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1.
Kinetics of fine wet grinding of zeolite in a steel ball mill in comparison to dry grinding 总被引：1，自引：0，他引：1
Batch wet grinding of zeolite was studied with emphasis on a kinetic study in a laboratory size steel ball mill of 200 mm diameter. The breakage parameters were determined by using the single sized feed fractions of − 850 + 600 µm, − 600 + 425 µm and − 425 + 300 µm for the zeolite samples. The Si (specific rate of breakage) and Bi,j (primary breakage distribution) values were obtained for those feed size fractions in order to predict the product size distributions by simulation for comparison to the experimental data. The specific rates of breakage values for wet grinding in the first-order breakage region were higher than the dry values reported previously by a factor 1.7 at the same experimental conditions, but the primary breakage distribution (Bi,j) values were approximately the same. The simulations of the product size distributions of zeolite were in good agreement with the experimental data using a standard ball mill simulation program. The wet grinding of zeolite was subjected to slowing-down effect in the mill at 2 min of grinding, corresponding to an 80% passing size of about 400 µm. On the other hand, the slowing down effect in the dry grinding of zeolite was also seen at 4 min of grinding. In addition, effects of some operational parameters on dry and wet grinding of zeolite were determined by simulation using the breakage parameters obtained experimentally. 相似文献
2.
无机盐改性对沸石覆盖技术控制底泥氮磷释放的影响研究 总被引：5，自引：0，他引：5
通过试验,考察了无机盐改性对沸石覆盖控制底泥氮磷释放效果的影响,并对沸石覆盖技术控制底泥氮磷释放的机理进行初步探讨,结果表明:①NaCl及CaCl2改性对沸石吸附氨氮的性能影响不大;CaCl2改性可以提高沸石Ca2 的交换量而降低Na 的交换量,NaCl改性则可以明显降低Ca2 的交换量和增加Na 的交换量.②NaCl及CaCl2改性对沸石覆盖技术控制底泥氨氮的释放影响不大,而对控制底泥磷的释放则影响较大,沸石覆盖控制底泥磷释放效率从大到小依次为CaCl2改性沸石＞天然沸石＞NaCl改性沸石.③沸石覆盖技术控制底泥氨氮释放的机理为沸石的物理吸附和阳离子交换作用,控制底泥磷释放的机理包括沸石的机械阻挡作用和沸石与铵所交换出来的Ca2 对磷酸盐的固定作用. 相似文献
3.
This is an exploratory study on the high-pressure (HP) structural evolution of a zeolitic framework (with LEV topology) on the basis of geometric modelling and previously published accurate unit-cell constants measured by means of single-crystal X-ray diffraction. The geometric simulations for 11 P values from 0 to 5 GPa gives more insight into the HP-behaviour of levyne, showing that the anomalous elastic behaviour of this zeolite observed under hydrostatic conditions at low P (P<1 GPa) is due to a double change in the compressional mechanism. Since the geometric simulation is not restricted to using the experimentally determined cell parameters, simulations of uniaxial compression along the [001] direction and of compression in the (001) plane have been performed, shedding more light on the compression mechanisms under non-hydrostatic regimes, which are difficult to access experimentally. The mechanisms associated with compressions along different axes provide insight into the hydrostatic compression mechanisms leading to the anomalous elastic behaviour.Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users. 相似文献
4.
Arkadiusz Derkowski Wojciech Franus Halina Waniak-Nowicka Adriana Czímerová 《International Journal of Mineral Processing》2007
Zeolite Na–X (FAU type) was synthesized from F-class fly ash in simple and economical way. Several months of storage of fly ash in NaOH solution, at room temperature, without any prior treatment, results in the production of material with ca. 50% content of Na–X zeolite. The most efficient reaction takes place at (OH)− activity of 0.1–0.15 mol (OH)−/g of ash and at S/L ratio of 33 to 67 g/dm3. Higher S/L value causes an accelerating dissolution–crystallization equilibrium attainment. Cl− ion acts as the inhibitor of this reaction. 相似文献
5.
砚山沸石矿经物理法活化,化学法改型,制成离子交换剂(吸附剂),增强沸石矿的吸附、离子交换能力,对营养化水体有较好的净化作用。加工工艺成本低、设备简单、操作方便。 相似文献
6.
Lindsay J. McHenry Luis Luque Jos ngel Gmez Fernando Diez-Martín 《Quaternary Research》2011,75(3):708-720
The Pleistocene Humbu and Moinik formations of the Peninj Group in northern Tanzania preserve an important archaeological and paleontological record, in addition to a record of local volcanism in the form of tephra and lavas. Samples of the major Humbu and Moinik formations' basaltic and trachytic tephra were collected and characterized using phenocryst composition and both primary and authigenic mineral assemblage, since the volcanic glass was completely altered to zeolite. Some tephra are distinguishable solely using phenocrysts, but some are too similar in mineral composition or too poor in phenocrysts to definitively “fingerprint” without glass. Titanomagnetite phenocrysts were mostly altered; characterization was thus limited to feldspar, augite, and hornblende compositions for most tephra. Phenocryst compositions were compared to Olduvai tephra compositions to see if any regional tephra could be identified that could help correlate the sites. Augite or hornblende composition rules out potential correlations of Olduvai Bed I Tuff IF and the Bed II Bird Print Tuff or Tuff IID to otherwise similar Peninj Group tephra. Despite their overlap in age and locations at less than ~ 80 km from the Ngorongoro Volcanic Highlands, Peninj and Olduvai have different tephra records, which limits the possibilities for establishing a regional tephrostratigraphic framework. 相似文献
7.
The Hvalfjördur area, 30 km north of Iceland’s capital Reykjavik, belongs to the sequence of Late Tertiary to early Quaternary flood basalts with minor intercalations of hyaloclastites and rhyolites. The basalts are affected by progressive low-temperature metamorphism, caused by the burial of the lava succession and higher heat flow from nearby central volcanoes. Low-grade zeolite facies metamorphism of basaltic lavas in the Hvalfjördur area results in two distinct mineral parageneses that can be correlated to events in the burial and hydrothermal history of the lava pile. Stage Ia represents syn-eruptive near-surface alteration in which celadonite and silica were precipitated along primary pores. During regional burial metamorphism (stage Ib), hydrolysis of olivine and glass led to the formation of mixed-layer chlorite/smectite clays. The chlorite content of stage Ib phyllosilicate vesicle rims increases with increasing burial depth and temperature. Stage II occurred after the burial and is marked by zeolite mineralization caused by higher heat flow from the Laxárvogur and Hvalfjördur central volcanoes. Altogether 11 different zeolites were found in the Hvalfjördur area: analcime, chabazite, epistilbite, heulandite, laumontite, levyne, mesolite, stilbite, stellerite, thomsonite and yugawaralite. In total, three separate depth and temperature-controlled “zeolite zones” occur in the Hvalfjördur area. 相似文献
8.
Improving the Quality of Municipal Solid Waste Compost by Using Expanded Perlite and Natural Zeolite
The scope of this study was to investigate the effects of natural zeolite and expanded perlite on the quality of municipal solid waste compost. Various ratios of the materials were added as supplements to the organic fraction of municipal solid waste. These applications were periodically compared with an untreated control process. The results obtained from experimental studies clearly showed that municipal solid waste collected from the metropolitan city center of Samsun, Turkey could not be composted without any additions due to the very high moisture content, which reached up to 75–80%. In the untreated control process, thermophilic temperatures were not supported during the composting. In this system, ammonia and other odors became a problem because of the high pH levels, and the electrical conductivity was too high for aged compost. However, the addition of natural zeolite and expanded perlite had a positive affect on the quality of the final compost. Natural zeolite trapped ammonium and reduced nitrogen losses from the compost. Expanded perlite held excess moisture and supported improved aeration. The results also indicated that the use of natural zeolite together with expanded perlite in municipal solid waste composting processes produced mature and stable compost. 相似文献
9.
A. Alberti M. Sacerdoti S. Quartieri G. Vezzalini 《Physics and Chemistry of Minerals》1999,26(3):181-186
The dehydration-rehydration processes and phase transformations of brewsterite (space group P21/m, ideal formula (Sr,Ba)Al2Si6O16·5H2O) were studied by single crystal X-ray diffraction on two samples heated in an evacuated capillary for 24 h at 280°C and
330°C, respectively, and then cooled to room temperature. After the data collection, the capillary of the crystal heated at
280°C was broken, the sample was kept at room conditions for one month, and diffraction data were recollected. Brewsterite
heated in vacuum at 280°C shows a strong decrease of the unit cell volume (about 10%) and the statistical breaking of the
T1-O7-T2 bridge of the 4-ring of the 4254 PBU. T1 cation, in 31% of cases, migrates to a new tetrahedral site, which shares three vertices with the previously occupied
one; the fourth vertex is on the mirror plane, and joins two adjacent layers. T2 cation, in 20% of cases, migrates to a new
site, which is characterized by a 5-fold coordination. This coordination polyhedron shares three vertices with the previously
occupied tetrahedron; the fourth vertex is on the mirror plane, and joins two adjacent layers; the fifth one is unshared.
The formation of these new T-O-T bridges prevents the re-expansion and rehydration of the heated brewsterite; as a consequence,
the crystal brought back to room conditions does not show any noticeable structural difference with respect to that heated
at 280°C. The exchangeable cations, which occupy only one extraframework site in the untreated brewsterite, spread over several
sites. The sample heated at 330°C shows a further decrease in the unit cell volume of about 2% with respect to the sample
heated at 280°C, and an increase in the migration percentage of T1 and T2 cations to the new sites.
Received: 11 November 1997 / Revised, accepted: 26 June 1998 相似文献
10.
