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1.
Chemical structure of Jurassic vitrinites isolated from the coals in basins in NW China have been checked using solid state 13C NMR and flash pyrolysis-GC/MS. Study shows some Jurassic collodetrinites are rich in aliphatic products in pyrolysates, consisting with the high amount of methylene carbon in 13C NMR spectra. In contrast, pyrolysates of Jurassic collotelinites are rich in phenols and alkylbenzenes. Also one Pennsylvanian and one Permian vitrinite selected from the Ordos basin, NW China have been checked for comparison. The proportion of aliphatics is low in pyrolysates, and aliphatic carbon peak in 13C NMR spectrum of Permian vitrinite is mostly composed of gas-prone carbons compared with collodetrinites in those Jurassic basins. But both pyrolysis and 13C NMR data shows the Pennsylvanian vitrinite is not only gas-prone but also oil-prone. Relatively high proportion of long chain aliphatic structure of some Jurassic vitrinite in Junggar, Turpan-Hami basins may be due to the contribution of liptodetrinites, which may be included during the formation of vitrinites. And it seems that suberinite is the most possible precursor of long chain aliphatics in the structure of Jurassic collodetrinite. 相似文献
2.
Deep sea drilling in the Central Gulf of California, a young and active spreading centre, shows that the high heat flow typical of these regions causes extensive alteration of sediment organic matter, especially near sills and above magma chambers where hydrothermal activity is concentrated. Even on the nearby passive margin, where there are no sills, heat flow is moderately high and hydrocarbon generation has begun in immature sequences. Migrating light hydrocarbons are detected especially where hydrothermal activity is concentrated. Thermogenic methane is more widespread, though not in the passive margin bordering the spreading centre. Despite the incidence of hydrocarbon generation and migration, the amounts of hydrocarbons involved are relatively small and apparently do not lead to commercially significant accumulations of petroleum.The organic matter in these sediments is mostly marine because the Gulf of California generally has low runoff from land and highly productive surface waters. Turbidites rich in terrigenous organic material are locally abundant in the mainly pelagic section in the Guaymas Basin. The highest concentrations of organic matter are found in laminated diatomites deposited on the Guaymas passive margin within the oxygen minimum zone. 相似文献
3.
Combined subsidence and thermal 1D modelling was performed on six well-sections located in the north-western Mid-Polish Trough/Swell
in the eastern part of the Central European Basin system. The modelling allowed constraining quantitatively both the Mesozoic
subsidence and the magnitude of the Late Cretaceous–Paleocene inversion and erosion. The latter most probably reached 2,400 m
in the Mid-Polish Swell area. The modelled Upper Cretaceous thickness did not exceed 500 m, and probably corresponded to 200–300 m
in the swell area as compared with more than 2,000 m in the adjacent non-inverted part of the basin. Such Upper Cretaceous
thickness pattern implies early onset of inversion processes, probably in the Late Turonian or Coniacian. Our modelling, coupled
with previous results of stratigraphic and seismic studies, demonstrates that the relatively low sedimentation rates in the
inverted part of the basin during the Late Cretaceous were the net result of several discrete pulses of non-deposition and/or
erosion that were progressively more pronounced towards the trough axis. The last phase of inversion started in the Late Maastrichtian
and was responsible for the total amount of erosion, which removed also the reduced Upper Cretaceous deposits. According to
our modelling results, a Late Cretaceous heat-flow regime which is similar to the present-day conditions (about 50 mW/m2) was responsible for the observed organic maturity of the Permian-Mesozoic rocks. This conclusion does not affect the possibility
of Late Carboniferous–Permian and Late Permian–Early Triassic thermal events. 相似文献
4.
Saturated and aromatic biomarker ratios continue to change systematically through the oil window and into the gas-condensate window to high vitrinite reflectances (Ro = 1.16%) in mature marine and lacustrine Mesozoic clastic samples from a South African basin. Two of the ratios reverse above Ro = 0.9%. These unusual maturation effects result from isolated periods of high rates of maturation increase. The basin cooled regionally after the break-up of Gondwana but high heating rates prevailed during the late Cretaceous-early Tertiary, as Africa moved across a hotspot, and again in the late Tertiary as a result of a possible hotspot and hydrothermal event. 相似文献
5.
四川盆地东北地区古地温梯度模拟 总被引：2，自引：0，他引：2
四川盆地东北地区古地温梯度一直缺乏研究。以普光气田已有的实测反射率数据为依据,应用EasyRo模拟计算方法,研究了该区主要生烃期的古地温梯度。结果表明,对川东北地区主要埋藏与生烃期(三叠纪—早白垩世)进行的成熟度模拟计算,应用古地温梯度为3.0℃/100m的古地温模式计算所得的结果与实测结果非常吻合。进一步提出了该区的简化古地温模式为[3.0℃/100m(96Ma)—2.8℃/100m(65Ma)—2.2℃/100m(0Ma)]。 相似文献
6.
尽管塔里木盆地石炭系富含有机质且已发现其生成的原油,但关于石炭系烃源岩热演化研究却很薄弱。根据基础地质资料、古地温梯度和实测镜质体反射率数据,本文定量模拟了塔里木盆地6口典型井的石炭系烃源岩热演化史和这套烃源岩底界、顶界在二叠纪末期、三叠纪末期、白垩纪末期及现今成熟度的平面分布规律。塔北隆起南部、塔西南坳陷和阿瓦提凹陷在石炭-二叠纪作为沉降中心接受了巨厚的沉积物,造成这些地区石炭系烃源岩底界成熟度在二叠纪末期达到0.9%～1.3%（中-高成熟）,顶界为0.5%～0.9%（低-中成熟）,成为有利生油区。中生代时期,塔里木盆地中、东部长期处于沉降状态,石炭系烃源岩处于成熟演化阶段。白垩纪末期,塔中低凸起和满加尔凹陷的石炭系底界成熟度为0.7%～0.9%（中成熟）,顶界为0.5%～0.7%（低成熟）,而塘古孜巴斯坳陷底界成熟度为0.9%～1.1%（中-高成熟）,顶界为0.7%～0.9%（中成熟）。受羌塘地体、拉萨地体、印度板块分别与欧亚板块南缘碰撞远程效应的影响,塔西南坳陷和巴楚隆起在中生代一直处于隆升剥蚀状态,烃源岩热演化进入停滞状态。新生代以来,塔西南坳陷和阿瓦提凹陷演化为前陆盆地,再次接受了巨厚沉积物,致使石炭系烃源岩快速成熟演化,底-顶界成熟度现今已超过2.0%,进入干气阶段。满加尔凹陷石炭系烃源岩自石炭纪至今一直处于成熟演化阶段,现今达到最大,为0.8%～1.0%。另外,热史研究表明塔西南坳陷和阿瓦提凹陷石炭系烃源岩具有二次生烃潜力。本研究不仅丰富了塔里木盆地石炭系烃源岩热史研究成果,而且对油气勘探与开发具有重要的指导意义。 相似文献
7.
通过6种不同煤阶煤的弹性测试,分析了煤岩变质程度（以镜质组最大反射率表示）与煤岩品质因子之间的关系;在此基础上,进一步分析了煤岩速度与品质因子之间的关系及纵波与横波品质因子的各向异性特征.研究发现：煤岩镜质组最大反射率与纵波、横波品质因子均存在良好的线性相关性;垂直层理方向的波速与品质因子存在良好的线性关系,好于走向与倾向方向;垂直层理方向的纵波与横波品质因子线性相关,相关系数可达93.5%;煤岩的三方向品质因子存在各向异性,且强于速度的各向异性.通过横波品质因子与纵波品质因子间相互换算的理论公式计算结果与实验室实测结果的对比,证明了该理论公式的可靠性,误差小于10%,为多分量转换波的吸收衰减补偿提供了理论依据. 相似文献
8.
四川盆地的构造、热演化与峨眉山超级地幔柱有密切关系.峨眉山超级地幔柱对四川盆地中二叠统之下的烃源岩热演化有着十分重要的影响.在四川盆地热历史恢复的基础上,研究了峨眉山超级地幔柱对盆地内烃源岩,特别是中二叠统之下的古生界烃源岩热演化的影响.结果表明,中二叠统及下伏烃源岩的热演化受中晚二叠世发生在盆地西南方向的峨眉山超级地幔柱的影响巨大,且具地区差异性.即在靠近峨眉山地幔柱中心的地区,有机质迅速成熟并达到其成熟度的最高值(以H1井为代表),古生界烃源岩迅速进入过成熟,此后未有二次生烃;而远离峨眉山地幔柱的盆地大部分地区,古生界烃源岩在二叠纪以来具有多次生烃过程.中生界烃源岩热演化,主要和前陆盆地阶段的构造过程包括前陆沉积和断裂的逆冲推覆等相关. 在烃源岩有机质成熟度演化史的基础上,从盆地热史和烃源岩热演化的角度指出了下二叠统及之下烃源层在四川盆地不同地区油气勘探中的不同意义. 相似文献
9.
内蒙古锡林郭勒地区上古生界极低级变质作用:伊利石和镜质体反射率的证据 总被引：6，自引：3，他引：3
本文使用D/max-2500X射线衍射仪研究了内蒙古锡林郭勒地区上古生界泥质岩石伊利石的成因标志,讨论了有机质镜质体反射率对变质温度的表征。研究区上古生界泥质岩石伊利石的标型特征为:伊利石结晶度分布于0.28～>0.77之间,平均值0.40;伊利石(白云母)多型以2M1型为主,2M1+1Md多型和1Md多型相对较少;伊利石(白云母)b0值变化于8.983～9.046之间,平均值9.019,指示其形成于成岩-极低级变质作用。有机质镜质体反射率具有示踪变质温度的作用,应用Barker and Pawlewiez(1986,1994)、Barker and Goldsteinl(1990)和Mullis et al.(2001)建立的镜质体反射率地质温度计,对研究区上古生界泥质岩石变质温度进行了估算,揭示古地温处于136～321℃之间,温度估算值主要分布在180～260℃之间,平均值为245℃,这表明研究区上古生界遭受了成岩-极低级变质作用,变质程度属近变质带。研究区上古生界泥质岩石的Ro值主要分布在1.01%～3.67%之间,表明有机质演化处于成熟-过成熟阶段,泥质岩石具有生烃的能力,部分层位可能具有形成油气资源的潜力。 相似文献
10.
为了利用煤镜质组反射率推断豫北构造应力场,基于构造应力是造成镜质组反射率各向异性（VRA）的主要控制因素,对在豫北焦作、安阳、鹤壁三个矿区井下取的定向煤样品进行了室内显微镜下反射率测试,对测试数据按有关公式进行计算后就得出了由最大反射率值、中间反射率值、最小反射率值为轴组成的镜质组反射率椭球体（VRI）.结果表明,研究区煤样显示二轴晶正光性,它们经过了强烈的构造变形,研究区煤样镜质组反射率各向异性是由构造应力所引起;由镜质组反射率椭球体（VRI）得出的豫北构造应力场与钻探、节理统计、河南省区域构造应力场分析等方法得出的应力场基本上是吻合的,但也有一定的区别,主要体现在应力场到安阳、鹤壁矿区后发生了向左的偏转.总之,利用煤镜质组反射率各向异性推断构造应力场的方法是可行的、是有效的. 相似文献