Measurement of the total nitrogen in lake sediments： Comparison and its environmental significance     

Wei JIANG Xinqing LEE 《中国地球化学学报》2006,25(B08):12-12

Nitrogen cycle is an important bio-geochemical process in the environment. Measurement of the total nitrogen （TN） is a routine experiment in agriculture, biology and environmental sciences. The Kjeldahl method （KM） and elemental analyzer method （EA） are both commonly used to determine TN. Total nitrogen by EA is the sum of nitrate （NO3）, nitrite （NO2）, organic nitrogen and ammonia. Total nitrogen by KM （TKN） is made up of both organic nitrogen and ammonia. A comparative study focused on the two methods is conducted by analysis of TN in 97 samples from the sediment sequence of Gouchi, a salt lake in North China. KM presents a higher degree of accuracy than EA with a standard deviation of 0.007 vs. 0.024. With the presence of nitrate and/or nitrite nitrogen, however, measurement by KM is considerably lower than that by EA. Therefore, for samples from lake sediment sequences or soils in North China, KM is inapplicable to determining TN because of usually high contents of nitrous salt. Despite the inconsistency, use of both methods to the same samples makes sense in reconstructions of climatic and environmental changes from lake sediments. In Lake Gouchi, the contents of nitrate and nitrite nitrogen vary from 1.40% in the lower part of the sequence to 14.77% in the uppermost part, suggesting a gradual evolution process from a fresh water lake to the present-day salt lake.  相似文献   

Statistical tests for regional seismic phase characterizations   总被引：1，自引：0，他引：1  

L. Persson 《Journal of Seismology》2003,7(1):19-33

In seismic analysis some assumptions are often made aboutthe data, e.g. stationarity and Gaussianity. This is not obvious for all realseismic data. Here, we use statistical tests for characterization of regionalseismic data. We apply tests for stationarity, symmetry, linearity, andtime-reversibility. In the analysis we use twelve regional seismic events inFennoscandia recorded with the seismic small-aperture arrays NORESS,ARCESS and FINESA at hypocentral distances in the range from 160 to1580 km. For the tests we use the regional phases Pn, secondary P, Sn and Lg-phases and the preceding noise. Two of the eventsare explosions, two are rockbursts and eight are earthquakes. Theperformance and possibilities of using statistical tests based on bispectra, asa complementary tool for conventional analysis of seismic phases isdemonstrated. The preceding noise recorded before the first onset of theP-wave for the twelve events is tested to be spatially stationarybetween each channel within each array and temporal stationary in 21consecutive time windows of 3.2 sec each. Also, the preceding noise issymmetric and linear. The seismic phases defined by the symmetry test asnon-Gaussian (not symmetric) are all linear. This means a linear model canbe used to characterize both the noise and the phases. The first P-phase for the two explosions is characterized as non-Gaussian at thethree arrays. For all 36 possibly first P-phase arrivals at the three arraystations, 23 are non-Gaussian. The second P-phase is non-Gaussian at13 of 36 data records, the S-phase at eleven of 36 and the Lg-phase at nine of 36. For all the four phases more than 32 of possible36 are time-reversible.  相似文献   

一种新的多通道GPS共视资料的处理算法   总被引：2，自引：0，他引：2  

卢晓春  杨旭海  李孝辉  胡永辉 《武汉大学学报(信息科学版)》2003,28(6):736-739

提出了一种按仰角加权的多通道GPS共视资料处理算法，充分利用了所有观测数据，同时抑制了多径等因素影响，从而可提高共视比对精度。对日本邮政省通讯研究所(CRL)和国家授时中心(NTSC)2002年5月～2003年3月的多通道共视比对的处理结果表明，新的处理算法结果更接近真实钟差。  相似文献   

自动电位滴定仪应用于测定海洋沉积物中有机碳的可行性研究   总被引：1，自引：1，他引：0  

王兵  高丰蕾  杨佩华  孙承君  韩彬 《岩矿测试》2016,35(4):402-408

自动电位滴定仪具有操作简便、测定速度快的优势,减少了人为操作的影响,本文使用自动电位滴定仪测定海洋沉积物中有机碳的含量,并与国家标准(GB 17378.5—2007)中根据滴定过程中溶液颜色变化用肉眼判定滴定终点的方法进行了对比分析,确定通过仪器自动判断滴定终点实现准确测定的可行性。结果表明:自动电位滴定的方法检出限为0.029%,人工肉眼判定终点的方法检出限为0.086%,在滴定终点判定方面两种方法无显著性差异,但自动电位滴定仪的准确度和精密度更优,在一定程度上可代替肉眼判定滴定终点。实际应用过程中也发现,当滴定的溶液体系由于氧化还原反应、络合作用等影响因素使电位变化较为复杂时,自动电位滴定仪有可能会得到多个等当点而无法判断哪个等当点是真正的目标等当点,此时需要利用肉眼进行辅助确定。  相似文献   

利用LA-ICP-MS在16 μm和10 μm激光束斑条件下测定独居石U-Th-Pb年龄     

汪双双  韩延兵  李艳广  魏小燕  靳梦琪  程秀花 《岩矿测试》2016,35(4):349-357

我国锂钾主要矿产资源大多分布在西部偏远地区,其勘查找矿或综合利用迫切需要现场快速分析技术的支持。本文介绍了自行开发的便携式Li-K分析仪的主要性能及其在锂辉石中锂的分析应用。Li-K分析仪是一种基于大气压的液体阴极辉光放电光谱仪,以待测液体为放电阴极,实现样品中Li、K等元素的原子化和激发。该仪器以光纤传导CCD光谱仪作为检测器,其波长范围为345～1015 nm,分辨率3 nm;以Li 670.78 nm和K 769.90 nm分析谱线,在最佳仪器工作条件下测定Li、K的精密度（RSD,n=14）均低于2%,检出限为0.03 μg/mL,检测范围0.1～10 μg/mL。研究表明,不同酸度和酸的类型对谱线强度影响较大,且存在显著的样品基体效应,标准曲线法分析锂辉石中Li的结果偏差高达267%;而标准加入法可克服基体效应的影响,获得与ICP-OES一致性较好的分析结果,为现场开展固体样品中Li的测定奠定了基础。  相似文献   

Step-frequency radar applied on thin road layers     

X. Drobert  C. Fauchard  Cte  E. Le Brusq  E. Guillanton  J. Y. Dauvignac  Pichot 《Journal of Applied Geophysics》2001,47(3-4)

In the field of road construction and maintenance, the need for information on the thickness of very thin road layers is not satisfied by means of commercial pulse GPR, due to the inability of such devices to operate over ranges of several gigahertz. As a result, research has focused on the design of a step-frequency radar technique, able to work with very high-frequency synthetic pulses.An ultrawide band antenna, belonging to the family of Vivaldi antennas, has been developed for road applications. It has been created using stripline technology and yields a band width greater than one decade. During an initial step, this antenna was tested on various bituminous concrete samples with a network analyzer. Different parameters were studied, including band width, offset between antennas, and height and shape of the frequency-dependent pulse.A second step involved GPR dynamic measurements. A customized software program enabled recording data from the network analyzer. Several radar profiles were developed from selected road construction and maintenance test sites (e.g. the Circular Pavement Fatigue Test Track, composed of a number of known structures). Results show improved resolution when compared to a commercial impulse GPR system.  相似文献   

Automatic onset phase picking for portable seismic array observation   总被引：1，自引：0，他引：1  

王继陈九辉  刘启元李顺成 郭飚 《地震学报(英文版)》2006,19(1):44-53

Automatic phase picking is a critical procedure for seismic data processing, especially for a huge amount of seismic data recorded by a large-scale portable seismic array. In this study is presented a new method used for automatic accurate onset phase picking based on the proporty of dense seismic array observations. In our method, the Akaike＇s information criterion （AIC） for the single channel observation and the least-squares cross-correlation for the multi-channel observation are combined together. The tests by the seismic array observation data after triggering with the short-term average/long-term average （STA/LTA） technique show that the phase picking error is less than 0.3 s for local events by using the single channel AIC algorithm. In terms of multi-channel least-squares cross-correlation technique, the clear teleseismic P onset can be detected reliably. Even for the teleseismic records with high noise level, our algorithm is also able to effectually avoid manual misdetections.  相似文献   

多目标地球化学调查土壤样品中氮和碳的快速测定   总被引：2，自引：1，他引：2  

于兆水  胡外英张勤 《岩矿测试》2007,26(3):235-237

详细研究了元素分析仪的工作条件，建立了直接固体进样同时测定多目标地球化学调查土壤样苎支氮、碳的方法。方法简便、快速，检出限为氮14．5μg／g、碳0．013％。经土壤国家一级标准物质分析验证，测定值与标准值相符，精密度（RSD，n=12）为氮1．49％-3．27％、碳0.64％～3.63％。  相似文献   

云南天文台太阳光谱望远镜偏振分析器检验     

钟树华  顾啸马  张霄宇  陈学昆 《天文研究与技术》1998,(3)

介绍了利用云南天文台水平式太阳光谱仪对太阳光谱望远镜偏振分析器进行检验的情况。检验得到的太阳黑子Ｉ、Ｑ、Ｕ、Ｖ四个斯托克斯轮廓与理论轮廓的特征相近,表明该偏振分析器达到了设计要求,用它可以获得太阳黑子的所有斯托克斯参量。  相似文献   

Prediction of Shale Gas Pressure based on Multi-channel Seismic Inversion in Fuling     

XING Lei  LI Yu  LI Qianqian  LIU Yaowen  WAN Yunqiang  YANG Huiliang 《《地质学报》英文版》2022,96(4):1237-1245

The accurate prediction of formation pressure is important in oil/gas exploration and development. However, the achievement of this goal remains challenging, due to insufficient logging data and the low predictive data accuracy from seismic data. In this work, a case study was carried out in the Baima area of Wulong, in order to develop a workflow for accurately predicting shale gas formation pressure. The multi-channel stack method was first used, as well as the inversion of single-channel seismic data, to construct velocity and density models of the formation. Combined with the existing well-logging data, the velocity and density models of the whole well section were established. The shale gas formation pressure was then estimated using the Eaton method. The results show that the multi-channel seismic stacking method has a higher accuracy than the inversion of the formation velocity obtained by the single-channel seismic method. The discrepancies between our predicted formation pressure and the actual formation pressure measurement are within an acceptable range, indicating that our workflow is effective.  相似文献