Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Muon density measurements with the KASCADE central detector     

《Astroparticle Physics》2002,16(4):183-386

Frequency distributions of local muon densities in high-energy extensive air showers (EAS) are presented as signature of the primary cosmic ray energy spectrum in the knee region. Together with the gross shower variables like shower core position, angle of incidence, and the shower sizes, the KASCADE experiment is able to measure local muon densities for two different muon energy thresholds. The spectra have been reconstructed for various core distances, as well as for particular subsamples, classified on the basis of the shower size ratio N_μ/N_e. The measured density spectra of the total sample exhibit clear kinks reflecting the knee of the primary energy spectrum. While relatively sharp changes of the slopes are observed in the spectrum of EAS with small values of the shower size ratio, no such feature is detected at EAS of large N_μ/N_e ratio in the energy range of 1–10 PeV. Comparing the spectra for various thresholds and core distances with detailed Monte Carlo simulations the validity of EAS simulations is discussed.  相似文献   

关于高速滑坡的几个问题     

冯希杰  张骏 《地球科学与环境学报》1987,(4)

高速滑坡问题是当前工程地质和环境地质学界极为关注的问题。本文对诸如滑体高速滑动所对应的时空界限、滑体滑动过程所产生的热效应以及空气浮托力等高速滑坡产生机制问题进行了初步探讨。  相似文献   

EUV and coronagraphic observations of coronal mass ejections     

Durgesh Tripathi 《Journal of Astrophysics and Astronomy》2006,27(2-3):193-200

The Large Angle Spectrometric Coronagraph (LASCO) and Extreme-ultraviolet Imaging Telescope (EIT) onboard Solar and Heliospheric Observatory (SOHO) provide us with unprecedented multi-wavelength observations helping us to understand different dynamic phenomena on the Sun and in the corona. In this paper we discuss the association between post-eruptive arcades (PEAs) detected by EIT and white-light coronal mass ejections (CMEs) detected by LASCO/C2 telescope.  相似文献   

A charge-coupled device study of high-latitude Galactic structure: testing the model parameters     

S. Karaali  S. G. Ak  S. Bilir  Y. Karata&#;  G. Gilmore † 《Monthly notices of the Royal Astronomical Society》2003,343(3):1013-1024

  相似文献   

New evidence for a linear colour–magnitude relation and a single Schechter function for red galaxies in a nearby cluster of galaxies down to M*+ 8     

S. Andreon  J.-C. Cuillandre  E. Puddu  Y. Mellier 《Monthly notices of the Royal Astronomical Society》2006,372(1):60-68

  相似文献   

The Roche Limit     

I. P. Williams 《Celestial Mechanics and Dynamical Astronomy》2003,87(1-2):13-25

The role of tides in deforming and possibly disrupting a secondary body orbiting about a primary body has been known for a considerable time. This was first inspired by the observations of ocean tides on Earth and then seen as playing an important role in the formation and evolution of the Earth–Moon system. Finally, in the beginning of the 20th century it was generally thought to have a significant role in the formation of the solar system through the tidal disruption of the Sun. Here, an overview of the historical developments of the ideas concerned with tidal disruption of a secondary body that can lead to mass loss is given. Some discussion of possible extensions to consider more realistic situations where the secondary body may not be moving on a circular orbit and may not rotate so as to maintain the phase-on configuration to the primary body is also given.  相似文献   

板翅式换热器综合性能优化的设计方法     

高俊忠  陈维汉 《广东海洋大学学报》2003,23(6):45-49

应用给定换热器结构材料而使换热量最大的两侧换热表面的最佳匹配准则和使可用能损失率最小的最佳运行参数准则。利用两个准则间的关系 ,采用迭代的方式完成换热器的优化设计 ,使换热器的设计达到材料省、换热效果好及运行费用低的目的 ,且能在设计阶段实现。  相似文献   

柴达木盆地东北缘古元古代变质镁铁—超镁铁质岩的地质特征及成因探讨     

王毅志  梁超云 《青海国土经略》2001,(Z1)

1:5万区域地质调查工作中,在柴达木陆块北缘首次发现古元古代变质镁铁—超镁铁质岩,获得成岩年龄为1952±15Ma,其岩石化学、地球化学特征反映出岩浆来源于亏损地幔,反映出该地区克拉通在古元古代(19亿年)发生了一次强烈的裂解(洋)事件,对于研究柴达木盆地北缘元古代结晶基底地质构造演化及进一步探讨柴达木盆地的起源及构造演化过程提供了重要地质线索。  相似文献   

Evolution of the luminosity function and colours of galaxies in a Λ cold dark matter universe     

K. Nagamine †  M. Fukugita  R. Cen  J.P. Ostriker 《Monthly notices of the Royal Astronomical Society》2001,327(1):L10-L14

The luminosity function of galaxies is derived from a cosmological hydrodynamic simulation of a Λ cold dark matter universe with the aid of a stellar population synthesis model. At     , the resulting B -band luminosity function has a flat faint-end slope of     with the characteristic luminosity and the normalization in fair agreement with observations, while the dark matter halo mass function is steep with a slope of     . The colour distribution of galaxies also agrees well with local observations. We also discuss the evolution of the luminosity function, and the colour distribution of galaxies from     to 5. A large evolution of the characteristic mass in the stellar mass function as a result of number evolution is compensated by luminosity evolution; the characteristic luminosity increases only by 0.8 mag from     to 2, and then declines towards higher redshift, while the B -band luminosity density continues to increase from     to 5 (but only slowly at     .  相似文献