南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪   总被引：1，自引：1，他引：0  

张美  陆红锋  管红香  刘丽华  邬黛黛  吴能友 《海洋学报(英文版)》2018,37(7):20-27

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.  相似文献   

珠江口淇澳岛滨海湿地沉积环境演化及其对人类活动的响应   总被引：1，自引：1，他引：0  

叶翔  李靖  王爱军 《海洋学报》2018,40(7):79-89

滨海湿地作为人类活动和全球变化反应最为敏感的区域，其沉积记录可以反映出周边地区环境变化及人类活动信息。珠江口淇澳岛滨海湿地钻孔分析结果表明，在中全新世期间淇澳岛附近海域为河口湾环境，在风化层以上开始出现淤积，但在4 200 a BP前后受极冷气候的影响，沉积物粗化；自2 500 a BP以来，沉积环境相对稳定，在小冰期期间略有变化。沉积速率计算结果显示:淇澳岛附近海域自中全新世高海面以来的平均沉积速率为0.29 cm/a，4 160~2 500 a BP、2 500 a BP-1488年、1488-1893年、1893-1986年、1990-2007年期间的平均沉积速率分别为:0.17 cm/a、0.23 cm/a、0.35 cm/a、1.37 cm/a和5.94 cm/a，沉积速率逐渐增大，反映了珠江三角洲演化过程中沉积相与沉积环境的变化；1986-1990年期间的海堤建造极大地扰动了该钻孔上部的沉积过程，在工程施工期间共沉积了厚度约112 cm的沉积层，而在海堤建成后，沉积速率也显著增大。沉积物总有机碳、总氮和C/N值的垂向分布表明，在4 160~2 500 a BP期间受海洋环境影响较大，沉积物中有机碳以海源为主，2 500 a BP以来沉积物中碳、氮含量明显增大，C/N也相应变大，有机碳主要来源于陆源输入，但在小冰期期间海源有机碳贡献略有所增大；近百年来由于受人类活动影响显著，陆源有机碳的贡献快速增加。  相似文献   

Petrochronology of oxidized granulites from southern Peru     

Chris Yakymchuk  Adrian Rehm  Zhuoheng Liao  John M. Cottle 《Journal of Metamorphic Geology》2019,37(6):839-862

Sapphirine–quartz granulites from the Cocachacra region of the Arequipa Massif in southern Peru record early Neoproterozoic ultrahigh‐temperature metamorphism. Phase equilibrium modelling and zircon petrochronology are used to quantify timing and pressure–temperature (P–T) conditions of metamorphism. Modelling of three magnetite‐bearing sapphirine–quartz samples indicates peak temperatures of >950°C at ~0.7 GPa and a clockwise P–T evolution. Elevated concentrations of Al in orthopyroxene are also consistent with ultrahigh‐temperature conditions. Neoblastic zircon records ages of c. 1.0–0.9 Ga that are interpreted to record protracted ultrahigh‐temperature metamorphism. Th/U ratios of zircon of up to 100 reflect U‐depleted whole‐rock compositions. Concentrations of heavy rare earth elements in zircon do not show systematic trends with U–Pb age but do correlate with variable whole‐rock compositions. Very large positive Ce anomalies in zircon from two samples probably relate to strongly oxidizing conditions during neoblastic zircon crystallization. Low concentrations of Ti‐in‐zircon (<10 ppm) are interpreted to result from reduced titania activities due to the strongly oxidized nature of the granulites and the sequestration of titanium‐rich minerals away from the reaction volume. Whole‐rock compositions and oxidation state have a strong influence on the trace element composition of metamorphic zircon, which has implications for interpreting the geological significance of ages retrieved from zircon in oxidized metamorphic rocks.  相似文献   

Application of Grain Size Analysis to Study Sedimentary Environment of Sand Dune in the Vicinity of Tumen River     

Feng Ma  Li Liu  Lin Cao 《东北亚地学研究》2003,(1)

The dunes in estuary of Tumen River in China lie to the area between the Jiushaping and Fangchuan in the left bank of Tumen River (Fig.1). The dis-tance is about 15～20 km between the dunes and the coast. It ranges from China to D. P. R. Korea and Russia. The range of the height of dunes is about 15～20 m and the width is 100～200 m. By the re-connaissance, we protracted 9 section planes of the dunes and collected 40 sand samples of the dunes, and identified the sedimentary environment …  相似文献   

The range of effects of azimuthal isotropy and EDA anisotropy in sedimentary basins   总被引：4，自引：0，他引：4  

Philip Wild  Stuart Crampin 《Geophysical Journal International》1991,107(3):513-529

  相似文献   

凤太矿田层控铅锌(铜)矿床的成矿物质来源探讨     

隗合明  吕仁生 《地球科学与环境学报》1990,(1)

秦岭凤太矿田层控铅锌(铜)矿床的金属物质、硫和成矿溶液主要来自深部基底的岩石,属海底喷流—沉积成因矿床。从这一理论认识出发可进一步分析控矿地质条件及今后在该区有效地寻找同类矿床。  相似文献   

右江复合盆地的沉积特征及其构造演化     

曾允孚  刘文均  陈洪德  郑荣才  张锦泉  李孝全  蒋廷操 《南方国土资源》1992,(4)

位于华南褶皱带南缘的右江盆地,其发展可分为两个不同的阶段。它的轮廓和结构,与NW向及NE向同沉积断裂关系密切。盆地内的沉积物,分别由特征不同的非补偿性和补偿性沉积相组成两个双层结构。盆地内火山活动发育,也明显的分为两个阶段。海西期,古特提斯洋的发展使哀牢山洋盆开裂,导致了右江地区在拉张应力条件下出现若干NW向裂陷带,这时的盆地具有大陆边缘裂谷特点。东吴运动后开始的印支期,区域应力条件发生变化。滨大平洋构造的发生,使盆地轮廓和结构发生明显变化,与此同时开始的哀牢山洋盆向NE方向的俯冲消减作用,使盆地在新的挤压条件下再次发生张裂和拗陷。进入了弧后盆地发展阶段。印支期末,盆地封闭。  相似文献   

Nitrogen uptake,ammonium oxidation and nitrous oxide (N₂O) levels in the coastal waters of western Cook Strait,New Zealand     

John C. Priscu  Malcolm T. Downes 《Estuarine, Coastal and Shelf Science》1985,20(5):529-542

Vertical measurements of $\text{NH}{}_4{}^{\mathrm{+}}$, $\text{NO}{}_3{}^{\mathrm{?}}$ and N₂O concentrations, $\text{NO}{}_3{}^{\mathrm{?}}$ and $\text{NH}{}_4{}^{\mathrm{+}}$ uptake, and $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation rates were measured at 5 sites in western Cook Strait, New Zealand, between 31 March and 3 April 1983. Nitrate increased with depth at all stations reaching a maximum of 10.5 μg-atom $\text{NO}{}_3{}^{\mathrm{?}}\text{N l}{}^{\mathrm{?1}}$ at the most strongly stratified station whereas $\text{NH}{}_4{}^{\mathrm{+}}$ was relatively constant with depth at all stations (～0.1 μg-atom $\text{NH}{}_4{}^{\mathrm{+}}\text{N l}{}^{\mathrm{?1}}$). The highest rates of $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation generally occurred in the near surface waters and decreased with depth. N₂O levels were near saturation with respect to the air above the sea surface and showed no obvious changes during 24 h incubation. $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation by nitrifying bacteria may account for about 30% of the total $\text{NH}{}_4{}^{\mathrm{+}}$ utilization (i.e. bacterial+agal) and, assuming oxidation through to $\text{NO}{}_3{}^{\mathrm{?}}$, may supply about 40% of the algal requirements of $\text{NO}{}_3{}^{\mathrm{?}}$ in the study area. These results suggest that bacterial nitrification is of potential importance to the nitrogen dynamics of the western Cook Strait, particularly with respect to the nitrogen demands of the phytoplankton.  相似文献   

沉积物粒度分析在厦门市第四纪环境研究和地层划分对比中的应用   总被引：6，自引：0，他引：6  

张璞  陈建强  田明中  朱金芳  黄宗林  江春亮 《地球科学与环境学报》2005,27(1):88-94

采用MS2000型激光粒度分析仪进行测试，利用计算机粒度分析软件对数据进行整理和计算，绘制出样品的频率曲线、概率累积曲线以及粒度众数位值曲线等图件并进行沉积环境分析。厦门地区第四纪环境演化经历了中更新世同安组(含泥中粗砂、含泥细中砂、砂为主)海积一冲积一更新统上部龙海组(含泥粗中砂、含泥细中砂、含泥粗砂、粗砂、细中砂、含细砾中粗砂、中细砂等)冲积一洪冲积一更新世上部东山组(砂、砂砾、含泥中粗砂、粗砂、泥质中细砂、细砂、中粗砂等)冲洪积及部分海积(粉砂、细粉砂、含碳质泥、粘土、淤泥质粘土、粉砂质粘土等)一全新世长乐组(粉砂，淤泥质粘土、粉砂质粘土、碳质粘土、含砂淤泥质粘土，粉砂质亚粘土、粉细砂亚粘土等)海湾沉积。在解释环境变化的同时，说明粒度变化曲线在一定程度上可以作为地层划分的依据之一，并以此对研究区地层进行了详细划分。  相似文献   

Paleosol at the Archean—Proterozoic contact in NW India revisited: Evidence for oxidizing conditions during paleo-weathering?     

Manoj K. Pandit  Helga de Wall  Narendra K. Chauhan 《Journal of Earth System Science》2008,117(3):201-209

A number of fine-grained sericite bearing pelitic, schistose lithologies occur along the Archean (Banded Gneiss Complex)-Proterozoic (Aravalli Supergroup) contact (APC) in the Udaipur valley in NW Indian craton. These Al-rich lithologies (subsequently metamorphosed) have been described as ‘paleosols’, developed over a 3.3 Ga old Archean gneissic basement and are overlain by Paleoproterozoic Aravalli quartzite. The paleosol was developed between 2.5 and 2.1, coincident with the globally recognized Great Oxidation Event (GOE). In previous studies these paleosol sections were interpreted to have developed under reducing environment, however, the finding of a ‘ferricrete’ zone in the upper part of Tulsi Namla section (east of Udaipur) during the present study (in addition to earlier reported lithologies) has led to an alternative suggestion of oxygen-rich conditions during paleosol development. The Tulsi Namla paleosol section shows all the features characteristic of a complete paleosol section described from other Archean cratons. The paleosol includes sericite schist with kyanite as the prevalent Al-silicate in the lower part of profile while chloritoid and Fe-oxides typify the Fe-rich upper part. Alumina has remained immobile during the weathering process while Fe and Mn show a decrease in the lower part of the section and an abrupt rise in the upper part, in the ferricrete zone. The field and geochemical data indicate that the Tulsi Namla section is an in situ weathering profile and at least the upper part shows evidence of oxidizing conditions.  相似文献