吉林露水河硅藻土在煅烧中的结构及性能的变化   总被引：1，自引：0，他引：1  

张旭  李殿超  王安平  于洪林 《世界地质》2003,22(4):376-379

应用X射线衍射、红外光谱分析、扫描电镜及化学分析方法对吉林露水河硅藻土在煅烧中的结构及性能的变化进行研究，结果表明：高温时蛋白石转变成方英石，激烈的相变温度为1160℃左右；当温度在1100℃～1200℃时，硅藻的微孔开始阻塞或消失，并出现开裂现象，硅藻的结构变得模糊，但硅藻仍保持其外形；室温～600℃，比表面积逐渐增加，600℃～1200℃比表面积则减少；室温～700℃时，pH值逐渐减小，700℃～1200℃时，pH值则逐渐增加。  相似文献   

Weathering: Toward a Fractal Quantifying   总被引：1，自引：0，他引：1  

Klaudia Oleschko  Jean-Francois Parrot  Gerardo Ronquillo  Sergey Shoba  Georges Stoops  Vera Marcelino 《Mathematical Geology》2004,36(5):607-627

Weathering occurs over a wide range of scales. To link features through these scales is a major challenge for interdisciplinary weathering studies. Fractal approach seems to be specially useful for this purpose. We introduce a multistep fractal weathering assessment scheme devoted to extract fractal weathering classifiers from texture analysis of the mineral's image. Our scheme enables to quantitatively estimate the global and local information about the geometry of the weathering pattern. This information is basic to develop geometrical indices of weathering, which can significantly enrich the common qualitative and semiquantitative weathering assessment schemes. To justify the fractal approach, a strong statistical self-similarity has been documented for both the weathering and fresh features of two common silica minerals: quartz and biogenic A-opal (phytolith) over four orders of length scales. The procedure is fast, drastically reduces thresholding bias, promises to be universal, it is valid for genetically different minerals and rock types, scale independent, and specially useful for monitoring the changes in the mineral's roughness during the alteration. Two of the proposed classifiers seem to be potentially useful for direct application in the field and be used by nonspecialist.  相似文献   

古环境研究中深海沉积物粒度测试的预处理方法   总被引：12，自引：1，他引：11  

谢昕  郑洪波  陈国成  梅西 《沉积学报》2007,25(5):684-692

对深海沉积物样品进行粒度测试前,应根据研究目的,在预处理过程中有效去除碳酸盐和生物硅,同时完好保留陆源碎屑组分,才能使测试结果准确反映古气候和古环境变化。对采于南海的样品分别加入不同剂量浓度为10％的盐酸或浓度为25％的醋酸,以及不同剂量的NaOH或Na2CO3,同时利用有机元素分析仪、硅钼蓝比色法、环境扫描电子显微镜分析、观察不同方法的预处理效果,并结合粒度测试的结果认为,对于碳酸盐,盐酸和醋酸均可将其有效去除,但由于少量盐酸仍会对陆源矿物组分造成破坏,因此应使用酸性较弱的醋酸;对于生物硅,大剂量的Na2CO3仍难将其有效去除,而使用小剂量的NaOH即可去除干净,但需控制剂量以避免破坏矿物组分。针对南海沉积物中的各种生物组分含量,确定了醋酸和NaOH的使用剂量并建立了预处理流程。  相似文献   

南海北部一百万年以来的表层古生产力变化：来自ODP1144站的蛋白石记录   总被引：7，自引：1，他引：6  

李建  王汝建 《地质学报》2004,78(2):228-233

通过南海北部ODP 1144站蛋白石含量测定及其堆积速率的计算,并结合氧同位素记录等相关资料,获得南海北部1050ka以来高分辨率的表层古生产力变化与冰期旋回和东亚季风的关系。约900ka以来,蛋白石含量及其堆积速率较900ka以前明显增加,反映了“中更新世革命”事件之后,全球气候变冷,并导致表层生产力的提高。由于第四纪冰期旋回中的冬、夏季风的加强,加上1144站特殊的地理位置,使该站在冰期时表层生产力增加,间冰期时表层生产力降低。浮游有孔虫氧同位素记录与蛋白石含量及其堆积速率的时间序列频谱分析结果显示,三者均出现了相对应的偏心率周期、斜率周期和岁差周期,说明该站表层生产力的变化主要受地球轨道周期的驱动。  相似文献   

A late Pliocene diatom Ge/Si record from the Southeast Atlantic   总被引：1，自引：0，他引：1  

Hui-Ling Lin  Chiau-Ju Chen 《Marine Geology》2002,180(1-4):151-161

As a result of both culture and sediment core studies, the ratio of germanium (Ge) to silicon (Si) in diatom shells has been proposed as a proxy for monitoring whole-ocean changes in seawater Ge/Si, a ratio affected by changes in continental weathering. However, because of the difficulties of extracting and cleaning diatom frustules from deep-sea sediments, only samples from highly pure diatom oozes in the Antarctic region have been previously analyzed. Here we present data on diatom Ge/Si ratios, (Ge/Si)_opal, for the time interval between 3.1 and 1.9 Ma from a mid-latitude, coastal upwelling area where significant terrigenous sediment input complicated the sample processing and analyses. In general, our (Ge/Si)_opal values show the same decreasing trend after 2.6 Ma than previously measured in Antarctic sediments (Shemesh et al., 1989. Paleoceanography 4, 221–231), but with a noisier background that may reflect the local imprint of proximal continental input superimposed upon global changes in the ocean reservoir. The time of initiation of large-scale North Hemisphere glaciation at 2.6 Ma is characterized by a declining pattern of diatom Ge/Si ratios, which could have resulted from a global increase in the input of riverine Si due to enhanced silica weathering and/or equatorward (northward) intrusions of subantarctic waters enriched in silica. High (Ge/Si)_opal ratios are associated with high opal contents from the same sediment samples and with warm climate as indicated by depleted benthic foraminiferal δ¹⁸O values from the North and Equatorial Atlantic. Cold periods signified by enriched benthic δ¹⁸O values, on the contrary, are associated with lower (Ge/Si)_opal ratios. We interpret diatom Ge/Si values to reflect the prevailing weathering state on the continents, with greater chemical weathering during warm and wet periods of the Pliocene and less during cooler and drier intervals.  相似文献   

植硅体形态测量学研究与应用概述     

顾延生  季雅斌  管硕  刘红叶  米雨川  王翰林  李仁成 《第四纪研究》2019,39(1):12-23

植硅体形态测量学是植硅体研究的重要方向之一,随着学科交叉研究的深入,植硅体形态测量学在植物分类与生态学、环境考古学、全球变化与生态响应等领域得到快速发展。综合已有研究成果表明,长鞍型植硅体形态测量学在日本、中国的竹亚科属一级竹类生态学具有独特的指示作用,而扇型和长鞍型形态测量学在中国西南西双版纳竹亚科木本竹子属一级分类中具有重要的参考价值;稻亚科扇型形态测量学可以有效区分籼稻与粳稻,且扇型鱼鳞状纹饰与颖壳双峰植硅体形态测量学结合可以准确判别亚洲栽培稻与普通野生稻;黍亚科树状表皮长细胞形态测量学被成功运用到区分中国西北黍和粟及其亲缘物种的关系,葫芦科南瓜属刻面球型植硅体形态测量学揭示了野生种、半驯化种和驯化种之间植硅体形态大小及其关系,证实南美洲低地地区早全新世出现的南瓜驯化历史;中国东北不同环境条件下的禾本科羊草、芦苇植硅体形态测量学研究反映了陆生植物对全球变化的生理生态响应,为研究陆地生态系统对全球变化的响应及古环境重建提供了重要参考。  相似文献   

东北地区湿度梯度下的表土植硅体的空间分布规律     

刘洪妍  王海南  介冬梅  刘利丹  高桂在  李德晖  李楠楠  冷程程  李晨露 《第四纪研究》2019,(1):76-88

植硅体的现代过程研究是恢复古环境的基础,探讨表土植硅体分布及组合特征对环境因子的响应尤为重要。沿中国东北地区年均温为4 ℃等温线采集70块表土样品,研究了单一温度因素控制下表土植硅体的空间分布规律,以期获得不同类型植硅体对降水的响应。研究结果表明:所有表土样品中植硅体丰富且数量较多,主要有棒型、尖型、块状、扇型、扁平状、短鞍型、帽型、哑铃型、齿型、三棱柱型、导管型、硅质突起、硅化气孔、弓型和多面表皮植硅体;且主要以短细胞、棒型、尖型为主,其平均百分含量之和高达80.77%,块状、扁平状、扇型次之,其他类型的植硅体含量较少。方差分析结果表明:棒型、三棱柱型、硅质突起、哑铃型和扁平状在大兴安岭、松嫩平原和长白山之间存在显著性差异,且棒型、三棱柱型、硅质突起的百分含量与年降水量具有极显著的正相关性,哑铃型的百分含量与年降水量具有极显著的负相关性。总之,年均温为4 ℃等温线上70块表土样品中植硅体类型基本相同,但不同类型植硅体的百分含量存在差异,说明本研究区域内表土植硅体组合特征对降水的响应较为敏感。  相似文献   

长春南湖芦苇(Phragmites australis)茎、叶植硅体随生长期和生境的变化特征     

高桂在  介冬梅  刘利丹  刘洪妍  高卓  李德晖  李楠楠 《湖泊科学》2017,29(1):224-233

对于不同生长期、不同湿度条件下芦苇(Phragmites australis)茎、叶中多种类型植硅体含量变化的探讨,能够为植硅体形成机理研究和探讨植硅体对气候变化的响应提供理论依据.选取长春市南湖为实验样点,于5—10月在3种不同生境(旱生、季节性水生和水生生境)采集芦苇样品,并分别统计芦苇茎、叶植硅体形态和数量.实验结果显示:首先,茎、叶植硅体组合特征存在明显差异,茎中帽型及个体较大的尖型等植硅体多于叶中,而叶中硅化气孔含量明显高于茎中.其次,随着植株的生长,芦苇茎中硅化气孔含量先增加后减少,鞍型植硅体含量变化较小而帽型植硅体含量先减少后增加,棒型植硅体含量逐渐增加、尖型植硅体含量先增加后减少;芦苇叶中硅化气孔含量持续增加,鞍型、帽型等短细胞植硅体含量下降,尖型、扇型等个体较大的植硅体含量逐渐增加.最后,不同植硅体类型的含量在3种生境中的变化情况较为复杂,茎中植硅体的数量变化没有明显规律,而芦苇叶中硅化气孔含量由旱生生境向水生生境逐渐增加,可见叶中硅化气孔含量的增加可以指示相对湿润的生境条件.总之,芦苇茎、叶内不同类型植硅体的数量对植株生长及不同湿度环境有不同程度的响应,对芦苇植硅体的研究也有助于理解湿生植物植硅体与环境因子的关系,进而为探讨植硅体对古环境、古气候的响应提供理论基础.  相似文献   

Large-scale depositional characteristics of the Ulleung Basin and its impact on electrical resistivity and Archie-parameters for gas hydrate saturation estimates     

《Marine and Petroleum Geology》2013

Gas hydrate saturation estimates were obtained from an Archie-analysis of the Logging-While-Drilling (LWD) electrical resistivity logs under consideration of the regional geological framework of sediment deposition in the Ulleung Basin, East Sea, of Korea. Porosity was determined from the LWD bulk density log and core-derived values of grain density. In situ measurements of pore-fluid salinity as well as formation temperature define a background trend for pore-fluid resistivity at each drill site. The LWD data were used to define sets of empirical Archie-constants for different depth-intervals of the logged borehole at all sites drilled during the second Ulleung Basin Gas Hydrate Drilling Expedition (UBGH2). A clustering of data with distinctly different trend-lines is evident in the cross-plot of porosity and formation factor for all sites drilled during UBGH2. The reason for the clustering is related to the difference between hemipelagic sediments (mostly covering the top ∼100 mbsf) and mass-transport deposits (MTD) and/or the occurrence of biogenic opal. For sites located in the north-eastern portion of the Ulleung Basin a set of individual Archie-parameters for a shallow depth interval (hemipelagic) and a deeper MTD zone was achieved. The deeper zone shows typically higher resistivities for the same range of porosities seen in the upper zone, reflecting a shift in sediment properties. The presence of large amounts of biogenic opal (up to and often over 50% as defined by XRD data) was especially observed at Sites UBGH2-2_1 and UBGH2-2_2 (as well as UBGH1-9 from a previous drilling expedition in 2007). The boundary between these two zones can also easily be identified in gamma-ray logs, which also show unusually low readings in the opal-rich interval. Only by incorporating different Archie-parameters for the different zones a reasonable estimate of gas hydrate saturation was achieved that also matches results from other techniques such as pore-fluid freshening, velocity-based calculations, and pressure-core degassing experiments. Seismically, individual boundaries between zones were determined using a grid of regional 2D seismic data. Zoning from the Archie-analysis for sites in the south-western portion of the Ulleung Basin was also observed, but at these sites it is linked to individually stacked MTDs only and does not reflect a mineralogical occurrence of biogenic opal or hemipelagic sedimentation. The individual MTD events represent differently compacted material often associated with a strong decrease in porosity (and increase in density), warranting a separate set of empirical Archie-parameters.  相似文献   

应用FTIR-SEM研究一类合成欧珀的微结构及其变彩成因机制   总被引：1，自引：1，他引：0  

严俊  胡丹静  黄雪冰  彭秋瑾  刘晋华  张旭  张俭 《岩矿测试》2017,36(1):59-65

近些年来,相关人工合成欧泊的研究工作主要聚焦于天然与合成欧泊的鉴别与筛选,而相关合成欧泊的微结构、变彩机制及其中水的赋存状态的深入研究鲜见报道。本文通过傅里叶变换红外光谱(FTIR)、场发射扫描电镜(FE-SEM)对一类合成欧泊的微结构、结构缺陷进行较系统的研究。同时,结合对样品的热处理就该合成欧泊体色、变彩机制及其中水的赋存状态作了初步探讨。结果表明:该样品的红外光谱中,在约2900 cm~(-1)、1737 cm~(-1)处出现合成欧泊特征吸收,且在4000~6000 cm-1波段,合成欧泊相比天然欧泊的吸收峰更为复杂。合成欧泊的颜色由体色与变彩两者共同构成,该体色与存在于其微结构中准球状、粒径约205 nm的二氧化硅颗粒的间隙填充物直接关联,且在热处理条件下随着间隙物的析出而渐退。同时,该类合成欧泊的变彩归因于结构致色并由其内部SiO_2颗粒周期性排列而构成的三维的光子带隙结构所致。此外,在欧泊的微观结构发生重构前,变彩所呈现的颜色主要由准球状二氧化硅颗粒粒径与间隙填充物决定。  相似文献