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1.
运用铀系定年法首次对南水1井珊瑚礁岩心中的两个层位进行测年,结果与~(14)C测年一致,证实在晚更新世与全新世之间存在沉积间断面。  相似文献   
2.
High‐pressure granulites are characterised by the key associations garnet‐clinopyroxene‐plagioclase‐quartz (in basic rocks) and kyanite‐K‐feldspar (metapelites and felsic rocks) and are typically orthopyroxene‐free in both basic and felsic bulk compositions. In regional metamorphic areas, two essential varieties exist: a high‐ to ultrahigh‐temperature group and a group representing overprinted eclogites. The high‐ to ultrahigh‐temperature type formerly contained high‐temperature ternary feldspar (now mesoperthite) coexisting with kyanite, is associated with garnet peridotites, and formed at conditions above 900 °C and 1.5 GPa. Clinopyroxene in subordinate basic rocks is Al‐rich and textural evidence points to a high‐pressure–high‐temperature melting history. The second variety contains symplectite‐like or poikilitic clinopyroxene‐plagioclase intergrowths indicating former plagioclase‐free, i.e. eclogite facies assemblages. This type of rock formed at conditions straddling the high‐pressure amphibolite/high‐pressure granulite field at around 700–850 °C, 1.0–1.4 GPa. Importantly, in the majority of high‐pressure granulites, orthopyroxene is secondary and is a product of reactions at pressures lower than the peak recorded pressure. In contrast to low‐ and medium‐pressure granulites, which form at conditions attainable in the mid to lower levels of normal continental crust, high‐pressure granulites (of nonxenolith origin) mostly represent rocks formed as a result of short‐lived tectonic events that led to crustal thickening or subduction of the crust into the mantle. Short times at high‐temperature conditions are reflected in the preservation of prograde zoning in garnet and pyroxene. High‐pressure granulites of both regional types, although rare, are known from both old and young metamorphic terranes (e.g. c. 45 Ma, Namche Barwa, E Himalaya; 400–340 Ma, European Variscides; 1.8 Ga Hengshan, China; 1.9 Ga, Snowbird, Saskatchewan and 2.5 Ga Jianping, China). This spread of ages supports proposals suggesting that thermal and tectonic processes in the lithosphere have not changed significantly since at least the end of the Archean.  相似文献   
3.
Calculations,according to some open-system models,point out that while a statistically significant discrepancy between the results of two U-series methods,^230Th/^234U and ^227Th/^220Th(or ^231Pa/^235U),attests a relatively recent and important uranium migration,concordant dates cannot guarantee closes-system behavior of sample.The results of 20 fossil bones from 10 Chinese sites,19 of which are determined by two U-series methods,are given,Judging from independent age controls,8 out of the 11 concordant age sets are unacceptable,The results in this paper suggest that uranium may cycle into or out of fossil bones,such geochemical events may take place at any time and no known preserving condition may securely protect them from being affected.So for the sitew we have studied,the U-series dating of fossil bones is of limited reliability.  相似文献   
4.
Wet climatic episodes are known to have prevailed in the Egyptian Sahara several times during the late Quaternary, most recently during the Holocene 8000 yr ago. Earlier wet episodes have been recognized as having occurred during the past 300,000 yr and have been dated by U-series methods in speleothems and in lake travertines. We show here that the times of enhanced groundwater movement can also be determined by 230Th/234U dating of secondary U in ores of uranium, iron, and phosphate. We also present evidence that such acceleration of groundwater movements is indicated by relatively low 234U/238U activity ratios in the secondary uranium. Our new data show that pluvial periods in Egypt occurred during marine oxygen isotope stages 4, 5, 6, and 7 and therefore are consistent with the view that the wet episodes are the results of migration of the tropical monsoonal belt driven primarily by the 23,000-yr precession cycle of the Milankovich curve, modulated by the 100,000-yr eccentricity cycle.  相似文献   
5.
Differentiation of the continental crust is the result of complex interactions between a large number of processes, which govern partial melting of the deep crust, magma formation and segregation, and magma ascent to significantly higher crustal levels. The anatectic metasedimentary rocks exposed in the Southern Marginal Zone of the Limpopo Belt represent an unusually well‐exposed natural laboratory where the portion of these processes that operate in the deep crust can be directly investigated in the field. The formation of these migmatites occurred via absent incongruent melting reactions involving biotite, which produced cm‐ to m‐scale, K2O‐poor garnet‐bearing stromatic leucosomes, with high Ca/Na ratios relative to their source rocks. Field investigation combined with geochemical analyses, and phase equilibrium modelling designed to investigate some aspects of disequilibrium partial melting show that the outcrop features and compositions of the leucosomes suggest several steps in their evolution: (1) Melting of a portion of the source, with restricted plagioclase availability due to kinetic controls, to produce a magma (melt + entrained peritectic minerals in variable proportions relative to melt); (2) Segregation of the magma at near peak metamorphic conditions into melt accumulation sites (MAS), also known as future leucosome; (3a) Re‐equilibration of the magma with a portion of the bounding mafic residuum via chemical diffusion (H2O, K2O), which triggers the co‐precipitation of quartz and plagioclase in the MAS; (3b) Extraction of melt‐dominated magma to higher crustal levels, leaving peritectic minerals entrained from the site of the melting reaction, and the minerals precipitated in the MASs to form the leucosome in the source. The key mechanism controlling this behaviour is the kinetically induced restriction of the amount of plagioclase available to the melting reaction. This results in elevated melt H2O and K2O and chemical potential gradient for these components across the leucosome/mafic residuum contact. The combination of all of these processes accurately explains the composition of the K2O‐poor leucosomes. These findings have important implications for our understanding of melt segregation in the lower crust and minimum melt residency time which, according to the chemical modelling, is <5 years. We demonstrate that in some migmatitic granulites, the leucosomes constitute a type of felsic refractory residuum, rather than evidence of failed magma extraction. This provides a new insight into the ways that source heterogeneity may control anatexis.  相似文献   
6.
A dramatic demonstration of the role of intergranular solubility in promoting chemical equilibration during metamorphism is found in the unusual zoning of garnet in pelitic schist exposed at Harpswell Neck, Maine, USA. Many garnet crystals have irregular, patchy distributions of Mn, Cr, Fe and Mg in their inclusion‐rich interiors, transitioning to smooth, concentric zoning in their inclusion‐poor outer rims; in contrast, zoning of Ca and Y is comparatively smooth and concentric throughout. We re‐assess the disputed origin of these zoning features by examining garnet growth in the context of the thermal and structural history of the rocks, and by evaluating the record of fluid–rock interaction revealed in outcrop‐scale veining and fluid‐inclusion assemblages. The transition in the character of garnet zoning correlates with the onset of a synkinematic, simple‐shear‐dominated phase of garnet growth and with a shift in the composition of the intergranular fluid from CO2‐rich to H2O‐rich. Compositional variations in garnet are therefore best explained by a two‐stage growth history in which intergranular diffusive fluxes reflect differences in the concentration of dissolved species in these two contrasting fluids. Interiors of garnet crystals grew in the presence of a CO2‐rich fluid, in which limited solubility for Mn and Cr (and perhaps Fe and Mg) produced patchy disequilibrium overprint zoning, while appreciable solubility for Ca and Y permitted their rock‐wide equilibration. Rims grew in the presence of an H2O‐rich fluid, in which high intergranular concentrations for all elements except Cr enabled diffusion over length scales sufficient for rock‐wide equilibration. This striking example of partial chemical equilibrium during reaction and porphyroblast growth implies that thermal effects may commonly be subsidiary in importance to solubilities in the intergranular medium as determinants of length scales for metamorphic equilibration.  相似文献   
7.
The Timor Orogen represents one of the youngest arc–continent collisions exposed on the Earth. It has the potential to provide some of the key parameters about how this style of orogeny evolves. However, the metamorphic age of the highest-grade rocks formed in the collision remains controversial. Using U–Th–Pb dating of monazite from amphibolite-grade sillimanite and garnet-bearing schists we show the peak metamorphism occurred at 5.5–4.7 Ma. The young age of the monazite and the presence of significant amounts of common Pb required the development of a new protocol to simultaneously account for the 230Th disequilibrium and the 207Pb common Pb correction. The new estimate of metamorphic age is consistent with the estimates based on plate reconstructions for the initiation of arc–continent collision in East Timor. The metamorphic event is a result of this collision.  相似文献   
8.
The determination of uranium series disequilibria in fluvial environments is proposed as a method of calculating catchment mass balances. The technique is based on two main principles. Firstly, 234U is more mobile than 238U, especially during the early stages of weathering. Secondly, uranium is far more mobile than either thorium or protactinium. Consequently, teaching during weathering results in the loss of the uranium found in the fresh rock, leaving the two immobile daughters behind. The ratio of uranium carried by sediment to that dissolved, US/UW can, therefore, be determined from river water and sediment isotopic activity ratios. Fluxes of uranium can then be calculated from average concentrations in the water and the associated sediment, from which a sediment yield can be inferred. The Witham catchment in Lincolnshire has been used to test the proposed method. A US/UW ratio of between 5 and 7 is determined and a sediment yield of 2.51 ± 2.12 tonnes yr?1 km?2 is proposed. Although some problems concerning environmental chemistry have arisen, the validity of the approach is confirmed by the close correspondence between the results obtained and those inferred by earlier workers using more conventional methods.  相似文献   
9.
A 26-cm-long stalagmite (XY2) from Xinya Cave in northeastern Chongqing of China has been ICP-MS 230Th/U dated, showing a depositional hiatus at 2.3 cm depth from the top. The growth of the 2.3–26 cm interval determined by four dates was between 57 ka and 70 ka, with a linear growth rate of 0.023 mm/a. We have analyzed 190 samples for δ 18O and δ 13C, mostly in the 2.3–26 cm part. The δ 18O and δ 13C values between 57 ka and 70 ka reveal decadal-to-centennial climatic variability during the glacial interval of Marine Isotope Stage 4 (MIS4), exhibiting much higher resolution than that of the published Hulu and Dongge records during this interval. Speleothem δ 18O in eastern China, including our study area can be used as a proxy of summer monsoon strength, with lighter values pointing to stronger summer monsoon and higher precipitation, and vice versa. Two decreases in the δ 18O signature of XY2 record around 59.5 and 64.5 Ka are argued to correspond to the Dansgaard-Oeschger (D-O) events 17 and 18 respectively. The Heinrich event 6 (H6) can be identified in the record as a heavy δ 18O peak around 60 ka, indicating significant weakening of the monsoon in Chongqing during the cold period. The XY2 δ 18O record shows very rapid change toward to the interstadial condition of the D-O event, but more gradual change toward to the cold stadial condition. This phenomenon found in the Greenland ice core records is rarely observed so clearly in previously published speleothem records. According to SPECMAP δ 18O record, the glacial maximum of MIS 4 was around 64.5 ka with the boundary of MIS 3/4 around 60 ka. Unlike the marine record, the speleothem record of XY2, China, exhibits much high frequency variations without an apparent glacial maximum during MIS 4. However, the timing of MIS 3/4 boundary seems to be around 60 ka when the H6 terminated, in agreement with the marine chronology. The growth period of sample XY2 during glacial times probably reflects a local karstic routing of water, rather than having climatic significance. Supported by the National Natural Science Foundation of China (Grant Nos. 40672165, 90511004, 40672202) and the Academician Special Project of Chongqing Science Committee (Grant No. 2003-7835)  相似文献   
10.
杨书桐 《矿物岩石》1993,13(1):14-17
绝大多数的金矿化作用都是在非平衡的开放体系中完成的,再加上硫化物在结晶过程中生长速度过快,因此难免产生一些异常特征:晶格金在硫化物中大量出现、含金硫化物单晶中主元素含量变化很大以及主族元素Si加入硫化物晶格等。这些异常特征在皖南东至金矿化区得到了良好的体现,其成因是不能用经典的平衡态热力学和晶体化学理论来解释的。  相似文献   
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