The transition from peraluminous to peralkaline granitic melts: Evidence from melt inclusions and accessory minerals     

R. Thomas  J.D. Webster  D. Rhede  W. Seifert  K. Rickers  H.-J. Frster  W. Heinrich  P. Davidson 《Lithos》2006,91(1-4):137-149

Fractional crystallization of peraluminous F- and H₂O-rich granite magmas progressively enriches the remaining melt with volatiles. We show that, at saturation, the melt may separate into two immiscible conjugate melt fractions, one of the fractions shows increasing peraluminosity and the other increasing peralkalinity. These melt fractions also fractionate the incompatible elements to significantly different degrees. Coexisting melt fractions have differing chemical and physical properties and, due to their high density and viscosity contrasts, they will tend to separate readily from each other. Once separated, each melt fraction evolves independently in response to changing T/P/X conditions and further immiscibility events may occur, each generating its own conjugate pair of melt fractions. The strongly peralkaline melt fractions in particular are very reactive and commonly react until equilibrium is attained. Consequently, the peralkaline melt fraction is commonly preserved only in the isolated melt and mineral inclusions.

We demonstrate that the differences between melt fractions that can be seen most clearly in differing melt inclusion compositions are also visible in the composition of the resulting ore-forming and accessory minerals, and are visible on scales from a few micrometers to hundreds of meters.  相似文献   

铝硅酸盐熔体微结构单元的探讨     

蒋国昌吴永全  尤静林侯怀宇 陈辉 《岩石学报》2004,20(3):753-758

本文是一篇综述，讨论在熔融铝硅酸盐和铝酸盐中Al的两性行为。这是7台金学和岩石学中一个至今尚无可靠结论的问题。作者认为：每个四配位的Ala都含一个配位键，例如Al—O(^Ca Si)或Al—O(^Ca Al)。相应的非桥氧Onb并没有消失，而是变成了三价氧离子。碱性Alb能否出现取决于该体系的酸碱平衡。构筑硅酸盐的键合结构模型时，作者建议用5种Si-O四面体(Qn)作为微结构单元。即，用它们的相对量和微观化学位描述其宏观物性(如组元活度)。为了沟通铝硅酸盐的微观结构与宏观物性，仍可用5种Qn作为微结构单元。其中所含Ala的影响用各种Qn微观化学位的相应变化来反映。对于铝酸盐，建议用Ala-O四面体(Tn)作为微结构单元。  相似文献   

Conditions of pocket formation in the Oktyabrskaya tourmaline-rich gem pegmatite (the Malkhan field, Central Transbaikalia, Russia)     

Igor S. Peretyazhko  Victor Ye. Zagorsky  Sergey Z. Smirnov  Mikhail Y. Mikhailov 《Chemical Geology》2004,210(1-4):91-111

Coexisting melt (MI), fluid-melt (FMI) and fluid (FI) inclusions in quartz from the Oktaybrskaya pegmatite, central Transbaikalia, have been studied and the thermodynamic modeling of PVTX-properties of aqueous orthoboric-acid fluids has been carried out to define the conditions of pocket formation. At room temperature, FMI in early pocket quartz and in quartz from the coarse-grained quartz–oligoclase host pegmatite contain crystalline aggregates and an orthoboric-acid fluid. The portion of FMI in inclusion assemblages decreases and the volume of fluid in inclusions increases from the early to the late growth zones in the pocket quartz. No FMI have been found in the late growth zones. Significant variations of solid/fluid ratios in the neighboring FMI result from heterogeneous entrapment of coexisting melts and fluids by a host mineral. Raman spectroscopy, SEM EDS and EMPA indicate that the crystalline aggregates in FMI are dominated by mica minerals of the boron-rich muscovite–nanpingite CsAl₂[AlSi₃O₁₀](OH,F)₂ series as well as lepidolite. Topaz, quartz, potassium feldspar and several unidentified minerals occur in much lower amounts. Fluid isolations in FMI and FI have similar total salinity (4–8 wt.% NaCl eq.) and H₃BO₃ contents (12–16 wt.%). The melt inclusions in host-pegmatite quartz homogenize at 570–600 °C. The silicate crystalline aggregates in large inclusions in pocket quartz completely melt at 615 °C. However, even after those inclusions were significantly overheated at 650±10 °C and 2.5 kbar during 24 h they remained non-homogeneous and displayed two types: (i) glass+unmelted crystals and (ii) fluid+glass. The FMI glasses contain 1.94–2.73 wt.% F, 2.51 wt.% B₂O₃, 3.64–5.20 wt.% Cs₂O, 0.54 wt.% Li₂O, 0.57 wt.% Ta₂O₅, 0.10 wt.% Nb₂O₅, 0.12 wt.% BeO. The H₂O content of the glass could exceed 12 wt.%. Such compositions suggest that the residual melts of the latest magmatic stage were strongly enriched in H₂O, B, F, Cs and contained elevated concentrations of Li, Be, Ta, and Nb. FMI microthermometry showed that those melts could have crystallized at 615–550 °C.

Crystallization of quartz–feldspar pegmatite matrix leads to the formation of H₂O-, B- and F-enriched residual melts and associated fluids (prototypes of pockets). Fluids of different compositions and residual melts of different liquidus–solidus P–T-conditions would form pockets with various internal fluid pressures. During crystallization, those melts release more aqueous fluids resulting in a further increase of the fluid pressure in pockets. A significant overpressure and a possible pressure gradient between the neighboring pockets would induce fracturing of pockets and “fluid explosions”. The fracturing commonly results in the crushing of pocket walls, formation of new fractures connecting adjacent pockets, heterogenization and mixing of pocket fluids. Such newly formed fluids would interact with a primary pegmatite matrix along the fractures and cause autometasomatic alteration, recrystallization, leaching and formation of “primary–secondary” pockets.  相似文献   

The structural role of Ti in aluminosilicate liquids in the glass transition range: insights from heat capacity and shear viscosity measurements     

Mathieu Roskosz  M.J Toplis 《Geochimica et cosmochimica acta》2004,68(3):591-606

The shear viscosities and 1 bar heat capacities of glasses and melts along the 67mol% silica isopleth in the system SiO₂-Al₂O₃-Na₂O-TiO₂ have been determined in the temperature ranges 780-1140 K and 305-1090 K respectively. Anomalous behaviour of both these properties is observed for compositions rich in TiO₂ and/or Al₂O₃, an observation attributed to liquid-liquid phase separation followed by anatase crystallization. For samples which do not show anomalous behaviour, it is found that the partial molar heat capacity of the TiO₂ component previously determined in Al-free compositions reproduces our heat capacities to within 1.3%. Viscosity data show that addition of TiO₂ tends to increase viscosity and melt fragility at constant temperature. Furthermore, heat capacity and viscosity data may be combined within the framework of the Adam-Gibbs theory to extract values of the configurational entropy of the liquids and qualitative estimates of the variation of the average energy barrier to viscous flow. Configurational entropy at 900K is inferred to decrease upon addition of TiO₂, in contrast to previous results from Al-free systems. The compositional limit separating normal from anomalous behaviour, as well as the data for homogenous melts have been used to constrain the structural role of Ti in these samples. Our data are consistent with a majority of Ti in five-fold coordination associated with a titanyl bond, in agreement with previous spectroscopic studies. Furthermore, we find no evidence for a Ti-Al interaction in our samples, and we are led to the conclusion that Al and Ti are incompletely mixed, a hypothesis consistent with the observed reduction of configurational entropy upon addition of TiO₂, suggesting an important role of medium range order in controlling the variations in thermodynamic properties.  相似文献   

Shear wave velocity, seismic attenuation, and thermal structure of the continental upper mantle   总被引：3，自引：0，他引：3  

Irina M. Artemieva  Magali Billien  Jean-Jacques Lévêque  Walter D. Mooney 《Geophysical Journal International》2004,157(2):607-628

  相似文献   

富铌玄武岩：板片熔体交代的地幔楔橄榄岩部分熔融产物   总被引：4，自引：0，他引：4  

张海祥  张伯友  牛贺才 《地球科学进展》2005,20(11):1234-1242

富铌玄武岩是一类具有特殊地球化学特征的岛弧玄武岩。与正常岛弧玄武岩相比，它具有硅饱和并富钠的特征；同时具有相对高的Nb（一般>7×10-6）、TiO2（1%～2%）和P含量，以及低的LILE/HFSE和HREE/HFSE比值，并富集高场强元素；它的原始地幔标准化微量元素图显示了弱的Nb、Ta负异常（有时出现弱的正异常），原始地幔标准化La/Nb比值小于2（但很少小于0.7），它是由受埃达克质熔体交代过的地幔橄榄岩部分熔融形成的。由于富铌玄武岩与埃达克岩是大洋板片俯冲作用的直接产物，因此，通过对该岩石组合及与俯冲作用有关的流体和熔体的研究，不仅可以查明洋壳俯冲作用过程中的岩浆活动特征，还可以阐明洋壳俯冲及壳幔相互作用，具十分重要的地质意义。  相似文献   

不同大尺度强迫条件下考虑初始场与侧边界条件不确定性的对流尺度集合预报试验   总被引：5，自引：0，他引：5  

庄潇然  闵锦忠  蔡沅辰  朱浩楠 《气象学报》2016,74(2):244-258

研究了不同大尺度强迫条件下的暴雨个例中,考虑不同尺度特征的初始扰动与侧边界扰动相互作用构造对流尺度集合预报的可行性,为进一步构建“自适应”于不同强对流天气的对流尺度集合预报系统提供依据。结果表明,在大尺度强迫显著的个例1中,以大尺度扰动信息为主的动力降尺度的增长趋势较集合转换卡尔曼滤波(ETKF)更为显著,且总扰动能量在预报中后期超过集合转换卡尔曼滤波,而在大尺度强迫较弱的个例2中,集合转换卡尔曼滤波扰动能量始终高于动力降尺度。此外,当大尺度强迫显著时,初始扰动与侧边界扰动相匹配会产生相互促进的作用,而不匹配时初始扰动会在预报中后期抑制侧边界扰动的发展,当大尺度强迫较弱时,即使是互相间不匹配的初始扰动与侧边界扰动也能在大部分预报时段起到相互促进的作用,说明初始扰动与侧边界扰动的相互作用机制不仅与天气形势相关,也与二者是否匹配挂钩,另外,扰动的发展特征同样依赖于天气形势;从集合离散度的角度来看,当大尺度强迫明显时,侧边界扰动的作用会在更短的时间内取代初始扰动,从而对离散度起到主导地位;两种初始扰动方法相比,集合转换卡尔曼滤波在多数情况下对总离散度的贡献均大于动力降尺度;从降水量预报及概率预报情况来看,大尺度强迫明显的个例可预报性更高,且各集合成员间的差异较小,大尺度强迫较弱的个例则相反,且当两种初始扰动方案与侧边界扰动相结合时,较仅侧边界扰动均有一定提高。   相似文献   

Rock associations and their spatial-Temporal variations of the early mesozoic igneous rocks in the NE Asia: Constraints on the initial subduction timing of the paleo-pacific plate北大核心CSCD     

Tang J.Xu W.-L.Wang F. 《矿物岩石地球化学通报》2016,(6):1181-1194

This paper summarizes rook associations and spatial-Temporal variations of the early Mesozoic igneous rocks in the NE Asia, with the aim of revealing the initial subduction timing of the Paleo-Pacific Plate beneath the Eurasia, and the relationships between the early Mesozoic magmatisms and the Paleo-Asian tectonic system, Mongol-Okhotsk tectonic system, and amalgamation of the Yangtze and North China cratons. Dating results indicate that the early Mesozoic magmatisms in the NE Asia can be subdivided into three stages, i.e., Early-Middle Triassic, Late Triassic, and Early Jurassic. The early Mesozoic calc-Alkaline magmatisms within the Erguna Massif reveal southward subduction of the Mongol-Okhotsk oceanic plate. The Triassic alkaline and bimodal magmatisms within the northern margin of the North China Craton indicate an extensional environment related to the final closure of the Paleo-Asian Ocean. The Late Triassic A-Type rhyo- lites and bimodal magmatisms, together with the Late Triassic stable sedimentary rocks, in eastern Heilongjiang-Jilin provinces, reveal an extensional environment and passive continental margin setting, whereas the Early Jurassic calc-Alkaline magmatisms and its compositional variations, together with the coeval accretionary complex, reveal the onset of the Paleo- Pacific plate beneath the Euirasian continent.  相似文献   

Effects of initial step height on the headcut erosion of bank gullies: a case study using a 3D photo-reconstruction method in the dry-hot valley region of southwest China   总被引：1，自引：0，他引：1  

Baojun Zhang  Zhengan Su  Dan Yang  Yifan Dong  Liang Xiao 《自然地理学》2016,37(6):409-429

Abstract

Headcut erosion has been recognized as one of the main processes involved in gully development in the dry-hot valley region of southwest China. To examine the effect of initial step height on headcut erosion processes, three headcuts were constructed ranging in height from 0.75 to 1.25 m on an active bank gully head, and a series of scouring experiments were conducted under a flow discharge of 120 L min^?1. The morphological evolutions of the plunge pools and soil loss volume were estimated by three-dimensional photo-reconstruction methods (3D-PR). As the step height increased, the experimental results showed that: (1) the transformed potential energy and shear stress would increase by approximately 4.89 J s^?1 and 26.4 Pa on average when the step height increased 0.25 m; (2) the mean depth and width of the plunge pool exhibited obvious growth, and the morphology of the cross-section developed from approximately V-shaped to U-shaped; and (3) soil loss volume increased logarithmically, with total soil loss volumes of 0.076, 0.105 and 0.116 m³, respectively. Although the significant effects of the initial step height on headcut erosion were verified, further quantitative studies are required to quantify the mechanism of headcut erosion, especially for plunge pool erosion.  相似文献   

Zircon U–Pb–Hf isotopes and geochemistry analyses of the Huyu igneous rocks in northwestern Beijing,China: possible new evidence for the initial destruction of the North China Craton     

Zejia Ji  Baofu Han  Haifei Yu  Yan Chen 《International Geology Review》2018,60(2):196-216

The timing and extent of cratonic destruction are crucial to understanding the crustal evolution of the North China Craton (NCC). Zircon U–Pb–Hf isotope data and the whole-rock major and trace element characteristics of the Huyu igneous rocks in northwestern Beijing, China, provide possible new evidence for the initial destruction of the NCC. The igneous rocks occur as several sills and dikes, including lamprophyre, monzonite porphyry, and aplite. The lamprophyres have high Mg^# and K₂O contents. The monzonite porphyries have high Mg^#, high K₂O contents, and negative ε_Hf(t) values with zircon U–Pb ages of 225.5–227.7 Ma. These two types of rocks are both enriched in large ion lithosphere elements (LILEs) and light rare earth elements (LREEs) but are depleted in high field strength elements (HFSEs) and high rare earth elements (HREEs) and have almost no Eu anomalies and relatively high total rare earth element (ΣREE) contents. In contrast, the aplites exhibit high silica and K₂O contents, low MgO contents, and more negative ε_Hf(t) values with a zircon U–Pb age of 206.2 Ma. The aplites are also enriched in LILEs and LREEs but are depleted in HFSEs and HREEs, with strongly negative Eu, Ti, P, La, Ce, and Sr anomalies and relatively low ΣREE contents. These results indicate that the lamprophyres and monzonite porphyries represent a continuous cogenetic magma evolution series after melt derived from an enriched metasomatized lithospheric mantle experienced crust assimilation and fractional crystallization. The aplites were produced by the fractional crystallization of low-Mg parental magma derived from melting of the ancient Archaean crust. The occurrence of the Huyu intrusive rocks with many other plutons of similar ages on the northern margin of the NCC suggests that the northern NCC entered an intraplate extensional tectonic environment in the Late Triassic.  相似文献