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1.
Chris Yakymchuk Adrian Rehm Zhuoheng Liao John M. Cottle 《Journal of Metamorphic Geology》2019,37(6):839-862
Sapphirine–quartz granulites from the Cocachacra region of the Arequipa Massif in southern Peru record early Neoproterozoic ultrahigh‐temperature metamorphism. Phase equilibrium modelling and zircon petrochronology are used to quantify timing and pressure–temperature (P–T) conditions of metamorphism. Modelling of three magnetite‐bearing sapphirine–quartz samples indicates peak temperatures of >950°C at ~0.7 GPa and a clockwise P–T evolution. Elevated concentrations of Al in orthopyroxene are also consistent with ultrahigh‐temperature conditions. Neoblastic zircon records ages of c. 1.0–0.9 Ga that are interpreted to record protracted ultrahigh‐temperature metamorphism. Th/U ratios of zircon of up to 100 reflect U‐depleted whole‐rock compositions. Concentrations of heavy rare earth elements in zircon do not show systematic trends with U–Pb age but do correlate with variable whole‐rock compositions. Very large positive Ce anomalies in zircon from two samples probably relate to strongly oxidizing conditions during neoblastic zircon crystallization. Low concentrations of Ti‐in‐zircon (<10 ppm) are interpreted to result from reduced titania activities due to the strongly oxidized nature of the granulites and the sequestration of titanium‐rich minerals away from the reaction volume. Whole‐rock compositions and oxidation state have a strong influence on the trace element composition of metamorphic zircon, which has implications for interpreting the geological significance of ages retrieved from zircon in oxidized metamorphic rocks. 相似文献
2.
Silica-undersaturated sapphirine, spinel and kornerupine granulite facies rocks, NE Strangways Range, Central Australia 总被引：6，自引：0，他引：6
B. GOSCOMBE 《Journal of Metamorphic Geology》1992,10(2):181-201
Small pods of silica-undersaturated Al-rich and Mg-rich granulite facies rocks containing sapphirine, pleonastic spinel, kornerupine, cordierite, orthopyroxene, corundum, sillimanite and gedrite are scattered throughout the NE Strangways Range, Central Australia. These are divided into four distinct rock types, namely orthopyroxene-rich aluminous granofels and metapelitic gneisses containing sapphirine, spinel or kornerupine. Two granulite facies metamorphic events are recognized, of which only the first (M1) is considered in this paper. Peak metamorphic mineral parageneses indicate that the M1 thermal maximum occurred at approximately 900–950 °C and 8–9 kbar. All samples are characterized by profuse and diverse coronitic and symplectic reaction textures. These are interpreted as evidence for the sequential crossing of the following reactions in the system FMAS: cordierite + spinel + corundum = sapphirine + sillimanite, cordierite + spinel = orthopyroxene + sapphirine + sillimanite, sapphirine + spinel + sillimanite = orthopyroxene + corundum, sapphirine + sillimanite = cordierite + orthopyroxene + corundum. Phase stability relationships in FMAS and MASH indicate an anticlockwise P–T path terminated by isobaric cooling. Such a path is exemplified by early low-P mineral parageneses containing spinel, corundum and gedrite and the occurrence of both prograde and retrograde corundum. Reaction textures preserve evidence for an increase in aH2O and aB2O3 with progressive isobaric cooling. This hydrous retrogression resulted from crystallization of intimately associated M1 partial melt segregations. There is no evidence for voluminous magmatic accretion giving rise to the high M1 thermal gradient. The M1 P–T path may be the result of either lithospheric thinning after both crustal thickening and burial of the supracrustal terrane, or concomitant crustal thickening and mantle lithosphere thinning. 相似文献
3.
Sapphirine in SW Sweden: a record of Sveconorwegian (–Grenvillian) late-orogenic tectonic exhumation
MÖller 《Journal of Metamorphic Geology》1999,17(1):127-141
In the Sveconorwegian granulite region of SW Sweden, sapphirine occurs in reaction coronas in Mg- and Al-rich kyanite eclogites which form parts of mafic complexes. Aluminous to peraluminous sapphirine forms symplectitic intergrowths with plagioclase±corundum±spinel after kyanite. Kyanite and omphacite were the main reactants in the formation of sapphirine. The sapphirine formed during decompression from the eclogite facies ( P >15 kbar) through the high- to medium-pressure granulite and upper amphibolite facies at c. 750 °C. Preserved growth zoning in garnet, frozen-in reaction textures, and chemical disequilibrium suggest a rapid tectonic exhumation. Ductile deformation in the surrounding gneisses and parts of the mafic complex is characterized by foliation development, WNW–ESE stretching and dynamic recrystallization under granulite to upper amphibolite facies conditions, simultaneous with the sapphirine formation. This decompression, high-grade re-equilibration and associated deformation took place during the exhumation of the Sveconorwegian eclogites, bracketed between 969±14 and 956±7 Ma. Probable tectonic causes are late-orogenic gravitational collapse and/or plate divergence following the Sveconorwegian–Grenvillian continent–continent collision. There are no indications of metastability of aluminous and peraluminous sapphirine in the decompressed kyanite eclogites; sapphirine is stable in amphibole-poor and amphibolitized varieties, including rocks that have undergone dynamic recrystallization. Close similarities between rocks from different parts of the world with respect to reaction textures suggests that sapphirine+plagioclase-forming reactions are a universal feature in high-temperature decompressed kyanite eclogites. 相似文献
4.
Silica-deficient sapphirine-bearing rocks occur as an enclave within granulite facies Proterozoic gneisses and migmatites near Grimstad in the Bamble sector of south-east Norway (Hasleholmen locality). The rocks contain peraluminous sapphirine, orthopyroxene, gedrite, anthophyllite, sillimanite, sapphirine, corundum, cordierite, spinel, quartz and biotite in a variety of assemblages. Feldspar is absent.
Fe2+ /(Fe2+ + Mg) in the analysed minerals varies in the order: spinel > gedrite ≥ anthophyllite ≥ biotite > sapphirine>orthopyroxene > cordierite.
Characteristic pseudomorph textures indicate coexistence of orthopyroxene and sillimanite during early stages of the reaction history. Assemblages containing orthopyroxene-sillimanite-sapphirine-cordierite-corundum developed during a high-pressure phase of metamorphism and are consistent with equilibration pressures of about 9 kbar at temperatures of 750–800°C. Decompression towards medium-pressure granulite facies generated various sapphirine-bearing assemblages. The diagnostic assemblage of this stage is sapphirine-cordierite. Sapphirine occurs in characteristic symplectite textures. The major mineralogical changes can be described by the discontinuous FMAS reaction: orthopyroxene + sillimanite → sapphirine + cordierite + corundum.
The disequilibrium textures found in the Hasleholmen rocks are characteristic for reactions which have been in progress but then ceased before they run to completion. Textures such as reaction rims, symplectites, partial replacement, corrosion and dissolution of earlier minerals are characteristic of granulite facies rocks. They indicate that, despite relatively high temperatures (700–800° C), equilibrium domains were small and chemical communication and transport was hampered as a result of dry or H2 O-poor conditions. 相似文献
Fe
Characteristic pseudomorph textures indicate coexistence of orthopyroxene and sillimanite during early stages of the reaction history. Assemblages containing orthopyroxene-sillimanite-sapphirine-cordierite-corundum developed during a high-pressure phase of metamorphism and are consistent with equilibration pressures of about 9 kbar at temperatures of 750–800°C. Decompression towards medium-pressure granulite facies generated various sapphirine-bearing assemblages. The diagnostic assemblage of this stage is sapphirine-cordierite. Sapphirine occurs in characteristic symplectite textures. The major mineralogical changes can be described by the discontinuous FMAS reaction: orthopyroxene + sillimanite → sapphirine + cordierite + corundum.
The disequilibrium textures found in the Hasleholmen rocks are characteristic for reactions which have been in progress but then ceased before they run to completion. Textures such as reaction rims, symplectites, partial replacement, corrosion and dissolution of earlier minerals are characteristic of granulite facies rocks. They indicate that, despite relatively high temperatures (700–800° C), equilibrium domains were small and chemical communication and transport was hampered as a result of dry or H
5.
GREW EDWARD S.; YATES MARTIN G.; SHEARER CHARLES K.; HAGERTY JUSTIN J.; SHERATON JOHN W.; SANDIFORD MICHAEL 《Journal of Petrology》2006,47(5):859-882
Anatectic veins containing the Be minerals khmaralite and berylliansapphirine as primary phases (or surinamite derived therefrom)are associated with Mg–Al-rich paragneisses at three localitiesin the ultrahigh-temperature Napier complex, Antarctica, a uniqueBe mineralization in the granulite facies. Likely precursorsof the paragneisses are volcaniclastic deposits that were hydrothermallyaltered by heated seawater prior to metamorphism. Regular distributionof Be among minerals in the paragneisses suggests an approachto equilibrium with Be greatly concentrated in sapphirine (25–3430ppm Be) or cordierite (560–930 ppm Be) relative to plagioclaseAn53–66 (14–43 ppm Be) > cores of coarse-grainedorthopyroxene (0·7–29 ppm Be) > coronitic orthopyroxene(0·4–14 ppm Be) sillimanite (0·1–26ppm Be) plagioclase An18–33 (0·6–15 ppmBe) > biotite (0·06–8 ppm Be) > K-feldspar,quartz, garnet (0·05–0·7 ppm Be). Sapphirine-bearingparagneisses have average Be concentrations, 4·9 ±2·4 ppm (13 samples), about twice that of typical pelites,whereas paragneisses lacking sapphirine and primary cordieritehave only 2·9 ± 2·1 ppm Be (12 samples),implying some loss of Be during metamorphism. The likely sourcerocks for the Be-rich melts were biotitic rocks lacking theBe sinks sapphirine and cordierite. These gneisses were probablyless competent than the sapphirine-bearing gneisses, so themelts were drawn to the latter and collected in spaces openedduring deformation and boudinage of the more competent paragneisses.Fractionation of the melts concentrated Be to the extent thatBe minerals could crystallize. The final result was Be-mineralizedanatectic veins hosted by relatively Be-rich sapphirine-bearingparagneisses. KEY WORDS: Antarctica; beryllium; granulite facies; microprobe; sapphirine 相似文献
6.
西南天山昭苏县东德沟中异剥钙榴岩化斜长角闪岩中发现过铝质的假蓝宝石和富铝尖晶石,假蓝宝石的Al2O3含量在64.82％ ～ 66.36％之间,富铝尖晶石的Al2O3含量在65.24％～ 68.54％之间.根据含假蓝宝石和尖晶石的矿物组合和矿物反应结构,利用Theriak-Domino软件,对岩石的变质条件进行模拟,结果表明形成假蓝宝石的峰期温压为700～780℃,0.65～0.75 GPa,达到了麻粒岩相的变质条件,峰期变质反应为:角闪石(Am)+尖晶石(Spl)+钙长石(An)=绿泥石(Chl)+透辉石(Di)+假蓝宝石(Spr),岩石在异剥钙榴岩化之前经历了一次高温富Al(熔)流体的交代进变质作用.含假蓝宝石麻粒岩相变质作用的出现为西南天山俯冲上板片岩石复杂的变质作用过程又增添了新的内容,具有重要的地质意义. 相似文献
7.
The Al–Mg-rich granulites from the In Ouzzal craton, Algeria, show a great diversity of mineral reactions which correspond to continuous equilibria as predicted by phase relationships in the FeO–MgO–Al2O3–SiO2 system. The sequence of mineral reactions can be subdivided into three distinct stages: (1) a high-P stage characterized by the growth of coarse mineral assemblages involving sapphirine and the disappearance of early corundum and spinel-bearing assemblages; (2) a high-T stage characterized by the development of Sa–Qz-bearing assemblages; and (3) a later stage, in which garnet-bearing assemblages are replaced by more or less fine symplectites involving cordierite. During the course of early mineral reactions, the distribution coefficient, Kd, between the various ferromagnesian phases decreased significantly whereas Al2O3 in pyroxene increased concomitantly. These observations, when combined with topological constraints, clearly indicate that the high-P stage 1 was accompanied by a significant rise in temperature (estimated at 150 ± 50° C) under near isobaric conditions, in agreement with the reaction textures. By stage 2, pressure and temperature were extreme as evidenced by the low Kd value between orthopyroxene and garnet (Kd= 2.06–1.99), the high alumina content in pyroxene (up to 11.8%) and the high magnesium content in garnet [100 Mg/(Mg + Fe) = 60.6]. Mineral thermometry based on Fe–Mg exchange between garnet and pyroxene and on Al-solubility in pyroxene gives temperatures close to 970 ± 70° C at 10 ± 1.5 kbar. These results are in agreement with the development of Sa–Qz assemblages on a local scale. Late mineral reactions have been produced during a decompression stage from about 9 to 6 kbar. Except for local re-equilibration of Mg and Fe at grain boundaries, there is no evidence for further reactions below 700° C. We interpreted the whole set of mineral reactions as due to changes in pressure and temperature during a tectonic episode located at c. 2 Ga. Because of the lack of evidence for further uplift after the thermal relaxation which occurred at c. 6 kbar, it is possible however that the exhumation of this granulitic terrane occurred in a later tectonic event unrelated to its formation. 相似文献
8.
The presence in rocks of coexisting sapphirine + quartz has been widely used to diagnose conditions of ultra‐high‐temperature (UHT) metamorphism (>900 °C), an inference based on the restriction of this assemblage to temperatures >980 °C in the conventionally considered FeO–MgO–Al2O3–SiO2 (FMAS) chemical system. With a new thermodynamic model for sapphirine that includes Fe2O3, phase equilibra modelling using thermocalc software has been undertaken in the FeO–MgO–Al2O3–SiO2–O (FMASO) and FeO–MgO–Al2O3–SiO2– TiO2–O (FMASTO) chemical systems. Using a variety of calculated phase diagrams for quartz‐saturated systems, the effects of Fe2O3 and TiO2 on FMAS phase relations are shown to be considerable. Importantly, the stability field of sapphirine + quartz assemblages extends down temperature to 850 °C in oxidized systems and thus out of the UHT range. 相似文献
9.
D. L. WHITNEY 《Journal of Metamorphic Geology》2011,29(4):425-449
Gneiss domes are commonly cored by quartzofeldspathic rocks that provide little information about the pressure–temperature–fluid history of the domes. Three northern Cordilleran migmatite domes (Thor‐Odin and Valhalla/Passmore, British Columbia, Canada; Okanogan, Washington, USA), however, contain Mg–Al‐rich orthoamphibole‐cordierite gneiss as layers and lenses that record metamorphic conditions and pressure–temperature (P–T) path information not preserved in the host migmatite. These Mg–Al‐rich rocks are therefore a valuable archive of metamorphic conditions during dome evolution, although refractory rocks such as these commonly contain reaction textures that may complicate the calculation of metamorphic conditions. In the Okanogan dome, Mg–Al‐rich layers are part of the Tunk Creek unit, which occurs at the periphery of an underlying migmatite domain. Bulk compositional layers (mm‐ to m‐scale) consist of gedrite‐dominated, hornblende‐dominated and biotite‐bearing layers that contain variable amounts of gedrite, hornblende, anorthite, cordierite, spinel, sapphirine, corundum, kyanite, biotite and/or staurolite. The presence of different compositional layers (some with reaction textures, some without) allows systematic analysis of metamorphic history by a combined petrographic and phase equilibrium analysis. Gedrite‐dominated layers containing relict kyanite preserve evidence of the highest‐P conditions; symplectitic and coronal reaction textures around kyanite indicate decompression at high temperature. Gedrite‐dominated layers lacking these reaction textures contain layers of sapphirine and spinel in apparent textural equilibrium and record a later high‐T–low‐P part of the path. Phase equilibria (pseudosection) analysis for layers that lack reaction textures indicates metamorphic conditions of 720–750 °C at a range of pressures (>8 to <4 kbar) following decompression. Elevated crustal temperatures and concordant structural fabrics in the Tunk Creek unit and underlying migmatite domain suggest that the calculated P–T conditions recorded in Tunk Creek rocks were coeval with anatexis, extension, and dome formation in Palaeocene–Eocene time. In contrast to orthoamphibole‐cordierite gneiss in the other Cordilleran domes, the Tunk Creek unit occurs as a discontinuous km‐scale layer rather than as smaller (m‐scale) pods, is more calcic, and lacks garnet. In addition, kyanite did not transform to sillimanite, and spinel commonly occurs as a blocky matrix phase in addition to vermicules in symplectite. These differences, along with the compositional layering, allow an analysis of bulk composition v. tectonic (P–T path) controls on mineral assemblages and textures. Pseudosection modelling of different layers in the Tunk Creek unit provides a basis for understanding the metamorphic history of these texturally complex, refractory rocks and their host gneiss domes, and other such rocks in similar tectonic settings. 相似文献
10.
Corona textures between kyanite, garnet and gedrite in gneisses from Errabiddy, Western Australia 总被引：2，自引：0，他引：2
JUDY BAKER ROGER POWELL MICHAEL SANDIFORD JAN MUHLING 《Journal of Metamorphic Geology》1987,5(3):357-370
Abstract Corona textures, which developed in alternating layers in rocks in a supracrustal belt at Errabiddy, Western Australia, involved:
(a) The production of staurolite, cordierite and quartz or sapphirine between Kyanite and/or sillimanite and gedrite; and
(b) The production of cordierite between garnet and gedrite.
These textures are inconsistent with development along the same pressure–temperature path in the system FeO–MgO–Al2 O3 –SiO2 –H2 O, but can be accounted for if CaO, mainly in garnet, is taken into account. The sapphirine-bearing kyanite–gedrite textures are explained by lower a (SiO2 ) during their development. The assemblages indicate a consistent pressure–temperature ( P–T ) trajectory involving substantial uplift with only a slight decrease in temperature. The history of these rocks includes reheating of originally high-grade rocks that had cooled to a stable conductive geotherm, followed by substantial, essentially isothermal uplift. The tectonic environment for this was presumably the one responsible for emplacement of the high-grade terrain in the upper crust. 相似文献
(a) The production of staurolite, cordierite and quartz or sapphirine between Kyanite and/or sillimanite and gedrite; and
(b) The production of cordierite between garnet and gedrite.
These textures are inconsistent with development along the same pressure–temperature path in the system FeO–MgO–Al