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1.
Quartz‐rich veins in metapelitic schists of the Sanandaj‐Sirjan belt, Hamadan region, Iran, commonly contain two Al2SiO5 polymorphs, and, more rarely, three coexisting Al2SiO5 polymorphs. In most andalusite and sillimanite schists, the types of polymorphs in veins correlate with Al2SiO5 polymorph(s) in the host rocks, although vein polymorphs are texturally and compositionally distinct from those in adjacent host rocks; e.g. vein andalusite is enriched in Fe2O3 relative to host rock andalusite. Low‐grade rocks contain andalusite + quartz veins, medium‐grade rocks contain andalusite + sillimanite + quartz ± plagioclase veins, and high‐grade rocks contain sillimanite + quartz + plagioclase veins/leucosomes. Although most andalusite and sillimanite‐bearing veins occur in host rocks that also contain Al2SiO5, kyanite‐quartz veins crosscut rocks that lack Al2SiO5 (e.g. staurolite schist, granite). A quartz vein containing andalusite + kyanite + sillimanite + staurolite + muscovite occurs in andalusite–sillimanite host rocks. Textural relationships in this vein indicate the crystallization sequence andalusite to kyanite to sillimanite. This crystallization sequence conflicts with the observation that kyanite‐quartz veins post‐date andalusite–sillimanite veins and at least one intrusive phase of a granite that produced a low‐pressure–high‐temperature contact aureole; these relationships imply a sequence of andalusite to sillimanite to kyanite. Varying crystallization sequences for rocks in a largely coherent metamorphic belt can be explained by P–T paths of different rocks passing near (slightly above, slightly below) the Al2SiO5 triple point, and by overprinting of multiple metamorphic events in a terrane that evolved from a continental arc to a collisional orogen. 相似文献
2.
江西省武功山地区浒坑钨矿床的Re-Os年龄及其地质意义 总被引:2,自引:0,他引:2
浒坑钨矿床是位于江西省中部武功山成矿带的大型石英脉型黑钨矿床。为了确定该矿床的成矿时代,笔者选取了浒坑含钨石英脉中与黑钨矿共生的辉钼矿进行了高精度Re-Os同位素定年,并获得5个辉钼矿样品的Re-Os等时线年龄和模式加权平均年龄分别为150.2±2.2Ma和149.82±0.92Ma。测年数据表明浒坑钨矿床的成矿时代为150Ma左右,是华南地区中生代大规模成岩成矿作用高峰期的产物。辉钼矿含铼较低,表明成矿物质可能来自壳源,与形成浒坑花岗岩体的燕山期重熔S型花岗岩岩浆活动有关。该矿床形成于燕山期岩石圈伸展减薄环境。 相似文献
3.
分析表观耗氧量、滴定碱度及总二氧化碳量等资料来研判红海及亚丁湾间之海水交换。结果显示,红海深层水的方解石及霰石饱和度均比亚丁湾和阿拉伯海深层水的饱和度高。红海全水柱之方解石和霰石都处於过饱和状态,亚丁湾和阿拉伯海中各深度之方解石亦呈过饱和状态,但霰石的饱和探度则大约在500m左右。分析深层水之生物体无机碳与有机碳的分解比值,可以发现此地区深层水中,大约有25%的总二氧化碳增加量是由无机碳酸钙溶解而来。 相似文献
4.
Impact of Montmorillonite and Calcite on Release and Adsorption of Cyanobacterial Fatty Acids at Ambient Temperature 总被引:1,自引:0,他引:1
Minerals might act as important sorbents of sedimentary organic matter and reduce biodegradation, which favors the formation of hydrocarbon source rocks in the earth's history. Since most organic matter is degraded during the sinking process, at ambient temperature, it is important to investigate the adsorption capacity of different minerals during this process, to assess the organic loss from primary productivity to sedimentary organic matter. In this study, montmorillonite and calcite have been selected to study the impact of different minerals on the release, adsorption, and deposition of cyanobacterial (Synechococcus elonpata) fatty acids (FAs) at ambient temperature. Gas chromatography (GC), gas chromatography-mass spectrometry (GC-MS) have been utilized to detect the variation in fatty acids. Primary results suggest that minerals have a different impact on dissolved organic matter. Montmorillonite can specifically enhance the release of fatty acids from cyanobacterial cells by lowering the pH values of the solution. The adsorption of the dissolved organic matter by montmorillonite will also be enhanced under a lower pH value. Conjunction of fatty acids with montmorillonite to form a complex will favor the sinking and preservation of these organics. Selective adsorption is observed among fatty acids with different carbon numbers. In contrast, calcite does not show any impact on the release and adsorption of organic matter even though it is reportedly capable of acting as a catalyst during the transformation of organic matter at high temperature. The primary data bridge a link between primary productivity and sedimentary organic matter, suggesting the relative importance of claystones in the formation of hydrocarbon source rocks in the earth's history. 相似文献
5.
6.
Supergene nickel deposits of New Caledonia that have been formed in the Neogene by weathering of obducted ultramafic rocks are controlled by fracture development. The relationship of tropical weathering and tectonic structures, faults and tension gashes, have been investigated in order to determine whether fractures play a passive role only, as previously thought; or alternatively, if brittle tectonics was acting together with alteration. Observation of time‐relationship, textures, and mineralogy of various fracture fills and fault gouges shows that active faulting has played a prominent role not only in facilitating drainage and providing room for synkinematic crystallization of supergene nickel silicate, but also in mobilizing already formed sparse nickel ore, producing the very high grade ore nicknamed “green gold”. 相似文献
7.
微生物对碳酸盐岩的风化作用 总被引:7,自引:0,他引:7
微生物-矿物相互作用可以促进许多表生生物地球化学反应过程,是表生地球化学研究的重要内容。通过综合岩石表面的微生物类群及其地质作用,分析碳酸盐岩微生物风化的各种现象,特别是微观尺度上的各种形态,阐述碳酸盐岩的微生物风化机制与风化产物,笔者提出微生物对碳酸盐岩风化的4种途径:(1)通过微生物在岩石表面和缝隙中生长,导致岩石表层发生生物溶蚀、生物磨蚀和生物钻孔作用,加速岩石风化进程;(2)微生物群体形成的钻孔网络可以增强岩石化学溶蚀的有效表面积并导致其表面强度减弱而促进机械侵蚀作用,微生物对周围岩石颗粒胶结结构的破坏、疏松作用也会导致岩石矿物颗粒的分解;(3)微生物的持水作用,微生物分泌的有机酸以及微生物呼吸所释放的CO2对岩表水分的酸化过程亦加速岩石矿物的分解;(4)微生物生长过程中从岩石内摄取营养元素和产生复杂的有机配体,能促进矿物元素的释放。文中提出在开展微生物对碳酸盐岩风化过程和机理研究的基础上,有必要引入微生物生物技术来综合开发本地低品位含钾磷矿产资源,加速岩溶地区山地土壤的形成与演化。 相似文献
8.
Paleohydrology and paleochemistry of Lake Manitoba,Canada: the isotope and ostracode records 总被引:1,自引:1,他引:0
Lake Manitoba, the largest lake in the Prairie region of North America, contains a fine-grained sequence of late Pleistocene and Holocene sediment that documents a complex postglacial history. This record indicates that differential isostatic rebound and changing climate have interacted with varying drainage basin size and hydrologic budget to create significant variations in lake level and limnological conditions. During the initial depositional period in the basin, the Lake Agassiz phase (12–9 ka), 18O of ostracodes ranged from –16 to –5 (PDB), implying the lake was variously dominated by cold, dilute glacial meltwater and warm to cold, slightly saline water.Candona subtriangulata, which prefers cold, dilute water, dominates the most negative 18O intervals, when the basin was part of proglacial Lake Agassiz. At times during this early phase, the 18O of the lake abruptly shifted to higher values; euryhaline taxa such asC. rawsoni orLimnocythere ceriotuberosa, and halobiont taxa such asL. staplini orL. sappaensis are dominant in these intervals. This positive covariance of isotope and ostracode records implies that the lake level episodically fell, isolating the Lake Manitoba basin from the main glacial lake.18O values from inorganic endogenic Mg-calcite in the post-Agassiz phase of Lake Manitoba trend from –4 at 8 ka to –11 at 4.5 ka. We interpret that this trend indicates a gradually increasing influence of isotopically low (–20 SMOW) Paleozoic groundwater inflow, although periods of increased evaporation during this time may account for zones of less negative isotopic values. The 18O of this inorganic calcite abruptly shifts to higher values (–6) after 4.5 ka due to the combined effects of increased evaporative enrichment in a closed basin lake and the increased contribution of isotopically high surface water inflow on the hydrologic budget. After 2 ka, the 18O of the Mg-calcite fluctuates between –13 and –7, implying short-term variability in the lake's hydrologic budget, with values indicating the lake varied from outflow-dominated to evaporation-dominated. The 13C values of Mg-calcite remain nearly constant from 8 to 4.5 ka and then trend to higher values upward in the section. This pattern suggests primary productivity in the lake was initially constant but gradually increased after 4.5 ka.This is the sixth in a series of papers published in this issue on the paleolimnology of arid regions. These papers were presented at the Sixth International Palaeolimnology Symposium held 19–21 April, 1993 at the Australian National University, Canberra, Australia. Dr A. R. Chivas served as guest editor for these papers. 相似文献
9.
10.
Albite vein formation during exhumation of high-pressure terranes: a case study from alpine Corsica 总被引:1,自引:0,他引:1
The formation of late‐stage veins can yield valuable information about the movement and composition of fluids during uplift and exhumation of high‐pressure terranes. Albite veins are especially suited to this purpose because they are ubiquitously associated with the greenschist facies overprint in high‐pressure rocks. Albite veins in retrogressed metabasic rocks from high‐pressure ophiolitic units of Alpine Corsica (France) are nearly monomineralic, and have distinct alteration haloes composed of actinolite + epidote + chlorite + albite. Estimated P–T conditions of albite vein formation are 478 ± 31 °C and 0.37 ± 0.14 GPa. The P–T estimates and petrographic constraints indicate that the albite veins formed after the regional greenschist facies retrogression, in response to continued decompression and exhumation of the terrane. Stable isotope geochemistry of the albite veins, their associated alteration haloes and unaltered hostrocks indicates that the vein‐forming fluid was derived from the ophiolite units and probably from the metabasalts within each ophiolite slice. That the vein‐forming fluid was locally derived means that a viable source of fluid to form the veins was retained in the rocks during high‐pressure metamorphism, indicating that the rocks did not completely dehydrate. This conclusion is supported by the observation of abundant lawsonite at the highest metamorphic grades. Fluids were liberated during retrogression via decompression dehydration reactions such as those that break down hydrous high‐pressure minerals like lawsonite. Albite precipitation into veins is sensitive to the solubility and speciation of Al, which is more pressure sensitive than other factors which might influence albite vein formation such as silica saturation or Na:K fluid ratios. Hydraulic fracturing in response to fluid generation during decompression was probably the main mechanism of vein formation. The associated pressure decrease with fracturing and fluid decompression may also have been sufficient to change the solubility of Al and drive albite precipitation in fracture systems. 相似文献