Delineation of groundwater protection zones by the backward particle tracking method: theoretical background and GIS-based stochastic analysis   总被引：1，自引：0，他引：1  

Konstadinos N. Moutsopoulos  Alexandra Gemitzi  Vassilios A. Tsihrintzis 《Environmental Geology》2008,54(5):1081-1090

The backward particle tracking method, an effective and powerful tool that can be used to delineate groundwater protection zones, is presented. The theoretical background and insights on the applicability of this method are provided. Moreover, the present work enriches the backward particle tracking method with an uncertainty analysis concerning the porosity values, applying a Monte Carlo (MC) approach, coupled with the use of geographical information systems (GIS). As an application example, a wellfield in the Komotini area, Greece, is investigated. The present study may serve as a potential guideline for wellfield delineation, particularly in areas like Greece where lack of data related to the hydrogeological system is often a problem.  相似文献   

湖北黄土岭麻粒岩锆石拉曼光谱和等离子体质谱研究   总被引：3，自引：0，他引：3  

程昊  陈道公  吴元保  何谋春 《地学前缘》2003,10(2):313-317

对湖北黄土岭麻粒岩中锆石同时进行了激光拉曼探针、阴极发光 (CL)观察和U ,Th及Pb Pb年龄ICPMS测定 ,发现麻粒岩中部分锆石发生的不是固态重结晶作用 ,而是部分熔蚀 /沉淀再结晶过程。结合CL图像结构特征和2 0 7Pb/ 2 0 6Pb年龄初步推断 ,麻粒岩相事件发生在 2 0亿年之后。结构、化学和同位素组成的测定表明 ,大别地区广泛存在的燕山期热事件使锆石发生不同程度的变质重结晶作用 ,使锆石晶格愈合。  相似文献   

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials          下载免费PDF全文

Pei‐Pei Zhao  Jie Li  Le Zhang  Zhi‐Bing Wang  De‐Xin Kong  Jin‐Long Ma  Gang‐Jian Wei  Ji‐Feng Xu 《Geostandards and Geoanalytical Research》2016,40(2):217-226

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.  相似文献   

High Precision Sr‐Nd‐Hf‐Pb Isotopic Compositions of USGS Reference Material BCR‐2          下载免费PDF全文

Jason Jweda  Louise Bolge  Cornelia Class  Steven L. Goldstein 《Geostandards and Geoanalytical Research》2016,40(1):101-115

The Lamont‐Doherty Earth Observatory radiogenic isotope group has been systematically measuring Sr‐Nd‐Pb‐Hf isotopes of USGS reference material BCR‐2 (Columbia River Basalt 2), as a chemical processing and instrumental quality control monitor for isotopic measurements. BCR‐2 is now a widely used geochemical inter‐laboratory reference material (RM), with its predecessor BCR‐1 no longer available. Recognising that precise and accurate data on RMs is important for ensuring analytical quality and for comparing data between different laboratories, we present a compilation of multiple digestions and analyses made on BCR‐2 during the first author's dissertation research. The best estimates of Sr, Nd and Hf isotope ratios and measurement reproducibilities, after filtering at the 2s level for outliers, were ⁸⁷Sr/⁸⁶Sr = 0.705000 ± 11 (2s, 16 ppm, n = 21, sixteen digestions, one outlier), ¹⁴³Nd/¹⁴⁴Nd = 0.512637 ± 13 (2s, 25 ppm, n = 27, thirteen digestions, one outlier) and ¹⁷⁶Hf/¹⁷⁷Hf = 0.282866 ± 11 (2s, 39 ppm, n = 25, thirteen digestions, no outliers). Mean Nd and Hf values were within error of those reported by Weis et al. (2006, 2007) in their studies of RMs; mean Sr values were just outside the 2s uncertainty range of both laboratories. Moreover, a survey of published Sr‐Nd‐Hf data shows that our results fall within the range of reported values, but with a smaller variability. Our Pb isotope results on acid leached BCR‐2 aliquots (n = 26, twelve digestions, two outliers) were ²⁰⁶Pb/²⁰⁴Pb = 18.8029 ± 10 (2s, 55 ppm), ²⁰⁷Pb/²⁰⁴Pb = 15.6239 ± 8 (2s, 52 ppm), ²⁰⁸Pb/²⁰⁴Pb = 38.8287 ± 25 (2s, 63 ppm). We confirm that unleached BCR‐2 powder is contaminated with Pb, and that sufficient leaching prior to digestion is required to achieve accurate values for the uncontaminated Pb isotopic compositions.  相似文献   

Production and Certification of Synthetic Selenium Isotopic Reference Materials          下载免费PDF全文

Tongxiang Ren  Jun Wang  Hai Lu  Tao Zhou  Yuanjing Zhou 《Geostandards and Geoanalytical Research》2016,40(2):227-238

Due to intensive research into selenium isotopes in recent years, the increasing requirement for reliable and comparable measurement results has created a strong demand for selenium isotopic certified reference materials (iCRM) that were previously not available. To address this, eleven selenium iCRMs were developed, including ten synthetic iCRMs (GBW 04447–GBW 04456) and one natural iCRM (GBW 04457). The synthetic iCRMs were prepared with ⁷⁶Se, ⁷⁸Se, ⁸⁰Se and ⁸²Se solutions and a natural selenium solution; the natural iCRM was prepared with highly pure selenium material. The property values of isotope ratios in these iCRMs were certified by calibrated mass spectrometry with a collision cell multi‐collector ICP‐MS. The mass discrimination effect of the instrument was corrected with corresponding ⁷⁸Se/⁷⁶Se isotope mixtures and ⁸²Se/⁷⁶Se isotope mixtures, which were gravimetrically prepared with purified, isotopically enriched selenium materials. Homogeneity and stability tests were performed, and no significant influences were found. The uncertainty of the property values of the iCRMs was evaluated according to the Guide to the Expression of Uncertainty in Measurement (GUM) of ISO/BIPM and ISO Guide 35. The δ^82/76Se value of GBW 04457 relative to NIST SRM 3149 was also calculated. These iCRMs are intended for use in calibration of instruments and evaluation of methods for the determination of selenium isotope ratios.  相似文献   

Effect of the Dry Ashing Method on Cadmium Isotope Measurements in Soil and Plant Samples     

Wei‐Xin Lv  Hao‐Ming Yin  Meng‐Shu Liu  Fang Huang  Hui‐Min Yu 《Geostandards and Geoanalytical Research》2021,45(1):245-256

A dry ashing method is commonly used to remove organic material from samples prior to geochemical analysis. In the course of this study, the Cd isotope ratios of a series of soil and plant reference materials and samples were studied to evaluate the effect of the dry ashing method on measurement results of Cd isotope ratios. The samples were pre‐treated using the dry ashing method and high‐pressure bomb for comparison. The results show that the digestion using high‐pressure bombs did not lead to Cd loss, but using the dry ashing method would cause different proportions of Cd loss. The whole range of Cd isotope difference between two methods was from ?0.07‰ to 3.01‰. There was also an obvious difference in measured Cd isotope ratios from the same leaf sample pre‐treated independently by the dry ashing method, indicating that the amount of Cd loss and the effect on Cd isotope measurement during dry ashing is related to the properties of the samples. Therefore, dry ashing may not be appropriate for the removal of organic material in Cd isotope ratio measurement, especially for samples with high organic contents. The δ^114/110Cd values of reference materials NIST SRM 1573a and GSD‐30 are reported for the first time in this study.  相似文献   

豫北及其外围地区地壳上地幔结构研究   总被引：17，自引：3，他引：17       下载免费PDF全文

张成科  赵金仁 《地震地质》1994,16(3):243-253

利用菏泽～长治和郑州～济南深地震测深剖面资料，进行了一维、二维射线追踪走时拟合与合成地震图计算，获得了该区地壳上地幔速度结构。结果表明，地壳上地幔速度结构在纵向和横向上具有明显的不均一性。浅部断裂较发育，对应其地壳深部界面和速度等值线起伏变化较明显。在华北坳陷区南部上地幔隆起的背景上存在两个局部凸起，凸起最高处与浅部的东濮凹陷、汤阴地堑基本对应，Ｍ面埋深分别约３１ｋｍ和３４ｋｍ  相似文献   

粘滑失稳及其物理场时空分布的实验研究   总被引：6，自引：3，他引：6  

邓志辉  马胜利 《地震地质》1995,17(4):305-310

摩擦滑动的物理场实验研究表明：（１）能量空间分布的差异是失稳的重要条件，单发型大事件常发生于高能量向低能量的突变带或高能量背景区内的相对低能量区；（２）单发型大事件的孕育过程常常经历若干个能量输入输出循环，产生多个前兆阶段，并在失稳前源区常有一个弱化过程。小震或群发型事件失稳前常常只有一个能量积累与强化的过程，失稳前兆阶段性反映较差；（３）粘滑失稳时断层的位错与声发射的大小未见明显关系  相似文献   

湘东─赣西NNE向走滑构造   总被引：6，自引：3，他引：6  

李先福  傅昭仁  李建威  陈小东 《大地构造与成矿学》2001,25(2):136-140

湘东─赣西构造岩浆带位于郯庐断裂南延的关键性部位。中生代以来，该区 NNE向左旋走滑构造主要由会聚走滑和 K─ E离散走滑构造叠加而成。会聚走滑作用造就了 NNE向雁列式剪切断裂系、剪切弯曲和旋转构造、压剪性煤盆地以及断层动热变质─剪切重熔型花岗岩；而离散走滑作用则控制了该区广泛发育的张剪性红盆地、盆岭式构造地貌、以及大规模中低温热液矿床的形成。湘东─赣西复杂的平移构造型式很可能与该区地壳结构分层特征、前期断裂构造格局、平移幅度和多期走滑构造作用四个因素有关。  相似文献   

初论兰坪盆地构造流体与成矿作用的时空格架及可能的成矿模式   总被引：7，自引：0，他引：7  

李小明  胡宝清 《大地构造与成矿学》2001,25(2):187-193

滇西兰坪盆地中新生代形成了丰富的金属与盐类矿床，是我国著名的热液矿床成矿带。成矿系统时─空结构的统一性是进行成矿规律研究和成矿预测的前提和指导思想，综合分析兰坪盆地的成矿时代、矿床的空间分布及区域地质背景，初步认为：晚白垩世至早第三纪，盆地西缘出现以铜为主的成矿作用；兰坪盆地主要成矿作用发生在早、晚第三纪期间，因盆地东、西部边界向两边地块的俯冲碰撞及中轴断裂带的强烈活动，导致盆地中央地带出现大规模成矿流体活动，成矿流体因物理化学性质的改变而发生分异、运移，及盆地受挤压隆升，变成山间盆地，出现不同类型、不同大小的流体圈闭，因而形成不同种类，不同规模的矿床；同时，含有挥发性组分汞、锑、砷的流体从深部沿中轴断裂带上升向两侧的次级构造裂隙带扩散，导致盆地东部复式背斜带中出现锑、汞、砷的成矿作用；其后，矿床受到改造和氧化作用。盆地内发育深大断裂；兰坪盆地的成矿作用是在构造流体演化的制约下完成的，同时成矿作用的发生改变了流体的性质和构造环境，促使流体的再次循环，出现成矿作用的多期性、分带性。  相似文献