排序方式： 共有124条查询结果，搜索用时 234 毫秒
1.
Lutz Nasdala Wolfgang Hofmeister Nicholas Norberg James M. Martinson Fernando Corfu Wolfgang Dörr Sandra L. Kamo Allen K. Kennedy Andreas Kronz Peter W. Reiners Dirk Frei Jan Kosler Yusheng Wan Jens Götze Tobias Häger Alfred Kröner John W. Valley 《Geostandards and Geoanalytical Research》2008,32(3):247-265
We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for 206pb/238U and 0.7392 ± 0.0003 for 207pb/235U. Its 206pb/238U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 1018 g?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn. 相似文献
2.
Guillermo Booth-Rea Jos Fernando Simancas Antonio Azor Jos Miguel Azan Francisco Gonzlez-Lodeiro Paulo Fonseca 《Comptes Rendus Geoscience》2006,338(16):1260-1267
Multi-equilibrium thermobarometry shows that low-grade metapelites (Cubito-Moura schists) from the Ossa–Morena Zone underwent HP–LT metamorphism from 340–370 °C at 1.0–0.9 GPa to 400–450 °C at 0.8–0.7 GPa. These HP–LT equilibriums were reached by parageneses including white K mica, chlorite and chloritoid, which define the earliest schistosity (S1) in these rocks. The main foliation in the schists is a crenulation cleavage (S2), which developed during decompression from 0.8–0.7 to 0.4–0.3 GPa at increasing temperatures from 400–450 °C to 440–465 °C. Fe3+ in chlorite decreased greatly during prograde metamorphism from molar fractions of 0.4 determined in syn-S1 chlorites down to 0.1 in syn-S2 chlorites. These new data add to previous findings of eclogites in the Moura schists indicating that a pile of allochtonous rocks situated next to the Beja-Acebuches oceanic amphibolites underwent HP–LT metamorphism during the Variscan orogeny. To cite this article: G. Booth-Rea et al., C. R. Geoscience 338 (2006). 相似文献
3.
Renaud Denoyel 《Comptes Rendus Geoscience》2002,334(9):689-702
The applications of calorimetric and ellipsometric methods to the understanding of adsorption phenomena occurring at the solid–liquid interface are presented with examples in the field of surfactant adsorption. The various experimental approaches are presented and compared, i.e., immersion calorimetry, titration calorimetry and liquid flow calorimetry. It is shown how they can be used to follow, in situ, the building steps of the surfactant adsorbed layer. On the other hand, ellipsometry allows the adsorption isotherm, the adsorption kinetics as well as the thickness of the adsorbed layer to be determined on well-defined flat surfaces. To cite this article: R. Denoyel, C. R. Geoscience 334 (2002) 689–702. 相似文献
4.
《水文科学杂志》2013,58(5)
Abstract Some unique coupled wind–water erosion processes exist in the desert-loess transitional zone in the middle Yellow River basin. Based on data from 40 stations on 29 rivers, a study was made on the influence of such processes on suspended sediment grain-size characteristics of the tributaries of the Yellow River. Results show that the percentage of >0.05-mm grain size decreases with the increased annual mean precipitation, but increases with the increase in the annual mean number of sand-dust storm days. The percentage of <0.01-mm grain size increases with the increase in the annual mean precipitation, but decreases with the increase in the annual number of sand-dust storm days. Based on annual mean data from 40 stations, multiple regression equations were established between the percentages of >0.05-mm grain size (r >0.05) and <0.01-mm grain size (r <0.01), annual mean precipitation (P m) and annual mean number of sand-dust storm days (D ss). On this basis, the relative contributions of the variations in D ss and P m to the variation in r >0.05 and r <0.01 were estimated. The results indicate that the variation in sand-dust storm frequency exerts greater influences on the variation in grain-size characteristics of suspended load than does the variation in annual mean precipitation. With the increase in the coupled wind–water processes index, expressed by P m/D ss, the percentage of >0.05-mm grain size in suspended sediment decreases and the percentage of <0.01-mm grain size increases. With the variation in P m/D ss, different combinations of r >0.05 with r <0.01 appear, which have some influence on the formation of hyperconcentrated flows. There exist some optimal ratios of coarse to fine fractions in suspended sediment that make sediment concentrations of hyperconcentrated flows the highest. The optimal r >0.05/r <0.01 value is related to some range of the index P m/D ss. When the P m/D ss index falls in this range, the optimum combination of relative coarse with fine sediments in the suspended load appears, and thus results in the peak values of sediment concentration. 相似文献
5.
大规模伸展构造是华北克拉通东部岩石圈减薄的重要表现形式。部分低角度韧性剪切带是地壳伸展变形后所展现的构造形式。本文研究了王格庄韧性剪切带的岩石学、几何学、运动学等特征显示:韧性剪切带走向近南北向,剪切带断层面倾向多变(倾向西、西南、西北方向)。大部分区域面理低角度倾向西,矿物拉伸线理近东西向,不对称旋转碎斑及S-C组构指示顶端指向西的剪切特征。结合研究区西侧与伸展构造相匹配的半地堑伸展盆地证据:本研究认为伸展构造的形成可能与西太平洋板块的后撤相关,即大规模伸展构造作用引发了华北克拉通东部的地壳减薄作用。 相似文献
6.
Determination of Ga,Ge, Mo,Ag, Cd,In, Sn,Sb, W,Tl and Bi in USGS Whole‐Rock Reference Materials by Standard Addition ICP‐MS 
下载免费PDF全文
下载免费PDF全文 Richard M. Gaschnig Roberta L. Rudnick William F. McDonough 《Geostandards and Geoanalytical Research》2015,39(3):371-379
A procedure for determining a wide range of chalcophile and siderophile elements in typical crustal rocks using standard addition and ICP‐SFMS (inductively coupled plasma sector field mass spectrometry) is presented. New results for Ga, Ge, Mo, Ag, Cd, In, Sn, Sb, W, Tl and Bi abundances in USGS whole‐rock reference materials AGV‐2, BHVO‐1, BIR‐1, G‐2, GSP‐1 and W‐2 are reported using this analytical procedure. Intermediate precision of means based on multiple dissolved aliquots of each USGS reference material was 10% RSD or better for Ga, Ge, In and Sn in all, and similarly good for Ag, Cd, Sb, Tl and Bi in most reference materials. Poorer intermediate precision of Mo and W measurements in several reference materials is probably due to higher analytical blanks on these elements and powder heterogeneity due to a sulfide‐related nugget effect in the specific case of Mo in GSP‐1. Results for all elements fell within the range of available published data with the exception of Ag, which yielded systematically higher concentrations than found in the literature for five of the six reference materials, likely reflecting interference from unresolved polyatomic species. 相似文献
7.
中国土壤湿度的时空变化特征 总被引：3，自引：1，他引：2
基于中国155个农业气象观测站1981-2010年逐旬土壤湿度资料,分析了全国和12个气候区域0~50 cm逐层的土壤湿度时空分布规律,采用趋势分析和Cramér-von Mises（CVM）方法探究了土壤湿度的变化趋势及突变性。结果表明：西南、江淮、东北、江南、江汉、黄淮和华南地区各层土壤湿度均高于全国平均值,内蒙古地区最低;随着深度增加,西南地区土壤湿度增加最明显,仅青藏高原地区土壤湿度减小。不同区域0~50 cm各层土壤湿度年变化和季节变化差异明显,并具有阶段性特征,大部地区深层土壤湿度高于浅层;总体上,新疆、华南、华北、青藏高原、东北、黄淮地区1981-2010年土壤湿度减小趋势显著,其中新疆地区减小最为明显。除江淮地区外,各区域土壤湿度均存在较为明显的年际差异,突变时段主要集中在20世纪80年代后期至90年代初期、90年代后期两个时间段。 相似文献
8.
南天山区域大地构造与演化 总被引：27，自引：0，他引：27
塔里木和中天山之间的南天山造山带,经历了复杂的构造演化与地壳增生过程。综合分析南天山造山带的构造、地层、古生物、岩石、地球化学和同位素年代学等方面的资料,特别是放射虫、蛇绿岩、蓝片岩等方面的最新研究成果,讨论了南天山的区域构造格局和演化过程。南天山主体为一上百公里宽的增生-碰撞混杂带-南天山(蛇绿)混杂带;其北侧为中天山岛弧,是仰冲壳楔;南侧为塔里木陆块,是俯冲壳楔。古南天山洋为一广阔的大洋,南天山碰撞造山作用起始于二叠纪末-三叠纪初,新近纪-第四纪进入陆内造山作用阶段。 相似文献
9.
东昆仑可支塔格蛇绿混杂岩的地质地球化学特征 总被引：1，自引：0，他引：1
东昆仑可支塔格蛇绿混杂岩属于木孜塔格-鲸鱼湖大断裂的西延部分,主要由辉橄岩、辉长岩、闪长岩、斜长花岗岩、辉绿岩、玄武岩及硅质岩等组成,形成时代为早石炭世。为构造强烈破坏的蛇绿混杂岩,形成于俯冲带环境,属SSZ型蛇绿岩。其中辉橄岩以相对低SiO2、TiO2、Al2O3和CaO、高MgO为特征,贫有色金属成矿元素,富集相容元素Cr、Ni、Co。稀土总量低,接近于球粒陨石稀土元素总量,以LREE略富集为特征。闪长岩SiO2、K2O含量较低,MgO、CaO、Na2O较高,稀土总量高,∑REE为90.95μg/g,LREE富集。斜长花岗岩SiO269.8%,Na2O>K2O,K2O/Na2O为0.78,A/CNK为1.68,具有大洋斜长花岗岩的岩石化学特征。闪长岩、斜长花岗岩的微量元素特征相似,表现为大离子亲石元素K、Sr、Rb、Ba相对富集,高场强元素Nb、Ta、Zr、Hf相对亏损。研究表明,辉橄岩来源于亏损的地幔岩,接近于强烈亏损的方辉橄榄岩,而明显不同于结晶分异作用成因的超镁铁质岩石。闪长岩、斜长花岗岩为蛇绿混杂岩的浅色岩组分,是地幔岩浆结晶分异的产物。 相似文献
10.
Hélène Balcone‐Boissard Agnès Michel Benoît Villemant 《Geostandards and Geoanalytical Research》2009,33(4):477-485
Concentrations of halogens (fluorine, chlorine, bromine and iodine) were determined in six geochemical reference materials (BHVO‐2, GS‐N, JG‐1, JR‐1, JB‐1b, JB‐2). Halogens were first extracted from powdered samples using a pyrohydrolysis technique, then hydrolysis solutions were analysed by ion chromatography for F and Cl and inductively coupled plasma‐mass spectrometry for Br and I. The detection limits in solutions were 100 μg l?1 for both F and Cl and 10 ng l?1 for Br and I. Considering the extraction procedure, performed on a maximum of 500 mg of sample and producing 100 ml of pyrohydrolysis solution, detection limits in rock samples were 20 mg kg?1 for F and Cl and 2 μg kg?1 for Br and I. The mean analytical errors on the studied composition ranges were estimated at 10 mg kg?1 for F and Cl, 100 μg kg?1 for Br and 25 μg kg?1 for I. The concentration values, based on repeated (generally > 10) sample analysis, were in good agreement generally with published values and narrowed the mean dispersion around mean values. Large dispersions are discussed in terms of samples heterogeneity and contaminations during sample preparation. Basaltic RMs were found to be more suitable for studies of halogen compositions than differentiated rock material, especially granites – the powders of which were heterogeneous in halogens at the 500 mg level. 相似文献