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沉积盆地有机质自由基热演化特征及其作为古温标的探索 总被引：1，自引：0，他引：1
恢复沉积盆地热历史的方法主要有古地温指标法和动力学模拟法两类.古温标法中最常用的为有机质成熟度和矿物裂变径迹,动力学模拟法中最常用的是盆地的拉张模型和挤压模型.本文针对Ⅰ型有机质自由基浓度作为沉积盆地古温标进行了探索研究.分析了自然演化系列Ⅰ型有机质的自由基的热演化特征;根据自然演化系列的Ⅰ型有机质自由基浓度及时间-温度指数(TTI)数据,对热模拟实验下的Ⅰ型有机质自由基浓度及时间-温度指数(TTI)值进行校正,由校正后的数据初步建立了Ⅰ型有机质的自由基浓度(Ng)与时间-温度指数(TTI)的定量模型. 相似文献
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岩石的时温等效效应是指岩石在低温、长时间尺度下与在高温、短时间尺度下的流变力学特性等效的效应。利用岩石的时温等效效应,可以通过提高试验温度方法得到岩石在相对低温下的长期流变力学特性。为研究岩石在非线性黏弹性条件下的时温等效效应,基于Schapery单积分型的非线性本构方程,得到了岩石非线性黏弹性蠕变力学特性时温等效效应的数学表示。根据不同应力及温度下花岗岩的蠕变试验结果,设定20 ℃为参考温度,考虑温度改变对岩石瞬时蠕变柔量的影响,得到了垂直移位因子随温度的变化规律及修正后的蠕变柔量的时间对数曲线;对修正后的曲线进行水平移位使得相邻温度曲线之间相交于一点,得到不同应力下蠕变柔量的主曲线及水平移位因子的变化规律;主曲线中相邻温度曲线之间的一致性较好,进一步验证了花岗岩时温等效效应的存在性。通过对不同应力下的垂直移位因子和水平移位因子的变化规律分析,发现应力为40～60 MPa之间的非线性并不明显,但到87 MPa,非线性特性明显增强。 相似文献
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In order to know about the rheological properties of rock in a long range of the time scale,method of increasing temperature was brought forward to accelerate the rheological process of rock,which could extend the time scale of experimental test data.Firstly,based on the generalized linear viscoelastic constitutive equation with temperature variable,the creep behavior of rock was divided into three types according to the different strain dependences of the time,that is,Hookean deformation,Newtonian flow,and retarded elasticity.Then the general equivalence relationship between time parameter and temperature parameter was derived for each type of strain.Finally,the relation between time parameter and temperature parameter in the whole creep was considered and the general theory of time-temperature equivalence effect(TTEE) of rock was established.This research reveals: ①The temperature effect on the instantaneous strain could be modified through vertical shift.②The key point of the TTEE of Newtonian flow depends on whether in the study of linear viscoelastic behavior of rock change of temperature is completely equivalent to a shift of the logarithmic time scale or not.③By plotting the results of a creep experiment performed at different temperatures and comparing the curves obtained,one can decide whether the rock considered have TTEE.④The TTEE of the whole creep should satisfy that the horizontal shift function of Newtonian flow and retarded elasticity is consentaneous. 相似文献
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With the creep test data of granite taken from Three Gorges,the existence of time-temperature equivalence effect(TTEE) of granite is investigated.Based on the creep test data at different temperatures,which are 20 ℃,60 ℃,80 ℃,100 ℃,200 ℃,300 ℃,four-component viscoelastic Burgers model is presented to characterize the creep curves.The parameters of elasticity modulus and viscosity coefficient in the constitutive model at different temperatures and their functional dependences on temperature are obtained.Then,according to the basic theory of TTEE presented in research(I),the TTEE of granite is investigated through modifying the compliance curves with vertical shift function and checking the coincidence of the modified curves with horizontal shift functions.It is concluded that:① Burgers model could appropriately characterize the creep property of granite in a short time scale.② Both elastic modulus and viscosity coefficient in the Burgers model decay exponentially with temperature.③ The coincidence of the curves at different temperatures after vertical shift modification and horizontal shift is fine,which indicates the existence of TTEE of granite.④The master curves which reflect the long time scale test data at temperatures 20 ℃,100 ℃,200 ℃ are obtained. 相似文献
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The regional burial history pattern, thermal maturity variations and source rock assessment of the sedimentary succession in the eastern Taurus region, in the southern part of Turkey, have been studied on surface samples collected from the six different sections which represent the entire region. Organic petrography (Thermal Alteration Index) and geochemical data (TOC content, Tmax and HI values) were obtained from transmitted-light microscopy and Rock-Eval pyrolysis.The Lower Paleozoic (Cambrian, Ordovician and Silurian) strata were not investigated and modeled in terms of the maturity and hydrocarbon source rock potential, because of their poor organic matter content and their over maturity resulting from great burial depth (more than 7630 m). Other Paleozoic strata, except the Lower Devonian Ayitepesi Formation, generally have the values of more than 0.5% TOC. Organic matter of the Middle Devonian Safaktepesi sediments are composed of highly terrestrial organic material (type III kerogen), while samples from other three formations (Gumusali, Ziyarettepe and Yigilitepe Formations), while samples from other organic matter (type II and type III kerogen). The average TAI values are as high as 3.4 (equivalent to 1.42 of R0%) for Ayitepesi and as low as 2.75 (equivalent to 0.77 of R0%) for Yigilitepe Formations. Time-temperature index values (TTI) indicate that Ziyarettepe and Yigilitepe sediments are marginally mature to mature, while the Devonian strata are overmature. There are minor discrepancies between ΣTTI values and geochemical data in terms of the organic maturity for Devonian strata. In contrast, the e is a consistency between those values for the Ziyarettepe and the Yigilitepe Formations. The onset of oil generation time in the region was initiated from as early as the Norian (216 Ma) to as late as the Lutetian (45 Ma).Regional variations in the level of thermal and source-rock maturities of the Upper Paleozoic sediments in the eastern Taurus region largely depend on burial depth. 相似文献
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Laboratory data on dry and saturated rocks show that pore fluid has the most important effect on rock attenuation. It is known
that viscous and inertial coupling between the frame of a porous rock and its pore fluid dissipates seismic energy by conversion
to heat and hence cause attenuation. We show that attenuation peaks, in saturated rock have the same property as that of typical
thermally activated relaxations. In the frequency domain, a plot of attenuation versus frequency shows an obvious systematic
shift to higher frequencies with increasing temperatures. Similarly, the attenuation versus temperature curve moves to higher
temperature with increasing frequencies. The attenuation peaks are somewhat broader than that for a Zener relaxation. A Cole-Cole
distribution of relaxation times closely matches the attenuations. This behavior can be explained theoretically by local flow
mechanisms. 相似文献
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