 °C towards a major suture zone called the Panimba thrust. In order to produce such nearly isothermal loading of 1–7 °C km ?1, we propose a model for the tectono‐metamorphic evolution of the study area based on crustal thickening caused by south‐westward thrusting of the 5–7 km‐thick upper‐plate metacarbonates over lower‐plate metapelites with velocity of c. 350 m Myr?1. A small temperature increase (up to 20 ± 15 °C) of the upper part of the overlapped plate is explained by specific behaviour of steady‐state geotherms calculated using lower radioactive heat production of metacarbonates as compared with metapelites. The suggested thermal‐mechanical model corresponds well with PT paths inferred from obtained thermobarometric data and correlates satisfactorily with PT trajectories predicted by other two‐dimensional thermal models for different crustal thickening and exhumation histories.  相似文献   
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采用基于密度泛函理论的第一性原理计算方法,对掺Fe和(或)Cd的闪锌矿型Zn S的电子结构进行了计算。计算结果表明,纯闪锌矿的禁带宽度为2.85 e V;掺Fe浓度为3.125%的闪锌矿禁带宽度为2.58 e V,且Fe的3d和S的3p轨道杂化在禁带中引入了两条杂质能级;随着掺Fe量的增加,杂质能级的宽度和峰高也随之增大;掺Cd闪锌矿的禁带宽度为2.68 e V,并在下价带底引入一条杂质能级;Fe/Cd共掺杂的闪锌矿禁带宽度为2.49 e V,在禁带中出现的两条施主杂质能级可提高闪锌矿的可见光响应及催化能力。计算结果为深入探讨天然闪锌矿的可见光催化机制提供了理论支持。  相似文献   
3.
青海东昆仑肯德可克铁钴多金属矿床特征   总被引:4,自引:0,他引:4  
青海东昆仑肯德可克铁钴多金属矿床位于柴达木盆地西南缘,祁漫塔格弧后裂陷带中部.矿体产于上奥陶统热水喷流沉积的炭泥钙铁硅质岩建造中,地层与构造控矿作用明显.印支-燕山期脉岩比较发育,近矿围岩蚀变组合复杂、分带不明显,说明有多期热液活动参与了成矿.因此,肯德可克铁钴多金属矿床属热水喷流沉积(改造)型矿床,形成铅锌-钴铋金-铁成矿系列.  相似文献   
4.
黑柱石是一种矽卡岩型铅锌及铁矿床中少见的矿物,与铅锌矿体、磁铁矿体关系密切。为查明黑柱石成矿过程中与铅锌铁铜多金属成矿作用的关系,本文对金厂河Fe- Cu- Pb- Zn多金属矿床中的黑柱石产状、矿物共生组合、化学成分、分带性等开展了研究。根据电子探针数据计算可得,金厂河矿区黑柱石的化学式为:Ca0. 95- 1. 08(Fe0. 87- 1. 97Mn0. 08- 0. 36Mg0. 01- 0. 06)2+(1. 89- 2. 03)(Fe0. 82- 1. 04Al0. 01- 0. 03)3+(0. 88- 1. 15)\[Si1. 94- 2. 08O7\]O(OH)。结合矿物组合类型、产状、分带特征等,推测矿床内矽卡岩由内带逐渐向外带交代的趋势。金厂河矿区主要有3种矿物共生组合:黑柱石+磁铁矿组合,黑柱石+磁铁矿+黄铁矿+黄铜矿组合,黑柱石+方铅矿+闪锌矿+黄铜矿组合,分别对应三个不同的蚀变阶段:晚期矽卡岩阶段(代表组合I),以石榴子石的分解为主,形成大量的黑柱石;退蚀变阶段(代表组合II),以阳起石、黄铜矿、黄铁矿发育为主;石英- 硫化物阶段(代表组合III),以发育大量的方铅矿、闪锌矿为主,同时这一阶段内黑柱石分解,形成阳起石、方解石、磁铁矿等。此外,黑柱石的稀土元素配分模式与石榴子石的类似,一定程度上保留了石榴子石的稀土元素特征。研究认为:黑柱石是早期石榴子石退化分解的产物,矿床自内向外逐渐交代,形成了铅锌铜矿体中以锰质黑柱石为主,而磁铁矿体、铜矿体中以含锰黑柱石为主的分带特性。锰质黑柱石有利于铅锌矿的形成,而对于磁铁矿有贫化的影响,同时也可为矿区揭露中酸性岩体和深部找矿提供重要科学意义。  相似文献   
5.
Four polymetamorphic complexes in the vicinity of regional faults in the Trans-Angarian region of the Yenisey Ridge were studied to determine their metamorphic evolution and to elucidate distinctive features of the regional geodynamic processes. Based on our geological and petrological studies using geothermobarometry and P–T path calculations, we show that a Neoproterozoic medium-pressure metamorphism of the kyanite-sillimanite type at c. 850 Ma overprinted regionally metamorphosed low-pressure andalusite-bearing rocks. A positive correlation between rock ages and P–T estimates for the kyanite-sillimanite metamorphism provides evidence for regional structural and tectonic heterogeneity. The medium-pressure recrystallization was characterized by (1) localized distribution of metamorphic zones in the area directly underlying thrust faults with a measured thickness of 2.5–8 km; (2) syntectonic formation of kyanite-bearing mineral assemblages related to thrusting; (3) gradual increase in metamorphic pressure towards the thrust faults associated with a low metamorphic field gradient (from 1–7 to 12°C/km); and (4) equally steep burial P–T paths recorded for the highest grade rocks. These specific features are typical of collisional metamorphism during overthrusting of continental blocks and are evidence of near-isothermal loading in accordance with the transient emplacement of thrust sheets. The proposed model for tectono-metamorphic evolution of the study areas due to crustal thickening at high thrusting rates and subsequent rapid exhumation explains these tectonic features. Data analysis allowed us to consider the medium-pressure kyanite-bearing metapelites as a product of collisional metamorphism, reflecting unidirectional thrusting of Siberian cratonal blocks onto Yenisey Ridge along regional deep faults (Angara, Mayakon, and Chapa areas) and by opposite movements in the zone of secondary splay faults (Garevka area).  相似文献   
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