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1.
Study of Sorptional Properties of the Cation Exchanger KB-2M with Macroreticular Structure for Recovery of Zinc Ions from Sewage and Rinsing Water Although a number of ion-exchange methods have been employed for the recovery of some transition metals from industrial effluents, knowledge about ion-exchange resins with macroreticular structure is poor. The present paper describes the mechanism of sorption on such exchangers and their application for recovery of zinc from sewage rinsing water. Ion exchanger of macroreticular structure are polymers with long-chained cross-linking agents. We have synthesized carboxylic ion-exchange resins by hydrolysis of copolymerisates of methyl acrylate with different cross-linking agents: divinylbenzene, divinyl sulfide, divinyl ester of ethylene glycol and divinyl ester of di- or triethylene glycol. The sorption process on modifications of the carboxylic resins KB-2 of various structure was studied with different methods: potentiometric titration, infrared spectroscopy, electron microscopy, X-ray structural analysis. The initial zinc concentration in rinsing water was 0.05 mol/L at pH from 3 to 6. For the sorption, 0.2…1.0 g of resin were equilibrated with 100 mL of zinc solution. After equilibrium (12 h), the resin was separated from solution. The zinc ions were determined by atomic absorption spectrometry after stripping with 100 mL of 10% sulfuric acid. The distribution ratio D was calculated (D: mmole of Zn sorbed per gram of resin divided by mmole of Zn per millilitre of solution). By means of infrared spectroscopy, the mechanism of sorption of zinc ions from rinsing water was determined. There may be a possibility of the formation of complexes in the cation-exchange resin phase. It was found out in this paper that the cation-exchanger KB-2M of macroreticular structure is the most effective for the sorption of the Zn2+-ions from sewage and rinsing water. 相似文献
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The polar cusps of the magnetosphere are key regions for the transfer of mass, momentum, and energy from the solar wind into the magnetosphere. Understaning these key regions and the dynamical interactions that occur there are fundamentally important to determining the physical nature of the magnetosphere. In this paper we try to summarize many of the conclusions reached in the papers of this special issue emphasizing the present concepts and definition of the cusp, what variations could be temporal structures and what could be spatial structures. We address the need for further measurements and the role of present and planned projects to address these needs. 相似文献
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John D. Zambakas 《Pure and Applied Geophysics》1982,120(4):691-697
A recently developed data presentation technique, the rectangular wind frequency isopleth diagram, has been applied to examine the effect of wind speed and direction, acting simultaneously, on ambient air negative ion densities. The large negative ion concentration decreases in the majority of directions and wind speed intervals, while that of the small ions increases, as the wind speed increases. The local maxima and minima, occurring in some sectors, are properly discussed. 相似文献
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Dimitris A. Retalis 《Pure and Applied Geophysics》1977,115(3):575-581
In the present study the influence of smoke and sulfur dioxide concentrations and of wind velocity on the concentration of small positive and negative ions above Athens area (=37°58.3N, =23°43E,h=107 m) is examined.Between the above mentioned elements simple linear correlation and multiple linear correlation is attempted. This correlation is based on mean daily values of the elements, for the two-year period 1971–1972, for each month separately.From the above examination it has been ascertained that small ions concentration increases as smoke and/or sulfur dioxide concentration decreases. Also, small ions concentration increases as wind velocity increases.In addition, it was ascertained that sulfur dioxide contributes the least to the determination of the variance of small ions concentration, whilst the greatest contribution is made by smoke for the positive small ions or by wind velocity for the negative ones. 相似文献
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《地球科学进展》2015,30(12):1295
The interaction between ions and soil particles plays an important role in the mobilization and bioavailability of ions in soils, which is one of the main research areas of soil chemistry. The new method based on suspension Wien effect has been developed recently to determine the binding energy and adsorption energy between ions and soil particles. Compared with other methods on the basis of adsorption isotherm or ions activity, Wien effect method has more advantages including convenience and direct measurement. The term suspension Wien effect refers to the increase of electrical conductivity of suspension with increasing applied electrical field. In this review paper, we introduced the fundamentals of suspension Wien effect, the apparatus about the Wien effect measurement, and along with demonstrating their application to quantifying the particles-ions interactions for several systems of soils. Our studies indicated that divalent cations have larger binding energies and adsorption energies on soil particles than monovalent because of the electrostatic interaction. However, few studies about the interaction between Cr3+ and La3+ on soil particles showed that the binding energy and adsorption energy of trivalent cations are lower than those of divalent cations because of hydrolysis. Soil properties such as soil organic matter, soil pH, and iron oxides significantly affected the binding energy and adsorption energy of ions. Our results deepened our understanding about the non specific adsorption of ions in soil chemistry, and enlarged the research area of soil chemistry in fundamental and methodology. 相似文献
7.
César A. Zen Vasconcellos Dimiter Hadjimichef Magno Machado Benno Bodmann Marcelo Netz-Marzola Geovane Naysinger Mariana Vargas Magaña Peter O. Hess Horst Stöcker Steven Gullberg Remo Ruffini 《Astronomische Nachrichten》2024,345(2-3):e240029
We outline our experience in organizing the first edition of the Workshop on Matter, Astrophysics, Gravitation, Ions and Cosmology, held in virtual and in-person format, denominated MAGIC23, held from 6 to 10 March, 2023, in Praia do Rosa, Santa Catarina, Brazil. The event aimed to bring together leading academic scientists, professors, students, and research scholars for exchanging experiences and discuss the most recent innovations, trends, practical challenges, and experimental and theoretical solutions adopted in the investigation fields within the scope of the meeting. The workshop offered to the participants a platform for scientific and academic projects, partnerships, and presentation of high-quality research contributions describing original and unpublished results on topics related to matter, astrophysics, gravitation, ions, and cosmology. 相似文献
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综合利用中国环境监测网公布的合肥市2013-2015年大气污染物浓度数据和合肥市气象站的常规气象资料,以及激光雷达探测资料、公益性行业（气象）专项（GYHY201206011）获得的气溶胶离子成分分析结果,分析了合肥市PM2.5重污染（日均浓度>150 μg/m3）特征。结果表明:（1）2013-2015年,合肥市PM2.5浓度和重污染天数空间分布差异明显,东北部多、西南部少,1月各站差异最大。除了低浓度日（日均浓度≤35 μg/m3）,PM2.5浓度都存在明显的日变化,午后低、早晚高,且随着污染程度加重,早上峰值出现时间推后。（2）重污染日臭氧以外的气态污染物浓度都显著上升。（3）重污染日常伴随着霾和轻雾天气,以稳定、小风天气为主,重污染日白天相对湿度偏高、风速偏小,600 m以下的消光系数显著增大且峰值高度降低。（4）重污染日PM2.5中水溶性无机离子含量增高,其中NO3-含量的占比增加最多,超过了SO42-的占比。 相似文献
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咸潮入侵对长江河口地区地下水质的影响 总被引：1，自引：0，他引：1
长江河口咸潮入侵对上海市自来水源水水质带来不良影响,从而殃及水厂产水质量而不利于生产和市民健康,这在上海市宝山区表现尤为显著。然而,宝山区地下承压含水层水质优良,资源丰富,且水质稳定,不受咸潮入侵影响。经研究,在不产生地面沉降危害等前提条件下,宝山区尚可扩采500万米~3/年优质地下水。 相似文献
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An important contribution to the thermalization of the solar wind ions at the Earth's bow shock for high Mach numbers comes from the reflection of a fraction of these ions from the shock. Previous studies have examined the trajectories of the reflected ions assuming the shock to be an infinite plane. In this paper a model is developed to describe the trajectories of particles after reflection for a variety of shock geometries. Of particular interest are the initial conditions which allow the particle to return to the shock with a greater normal velocity than at first encounter, or to return to the shock at all. The effects of the magnetic field direction and the curvature of the shock on particle trajectories are discussed for cylindrical and spherical shock geometries and compared to those for a planar shock. 相似文献