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K. B. P. N. Jinadasa C. B. Dissanayake S. V. R. Weerasooriya A. Senaratne 《Environmental Geology》1993,21(4):251-255
Fluoride ion interaction with synthetically prepared goethite has been investigated over a range of pH values (4–9) and F– concentrations (10–3–10–5 M). The amount of F– retained by goethite suspensions was found to be a function of pH, media ionic strength, F– concentration, and goethite concentration. The lowest ionic strength (0.001 M KNO3) gave the highest adsorption medium. Uptake was minimal at pH >7 and increased with decreasing pH. Thermodynamic properties for fluoride adsorption at 298 K and 323 K were investigated. The isosteric heat of adsorption (H
r) was calculated and the heterogeneity and homogeneity of the surface examined for goethite. In view of the importance of fluoride in dental health, the interaction of fluoride on goethite in the physical environment has important implications on dental epidemiology. 相似文献
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《地学前缘(英文版)》2022,13(3):101365
The study evaluated the sources and controlling factors of the groundwater contaminants in an agroeconomic region of Lower Ganga Basin using principal component analysis (PCA), multivariable linear regressions (MLR), correlation analysis, and hierarchical cluster analysis, and evaluated the public health risks using the Latin Hypercube Sampling, goodness-of-fit statistics, Monte Carlo simulation and Sobol sensitivity analysis based on the 1000 samples collected in two sampling cycles (N = 1000). The study reveals that the dissolution of fluoride-bearing minerals and semi-arid climate regulate the fluoride concentrations (0.10–18.25 mg/L) in groundwater. Extensive application of inorganic nitrogenous fertilizers and livestock manure mainly contributed to elevated nitrate levels (up to 435.0 mg/L) in groundwater. The health risks analysis indicates that fluoride exposure is more prevalent in the residents of each age group than the nitrate and both contaminants exhibited higher non-carcinogenic health risks on the infant and child (minor) age groups compared to adolescents and adults. Based on the cokriging interpolation mapping, the minor residents of 17.88%–23.15% of the total area (4545.0 km2) are vulnerable to methemoglobinemia whereas the residents of all age-groups in 38.47%–44.45% of the total area are susceptible to mild to severe dental/skeletal fluorosis owing to consumption of untreated nitrate and fluoride enriched groundwater. The Sobol sensitivity indices revealed contaminant levels, groundwater intake rate and their collective effects are the most influential factors to pose potential health risks on the residents. Artificial recharge and rainwater harvesting practices should be adopted to improve the groundwater quality and the residents are advised to drink purified groundwater. 相似文献
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F既是重要的岩浆挥发分,又是重要的助熔剂和矿化剂,同时也是克拉克值较大的元素之一,并且在(铝)硅酸盐熔体中高度可溶。本文从F的常见工业矿物和主要赋存形式、分配行为的多样性、对其它元素分配行为的影响、矿化作用(即亲氟元素在热液体系中的氟化物络合形式、存在环境和沉淀机制等)、萤石和冰晶石的溶解及沉淀机制以及富F岩浆一热液体系的成矿专属性及特征6个方面探讨了F的地球化学成矿作用。结论认为:F必须有能力大量进入与花岗质或伟晶岩质熔体共存的含水流体相中才具有进一步的成矿学意义,云英岩化、钠长石化、含黄玉—萤石石英脉、具有较高F/CaO比值的残余熔体以及F在高度演化花岗质岩浆中的过饱和等因素均可能导致含矿富F热液的出溶;但总体上,富F岩浆—热液体系具有成矿专属性的原因之一仍在于:F首先通过对熔体物理化学性质的影响间接支配着高场强亲氟元素如W、Sn、Nb、Ta、REE、U等的热液成矿效应。 相似文献
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Sunil K. Jha 《洁净——土壤、空气、水》2012,40(12):1392-1400
The geochemical characteristics and the spatial distribution of the fluoride were studied in the soils of Indo‐Gangetic plains using multivariate analysis. The fluoride (F) distribution in soil profiles and surface soil (0–15 cm) samples were studied. It was found that total fluoride (TF) in the profiles ranged from 248 to 786 mg kg?1 with a mean of 515.1 mg kg?1 whereas CaCl2 extractable soluble fluoride (FCa) was found to be in the range of 1.68 to 99.1 mg F kg?1 soil. On the other hand, in surface soils, the TF and FCa ranged from 118 to 436 mg kg?1 with a mean of 251.2 mg kg?1 and 1.01 to 5.05 mg kg?1 with a mean of 2.12 mg kg?1, respectively, in the study area. The principal component analysis revealed that the natural weathering of fluoride bearing rock and minerals, various ion‐exchange and dissolution processes in the soil, alkalinity, sodium adsorption ratio, calcium (Ca), magnesium (Mg), and clay contents of the soil are responsible for high fluoride occurrence in the area. The fluoride contamination index developed by using these factors could explain more than 76% variance of F contamination due to FCa in soils. The interpolated kriged map of FCa in surface soil indicated a distinct loop of 1.0–2.0, 2.0–3.0, 3.0–4.0, and >4.0 mg kg?1. 相似文献
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Judith Hebelen Rodriguez Eduardo Daniel Wannaz María Luisa Pignata Andreas Fangmeier Jürgen Franzaring 《洁净——土壤、空气、水》2012,40(12):1315-1319
In order to study the pollution gradient in the vicinity of a large aluminium production facility in Patagonia (Argentina), a passive biomonitoring was performed employing foliage from three tree species. Primary scope was to identify pollution gradients and to select suitable tree species which can be used as biomonitor plants in the study area. Therefore, leaves of Eucalyptus rostrata, Populus hybridus and different needle ages of Pinus radiata were collected at different distances from the industry and the fluoride concentration was analysed in washed and unwashed samples in order to determine the amount of external fluoride. Washing reduced the F‐concentrations by 24, 39 and 51% on average in E. rostrata, P. hybridus and P. radiata, respectively, indicating that species‐specific characteristics determine the accumulation and wash‐off of dust‐associated fluorine. F‐concentrations varied from 6 to 3652 ppm F in unwashed samples indicating a steep pollution gradient in the study area. The influence of F‐emissions was discernible in all samples up to a distance of 3500 m from the smelter. E. rostrata accumulated more fluorine than the other species at equal distance from the emission source. The present study confirms that aluminium smelting results in high F deposition in the study area. Establishing a biomonitor network around large emitters is suitable and feasible to evaluate the efficiency of air control measures. 相似文献
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Temporal variations of fluoride concentration in Isparta public water system and health impact assessment (SW-Turkey) 总被引：1，自引：0，他引：1
Water–rock interaction is one of the prime factors affecting the fluoride contents of surface and groundwater. If fluoride
concentration of drinking water has been neglected, excess fluoride can cause serious dental and medical problems on human
health, which is well known at Golcuk-Isparta region. In the research area, Egirdir lake, Golcuk lake and surrounding springs
have been utilized as drinking water sources. Golcuk lake water and surrounding groundwaters have high fluoride content (1.4–4.6 mg/l),
which is above the WHO standards. Fluoride is predominantly supplied by dissolution of fluoride within the fluormicas of volcanics
during the circulation of water. Fluoride concentrations of waters have shown variations for dry and rainy seasons depending
on the degree of interaction between groundwater and volcanic rocks. It tends to decrease in rainy seasons and increase in
dry seasons for all years. In this study, temporal variations and spatial distribution of fluoride concentration in public
water system of Isparta were investigated to get benefit using GIS techniques from1990 to 2003 years. Extremely fluoride concentrations
were measured in the public water system in 1990 at almost every district of the city. In 2003, fluoride content of the public
water system decreased in some district of city due to drinking water has started obtaining from Egirdir lake in 1995. The
fluoride contents of Isparta drinking water ought to be modified with suitable mixture of lake waters and groundwater point
of view to health impact. 相似文献
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选作药用的蒙脱石。采自陕西省一处探明的粘土矿。矿体呈似层状,透镜状,产于第四系下更新统地层中,层位明显。矿石的矿物成分主要是蒙脱石和石英;化学成分以 SiO_2、Al_2O_3为主;总比表面和阳离子交换容量较大,交换性阳离子以 Ca~(2+)为主,其次是 Mg~(2+)。依照试验确定的活化方法和条件,将蒙脱石试样酸化处理,制成片剂,在氟病现场进行临床疗效观察。临床证明,用蒙脱石治疗氟骨症,效果显著,且无毒副作用。 相似文献
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Geochemical assessment of groundwater contamination with special emphasis on fluoride concentration, North Jordan 总被引：1，自引：0，他引：1
The concentrations of fluorine in groundwater of North Jordan range from 0.009 to 0.055 mg/l. Other chemical parameters, e.g. pH, EC, TDS, Cl, TH, HCO3, PO4, SO4, NO3, NH4, K, Ca, Mg, and NO3 have been studied and showed higher concentrations in HCO3− and NO3− of 307 and 51 mg/l, respectively. Thermodynamic considerations show that almost all the analyzed samples are undersaturated with respect to calcite and fluorite. This undersaturation is probably due to their low availability in the locations. Fluoride concentration shows a positive relation to pH and HCO3, whereas Cl, Mg, Ca, and Na initially increase and then decrease with increasing fluoride in the water. Saturation indexes of fluorite and calcite are estimated. The chemistry of the groundwater is controlled by the fluorite and calcite solubility. The topography of the area has exerted control on the aerial extent of fluoride concentration. 相似文献
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由高斯烟羽模式推导出的标准浓度分布推算源强分布的反演模式方法,计算了西宁市北郊地区环境空气中氟化物的环境容量。计算结果表明:拟建或已经在生产的各铝厂氟化物排放量均不超过按城市标准计算出的环境容量值,但均超过按农业区标准计算出的环境容量值。为了保护该地区农业生态环境,需要对现有的各铝厂氟化物排放量进行削减。 相似文献