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1.
The organic geochemical methods of hydrocarbon prospecting involve the characterization of sedimentary organic matter in terms of its abundance, source and thermal maturity, which are essential prerequisites for a hydrocarbon source rock. In the present study, evaluation of organic matter in the outcrop shale samples from the Semri and Kaimur Groups of Vindhyan basin was carried out using Rock Eval pyrolysis. Also, the adsorbed low molecular weight hydrocarbons, methane, ethane, propane and butane, were investigated in the near surface soils to infer the generation of hydrocarbons in the Vindhyan basin. The Total Organic Carbon (TOC) content in shales ranges between 0.04% and 1.43%. The S1 (thermally liberated free hydrocarbons) values range between 0.01–0.09 mgHC/gRock (milligram hydrocarbon per gram of rock sample), whereas the S2 (hydrocarbons from cracking of kerogen) show the values between 0.01 and 0.14 mgHC/gRock. Based on the Tmax (temperature at highest yield of S2) and the hydrogen index (HI) correlations, the organic matter is characterized by Type III kerogen. The adsorbed soil gas, CH4 (C1), C2H6 (C2), C3H8 (C3) and nC4H10, (nC4), concentrations measured in the soil samples from the eastern part of Vindhyan basin (Son Valley) vary from 0 to 186 ppb, 0 to 4 ppb, 0 to 5 ppb, and 0 to 1 ppb, respectively. The stable carbon isotope values for the desorbed methane (δ13C1) and ethane (δ13C2) range between −45.7‰ to −25.2‰ and −35.3‰ to −20.19‰ (VPDB), respectively suggesting a thermogenic source for these hydrocarbons. High concentrations of thermogenic hydrocarbons are characteristic of areas around Sagar, Narsinghpur, Katni and Satna in the Son Valley. The light hydrocarbon concentrations (C1–C4) in near surface soils of the western Vindhyan basin around Chambal Valley have been reported to vary between 1–2547 ppb, 1–558 ppb, 1–181 ppb, 1–37 ppb and 1–32 ppb, respectively with high concentrations around Baran-Jhalawar-Bhanpur-Garot regions (Kumar et al., 2006). The light gaseous hydrocarbon anomalies are coincident with the wrench faults (Kota – Dholpur, Ratlam – Shivpuri, Kannod – Damoh, Son Banspur – Rewa wrench) in the Vindhyan basin, which may provide conducive pathways for the migration of the hydrocarbons towards the near surface soils. 相似文献
2.
Release of heavy metals during weathering of the Lower Cambrian Black Shales in western Hunan,China 总被引：8，自引：0，他引：8
Bo?PengEmail author Zhaoliang?Song Xiangling?Tu Meilian?Xiao Fucheng?Wu Huanzhe?Lv 《Environmental Geology》2004,45(8):1137-1147
Weathering of heavy metal enriched black shales may be one of the most important sources of environmental contamination in areas where black shales are distributed. Heavy metal release during weathering of the Lower Cambrian Black Shales (LCBS) in western Hunan, China, was investigated using traditional geochemical methods and the ICP-MS analytical technique. Concentrations of 16 heavy metals, 8 trace elements and P were measured for samples from selected weathering profiles at the Taiping vanadium ore mine (TP), the Matian phosphorous ore mine (MT), and Taojiang stone-coal mine (TJ). The results show that the bedrock at these three profiles is enriched with Sc, V, Cr, Co, Ni, Cu, Zn, Pb, Th, U, Mo, Cd, Sb, Tl, and P. Based on mass-balance calculation, the percentages of heavy metals released (in % loss) relative to immobile element Nb were estimated. The results show significant rates of release during weathering of: V, Cr, Co, Ni, Cu, Zn, U, Mo, Cd, Sn, Sb, and Tl for the TP profile; Sc, Cr, Mn, Co, Ni, Cu, Zn, Pb, Th, Cd, and Sn for the MT profile; and Sc, Mn, Co, Ni, Zn, Th, Cd, Sn, and Tl for the TJ profile. Among these heavy metals, Co, Ni, Zn, Cd, and Sn show very similar features of release from each of the three weathering profiles. The heavy metals released during weathering may affect the environment (especially topsoil and surface waters) and are possibly related to an observed high incidence of endemic diseases in the area. 相似文献
3.
S.M. Moosavirad M.R. Janardhana M.S. Sethumadhav M.R. Moghadam M. Shankara 《Chemie der Erde / Geochemistry》2011,71(3):279-288
Lower Jurassic shales of the Shemshak Formation of Kerman Province, Central Iran, were analyzed for major and selected trace elements to infer their provenance, intensity of palaeoweathering of the source rocks and tectonic setting. Plots of shales on Al2O3 wt.% versus TiO2 wt.% diagram and Cr (ppm) versus Ni (ppm) diagram indicate that acidic (granitic) rocks constitute the source rocks in the provenance. Average CIA, PIA and CIW values (84%, 92%, 93%, respectively) imply intense weathering of the source material. Plots of shales on bivariate discriminant function diagram reveal an active continental margin setting for the provenance. The inferred tectonic setting for the Lower Jurassic shales of the Shemshak Formation of Kerman Province is in agreement with the tectonic evolutionary history of the Central Iran during the Jurassic period. 相似文献
4.
Jonathan B. Laronne 《地球表面变化过程与地形》1981,6(6):541-552
Inquiry into the dissolution kinetics of naturally occurring geologic materials, rather than individual mineral species, has been relatively neglected. This is especially true of surface processes, the realm of surface water hydrology and geomorphology. This paper focuses attention at a laboratory study of the rate of such complex reactions. Functions defining the dissolution rates of saline (0.1–20 per cent salt content) Mancos Shale-associated alluvium in distilled water follow varying patterns. Dissolution is characterized by an initial (<5 min) high rate constant, by a following phase (20 min-57 h) where rates are reduced drastically, and by a final period of encroachment to equilibrium. Initial dissolution rates increase with increase in salt content and sediment: water ratio. The time necessary to approach equilibrium is, however, found to be directly proportional to the sediment; water ratio. The concentration of Na+, Mg2+, Ca2+, SC2?4 and HCO?3, and the relative abundance of Ca2+ and HCO?3 increase continuously with contact time, indicating that the hydrated sodium and magnesium sulphate minerals provide most of the initial solutes, though not necessarily most of the total solute bulk. The results obtained in this study indicate that the high initial dissolution rate of soluble minerals from alluvium, and particularly from shales in contact with aqueous solutions, is too short-lived to account for most of the solutes occurring in heavily sediment-laden surface flow. Excluding input from slower, usually supersaturated subsurface flow, dissolution from sediment in transport should be a major source of solutes in originally undersaturated and kinetically unequilibrated surface water in semiarid and arid regions. 相似文献
5.
The Lagonegro Units are a part of the southern Apennines orogenic wedge. The age of the Lagonegro successions ranges from lower–middle Triassic to Oligo-Miocene. During late Cretaceous and Oligocene the deposition of calcareous-clastic sediments occurred interbedded with shales (Flysch Rosso Fm). During Oligocene and early Miocene, in the Mediterranean area, an important variation of the tectonic regime occurred, and siliciclastic sediments of the Numidian Basin unconformably lay on the Meso-Cenozoic units of the Lagonegro Basin. In the Lucanian Apennine, the Aquitanian–Langhian Numidian Flysch Fm overlies the Flysch rosso Fm. The shales of the Flysch rosso Fm have a peculiar geochemical fingerprint relative to typical shales of post-Archean age. The abundance of Ni and Cr is significantly higher and the HREE chondrite-normalized patterns are steep with a (Gd/Yb)ch>2. A supply of material from the African Archean terranes could be the cause. The palaeo-weathering indices record changes at the source, reflecting variations in the tectonic regime. The oldest samples are derived from an environment in which steady-state weathering conditions prevailed, whereas the youngest samples are related to non-steady-state weathering conditions. This difference could record deformational events that affected the Mediterranean area during the Oligocene and early Miocene. The sample at the top of the studied log has very high silica content and an abundant coarse grain-sized fraction. This suggests that this sample belongs to the Numidian Flysch Fm. The geochemical proxies of this sample are different from those associated with samples from the Flysch rosso Fm, indicating that the source-area of the Numidian Flysch Fm did not include the Archean terranes. 相似文献
6.
Yahia E.-A. Mohamedzein Amer A. Al-Rawas Mohammed Y. Al-Aghbari Ahmed Qatan Abdul-Hamid Al-Rawas 《Engineering Geology》2005,80(3-4):271-281
The possibility of using crushed shales as landfill liners is investigated in this study. Two types of shales were studied by performing the following laboratory tests: hydraulic conductivity, compaction, swelling, consolidation, X-ray diffraction (XRD), scanning electron microscope (SEM) and chemical analysis. For both compacted shales, the hydraulic conductivity was in order of 10− 7 cm/s or less which satisfies the specifications for landfill liners. The results of XRD and SEM support the low values of the hydraulic conductivity. Because of the dominant presence of low-activity kaolinite, there was no significant change in the hydraulic conductivity when the compacted shales are exposed to calcium chloride solution. The compressibility of the compacted clay was low and no serious post-construction settlement is expected. The shear strength of the compacted shales was within the usual expected range for earthen liners and, therefore, should pose no challenges with respect to shear strength. The crushed shales also satisfy the other criteria related to Atterberg limits and grain size. 相似文献
7.
Paola Di Leo Enrico Dinelli Giovanni Mongelli Marcello Schiattarella 《Sedimentary Geology》2002,150(3-4):229-246
A better understanding of genesis and palaeoenvironmental setting of the Scisti silicei Formation (Lagonegro units, southern Italy) was achieved by means of geochemical analysis integrated with new stratigraphic information. Data show that major and trace element geochemistry of ancient clay-rich beds and banded cherts add new insights into the Mesozoic evolution of the Lagonegro basin. Sedimentary contributions to Jurassic shales sampled during this study were mainly derived from two major sources: (i) a dominant terrigenous fine-grained component, having affinity with average upper continental crust that had not undergone intense weathering and (ii) biogenic siliceous material. The latter component occurs in clay-rich layers from the “basal member” of the Scisti silicei Formation.
Composition varies up section and accounts for changes in the detrital supply due to bathymetric oscillations. The compositional variations from the basal to the overlying member are consistent with a distal source passing in time to a more “proximal” source, as indicated by sharp changes in the concentrations of detrital elements (Ti, Zr and Nb). It is likely that increased detrital input occurred through turbidity current deposition. Finally, the chemical features of the clay-rich layers from the upper cherty portion of the studied succession imply a progressive deepening of the basin.
The lack of any mafic and hydrothermal contributions in the Jurassic shales as well as the continental nature of detrital input suggests that the Lagonegro basin was located between two carbonate platforms, in accordance with the classical restoration of the African–Apulian palaeomargin. Thus, the basin acted as a preferential sink connected to the African cratonic areas through a southern entry point. 相似文献
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9.
本研究对涪陵地区井下产气的龙马溪组页岩岩芯,采用三轴压机压裂制造裂缝,用工业CT扫描压裂前后岩芯,应用图像识别技术统计出裂缝体密度,又用超声脉冲透射法测定样品破裂前后裂缝方向上的纵波、单偏振方向与裂缝不同夹角的横波,来研究裂缝对页岩岩芯声学性质的影响.实验结果表明:压裂后样品的纵波速度略微降低,只有含较多内部裂隙的150#样品纵波速度减小幅度明显.压裂前后样品的纵波波形差别不大,纵波主频随裂缝体密度呈下降趋势,即压裂后纵波频谱主频向低频端移动.压裂前横波速度随自身与裂隙方位角变化而变化,与0°和180°相比,在45°和135°时略微减小,在90°时速度降低幅度最为明显并且发生相位反转.典型样品的横波主频随偏振方向与裂缝夹角的增大而逐渐向低频移动;压裂后,横波频谱杂乱,出现多处局部峰值,速度和主频较压裂前更低,平均横波波速随裂缝体密度呈明显减小趋势.平均纵横波速比随裂缝密度呈近线性增加,表明其与裂缝体密度有较强相关性. 相似文献
10.
皖北新元古代刘老碑组页岩的地球化学特征及其地质意义 总被引：16，自引：0，他引：16
从安徽北部新元古代刘老碑组页(泥)岩中采集了11个样品。地球化学分析表明,研究区南部的淮南和凤阳页岩样品SiO2、TiO2、Al2O3、K2O、TFeO和CaO含量分别为55.28%、0.87%、15.60%、2.99%、4.01%和5.83%,接近页岩平均值,只是CaO含量稍高。北部宿县地区页岩样品SiO2、TiO2、Al2O3、K2O、TFeO和CaO含量分别为57.01%、1.82%、20.97%、4.85%、3.31%和0.57%,与南部地区相比,TiO2和K2O含量显著偏高,是其2.1倍和1.6倍。刘老碑组页岩REE总量平均为219×10-6,LREE富集,La/Yb为14.2(9.8～18.6),Eu负异常,Eu/Eu*为0.60(0.54～0.63),但是北部页岩有更高的REE总量(295.8×10-6)和La/Yb比值(17.8)。微量元素分析表明,北部页岩中Sc、V、Zr、Nb和Th较高,南部Co和Pb较高。但是南部和北部却有比较一致的La/Sc(2.29±0.15)、Th/Sc(0.69±0.06)和La/Th(3.29±0.20)比值。La-Th-Sc和Th-Sc-Zr/10判别图清楚地表明,刘老碑组页岩形成于大陆岛弧构造环境,岛弧可能位于研究区的南部边缘。北部页岩明显偏高的TiO2和Al2O3含量以及化学风化指数(CIW)表明北部沉积物的源区经历了更强烈的风化作用。 相似文献