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1.
Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff 下载免费PDF全文
We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component. 相似文献
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通过将车流量的增大或减小转化为路长权重的变化。将交通流量的动态问题转化为静态问题,用解决最短路问题的Dijkstra方法,给出交通流量实时最优控制的可行性模型及其有效算法。 相似文献
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P-III分布参数的概率权重矩法S函数计算 总被引:4,自引:1,他引:3
概率权重矩法是一种估计统计分布参数的方法.本文根据不完全Γ函数在无限区间积分,推导了P-Ⅲ分布参数的S函数的计算公式.通过现有计算公式比较,其计算结果具有较高的计算精度,避免了的大量的数值积分计算.文中公式只要借助于计算编程进行求解,给定超几何函数项一定的截断误差,其运算具有较高的运行速度.文中计算公式是一种P-Ⅲ分布参数S函数的计算途径. 相似文献
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AbstractThe scour phenomena around vertical piles in oceans and under waves may influence the structure stability. Therefore, accurately predicting the scour depth is an important task in the design of piles. Empirical approaches often do not provide the required accuracy compared with data mining methods for modeling such complex processes. The main objective of this study is to develop three data-driven methods, locally weighted linear regression (LWLR), support vector machine (SVR), and multivariate linear regression (MLR) to predict the scour depth around vertical piles due to waves in a sand bed. It is the first effort to develop the LWLR to predict scour depth around vertical piles. The models simulate the scour depth mainly based on Shields parameter, pile Reynolds number, grain Reynolds number, Keulegan–Carpenter number, and sediment number. 111 laboratory datasets, derived from several experimental studies, were used for the modeling. The results indicated that the LWLR provided highly accurate predictions of the scour depths around piles (R?=?0.939 and RMSE = 0.075). Overall, this study demonstrated that the LWLR can be used as a valuable tool to predict the wave-induced scour around piles. 相似文献
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多波束数据的海底数字地形模型构建 总被引:11,自引:0,他引:11
提出大批量多格式原始多波束数据的DTM构建方法,以满足大区域、大比例尺海底地形制图的需要。在多种格式原始多波束数据接口和系统内部标准数据结构的基础上,通过对数据文件、数据种类和数据运算量的有效组织管理,实施边读入、边权重配赋的网格插值,分析了高斯、指数和距离平方反比权重函数的适用性,及最小值、最大值和平均值的实用性。在权重配赋网格插值基础上,提出分形fBM和张力样条配合使用的方程式插值方法,保证DTM数据的有效外延和地形分辨。整套算法效率高,并能有效保证DTM的精度,对存储在外部介质的数据遍历一次即可完成网格插值。 相似文献
6.
A Unified Variational Principle of Fluid Mechanics and Application on Solitary Subdomain or Point 总被引:1,自引:0,他引:1
-According to basic equations of fluid mechanics, this paper presents a unified variational principle of fluid mechanics (UVPFM) by using the optimization method of weighted residuals (OMWR). The advantages are as follows, the establishment of the functional and the variational principle is easy, it can change various problems of fluid mechanics derived by basic equations into a unified optimization problem, and the solution is the optimum one in some sense. According to the OMWR for the solitary subdomain, this paper uses UVPFM onto any solitary subdomain and gives the solution of the hydrodynamics equation which is suitable only for that solitary subdomain. According to the OMWR for solitary point, this paper uses UVPFM to any solitary point and gives the solution of the hydrodynamics equation (point solution) which is suitable only for that solitary point. As the solution for the solitary subdomain or solitary point is developed independently, the compatibility with other subdomain or other points, do 相似文献
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Researchers’ fame in most scientific fields is closely linked to their publishing capacity, both in terms of quantity and quality. In GIScience, as in other fields, this situation demands that the researcher evaluate and to be very familiar with the scientific journals in which they could publish. Some specialized journals (e.g. Journal of Citation Reports or JCR) are devoted to ranking these reviews according to various methods and criteria. Compared to other scientific communities, GIScience is relatively new and constantly evolving. Therefore, the journals of this field do not benefit from any real formal ranking yet. The objective of this paper is to present the process and results of a study aimed at addressing this gap. More specifically, the challenge is to elaborate an importance ranking of the scientific journals in the field of GIScience. To do so, both a qualitative (Delphi study carried out with 40 international experts) and a quantitative (JCR impact factor) approach has been implemented. This triangulation method leads to an early global ranking of the journals of this field. 相似文献
10.
联合多种测高资料和Geosat/GM波形重构数据,基于EIGEN_CG01C重力场模型,采用沿轨迹加权最小二乘方法和逆Vening-Meinesz公式,确定了中国海及其邻域1.5′×1.5′重力异常。将计算结果与最新船测资料进行了比较,标准差为3.37×10-5m.s-2。 相似文献