A numerical investigation of the destruction of peroxy radical by Cu ion catalysed reactions on atmospheric particles     

Howard B. Ross  Kevin J. Noone 《Journal of Atmospheric Chemistry》1991,12(2):121-136

To determine if Cu mediated reactions on atmospheric particles are important to HO₂ chemistry in the ambient atmosphere, Cu molalities were calculated from measured Cu aerosol particle concentrations, mass and number size distribution data from a site in central Sweden. A comparison of characteristic times indicates that at low relative humidities the reaction is limited by the mass transport of gas phase HO₂ to the particle surface and not by the chemical kinetics of the aqueous reaction. Comparison of half-lives for particle reactions and the gas phase destruction of HO₂ to form H₂O₂ indicate that heterogeneous reactions on aerosol particles may have important consequences on the chemistry of HO₂ and H₂O₂ in the troposphere.  相似文献   

SO4^2-改性铁铝复合层柱粘土的制备及其催化性能研究     

于少明  郝文正  翟林峰  陆亚玲  陈天虎  史铁钧 《矿物学报》2008,28(3)

由共聚法制得的铁铝复合交联剂交换钠基蒙脱石层间的水合钠离子,再经SO42-改性处理制备了铁铝复合层柱粘土固体超强酸催化剂.利用xRD、FT-IR和BET法对催化剂的结构进行了表征.以乙酸正丁酯的合成反应为探针反应对催化剂的活性进行了测试.通过正交实验确定了铁铝复合交联粘土SO42-改性最佳工艺条件.研究了催化剂对探针反应的选择性及重复使用情况.结果表明:在由实验确定的最佳改性工艺条件下,乙酸的转化率达92.2%,反应中无副产物产生,催化剂具有较好的重复使用性能.  相似文献   

关于多项式特征值的条件数     

刘新国  王学锋 《中国海洋大学学报(自然科学版)》2004,34(5):913-917

Tisseur(2000)研究了非齐次多项式特征值问题的条件数，所得结果的不足是对无穷特征值必须另外处理；Declieu和Tisseur(2003)运用微分几何方法研究了齐次多项式特征值问题的条件数，所得结果的不足之处是与系数矩阵的尺度化(scaling)有关。这两种条件数都有各自的应用范围。本文基于投影尺度引入齐次多项式特征值问题的条件数，其优点是与系数矩阵的尺度化无关，因而也许会有较广泛的应用。  相似文献   

Hydrometallurgical processing and recovery of molybdenum trioxide from spent catalyst   总被引：5，自引：0，他引：5  

Kyung Ho Park  B. Ramachandra Reddy  D. Mohapatra  Chul-Woo Nam 《International Journal of Mineral Processing》2006,80(2-4):261-265

Hydrometallurgical processing of spent hydrodesulphurisation (HDS) catalyst for the recovery of molybdenum using sodium carbonate and hydrogen peroxide mixtures was investigated. The results indicated that the recovery of molybdenum was largely dependent on the concentrations of Na₂CO₃ and H₂O₂ in the reaction medium, which controls the acidity of the leach liquor and carry over of impurities such as Al, Ni, P, Si and V. Leaching process was exothermic and leaching efficiency of molybdenum decreased with increasing solid to liquid ratio. Large scale leaching of spent catalyst, under optimum conditions: 20% pulp density, 85 g/L Na₂CO₃, 10 vol.% H₂O₂ and 1 h reaction, resulted a leaching efficiency of 84% Mo. The obtained leach liquor contained (g/L): Mo — 22.0, Ni — 0.015 and Al — 0.82, P — 1.1, Si — 0.094 and minor quantities of V — 8 mg/L, As and Co — < 1 mg/L. Recovery of Mo from leach solution as MoO₃ of 97.30% purity was achieved by ammonium molybdate precipitation method.  相似文献   

降水性层状云的微物理特征及人工增雨催化条件的研究   总被引：17，自引：2，他引：17       下载免费PDF全文

张连云  冯桂利 《气象》1997,23(5):3-7

根据２７架次粒子测量系统的探测资料，综合分析了影响山东春，秋季降水云系的微特征，计算了探测层以上云中积分含水量，并依据综合分析结果对山东春，秋季降水性层状云的人工引晶剂量进行了探讨。  相似文献   

对羟基苯甲酸异丙酯合成的研究     

谢宗波姜国芳  张玉玲吴志清 《华东地质学院学报》2005,28(1):91-92

以浓硫酸为催化剂，研究了对羟基苯甲酸和异丙醇合成对羟基苯甲酸异丙酯的工艺条件。对影响产率的因素进行了探讨：实验表明，在以7％的浓硫酸为催化剂，反应温度为120℃，醇酸摩尔比为4：1，反应时间为5h的最佳条件下，合成了羟基苯甲酸异丙脂，通过多次重结晶的方法纯化产品，产率可达85．5％，并通过熔点仪、红外光谱等手段对产品加以表征，验证了产品具有较高的纯度。该法简单、快速、产率高、纯度好，具有较高的实用价值。  相似文献   

The use of the exponent K(q) function to delimit homogeneous regions in regional frequency analysis of extreme annual daily rainfall          下载免费PDF全文

A. P. García‐Marín  J. Estévez  C. Sangüesa‐Pool  R. Pizarro‐Tapia  J. L. Ayuso‐Muñoz  F. J. Jimenez‐Hornero 《水文研究》2015,29(1):139-151

The regional frequency analysis of extreme annual rainfall data is a useful methodology in hydrology to obtain certain quantile values when no long data series are available. The most crucial step in the analysis is the grouping of sites into homogeneous regions. This work presents a new grouping criterion based on some multifractal properties of rainfall data. For this purpose, a regional frequency analysis of extreme annual rainfall data from the Maule Region (Chile) has been performed. Daily rainfall data series of 53 available stations have been studied, and their empirical moments scaling exponent functions K(q) have been obtained. Two characteristics parameters of the K(q) functions (γ_max and K(0)) have been used to group the stations into three homogeneous regions. Only five sites have not been possible to include into any homogenous regions, being the local frequency analysis of extreme daily rainfall the most appropriate method to be used at these locations. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

海河流域近60 a降水极值的频率分析及时空分布特征          下载免费PDF全文

邵月红  刘玲  刘俊杰  吴俊梅 《大气科学学报》2020,43(2):381-391

以海河流域为研究区域,利用MK和F检验对站点的年最大日降雨序列进行趋势、突变和跳跃分析。基于水文气象分区线性矩法进行一致区的划分、最优分布的选择和降水极值的频率估计值计算,并分析其空间分布特征。结果表明:MK趋势和突变检验显示只有8个站点(22.9%)呈现显著下降趋势,通过了信度为0.1的显著性水平检验,特别是京津唐区域具有显著的下降趋势,突变时段主要发生在1980-1990年。均值和方差的跳跃性显示大部分站点都呈现出显著的向下跳跃,主要分布在流域的滦河子流域和北三河水系;趋势和跳跃的综合分析能够对降水极值有可能引起的旱涝灾害进行更全面合理的判断。不同重现期下的频率估计值的空间分布总体趋势一致,从东南到西北、从沿海到内陆逐渐减少,并与地形表现出很好的一致性;降水极值空间分布的中心主要集中在滦河子流域的遵化和青龙附近;大部分站点50 a一遇的估计值和AMP序列的最大观测值能够保持较好的一致性,间接反映了估计值的合理准确性。  相似文献   

Variability of Convective Activity over the North Indian Ocean and its Associations with Monsoon Rainfall over India     

D. R. Pattanaik 《Pure and Applied Geophysics》2007,164(8-9):1527-1545

The present study is an attempt to examine the variability of convective activity over the north Indian Ocean (Bay of Bengal and Arabian Sea) on interannual and longer time scale and its association with the rainfall activity over the four different homogeneous regions of India (viz., northeast India, northwest India, central India and south peninsular India) during the monsoon season from June to September (JJAS) for the 26 year period (1979 to 2004). The monthly mean Outgoing Long-wave Radiation (OLR) data obtained from National Oceanic and Atmospheric Administration (NOAA) polar orbiting spacecraft are used in this study and the 26-year period has been divided into two periods of 13 years each with period-i from 1979 to 1991 and period -ii from 1992 to 2004. It is ascertained that the convective activity increases over the Arabian Sea and the Bay of Bengal in the recent period (period -ii; 1992 to 2004) compared to that of the former period (period -i; 1979 to 1991) during JJAS and is associated with a significantly increasing trend (at 95% level) of convective activity over the north Bay of Bengal (NBAY). On a monthly scale, July and August also show increase in convective activity over the Arabian Sea and the Bay of Bengal during the recent period and this is associated with slight changes in the monsoon activity cycle over India. The increase in convective activity particularly over the Arabian Sea during the recent period of June is basically associated with about three days early onset of the monsoon over Delhi and relatively faster progress of the monsoon northward from the southern tip of India. Over the homogeneous regions of India the correlation coefficient (CC) of OLR anomalies over the south Arabian Sea (SARA) is highly significant with the rainfall over central India, south peninsular India and northwest India, and for the north Arabian Sea (NARA), it is significant with northwest India rainfall and south peninsular rainfall. Similarly, the OLR anomalies over the south Bay of Bengal (SBAY) have significant CC with northwest India and south peninsular rainfall, whereas the most active convective region of the NBAY is not significantly correlated with rainfall over India. It is also found that the region over northeastern parts of India and its surroundings has a negative correlation with the OLR anomalies over the NARA and is associated with an anomalous sinking (rising) motion over the northeastern parts of India during the years of increase (decrease) of convective activity over the NARA.  相似文献   

偶极子流在台风异常路径形成中的作用     

马镜娴  马奋华  王咏青 《南京气象学院学报》2001,24(3):338-342

应用NCEP／NCAR再分析资料，分析了9408号台风异常路径形成的可能原因。结果表明，环境引导流、准均匀流和偶极子流的共同作用对移向突变和移速突变有着重要影响。  相似文献